4. Electronic Theses and Dissertations (ETDs) - Faculties submissions

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A comprehensive analysis of urban river pollution – the case of the Hennops river in Gauteng Province, South Africa
(University of the Witwatersrand, Johannesburg, 2023) Letseka, Thabiso Esaiah; Chimuka, L.; Richards, L.H.
The water quality of rivers is declining at an alarming rate due to pollution from anthropogenic activities associated with urbanization. To ensure ecological restoration and management of rivers, engaging in pollutant source apportionment, evaluation, and monitoring of water quality is of great significance. The study delivers a comprehensive assessment of the state of pollution in the Hennops river catchment facing pollution threats from rapid urbanization. The water quality assessment of the Hennops river was performed through chemical, microbiological, microplastics analysis and ecotoxicological approaches, spanning from upstream region in Tembisa to the downstream Hartbeespoort Dam. Standard methods were employed to assess physiochemical properties of the river’s water. Electrical conductivity and pH fell within the accepted criteria based on the standard water quality guidelines. However dissolved oxygen (DO) levels were below acceptable limits, ranging from 1.53 mg L-1 to 6.47 mg L-1. This signifies a substantial demand for oxygen in the river, likely due to the discharge of sewage from leaking pipes and wastewater treatment plants. This sewage introduces a high volume of organic matter, leading to an increased oxygen demand in the water. Microbiological pollution indicators were employed to assess the microbial water quality of the river. The study's findings revealed elevated bacterial counts, with Escherichia Coli (E. coli) reaching up to 2 250 cfu mL-1 upstream and decreasing to 30 cfu mL-1 downstream. These high counts suggest faecal contamination in the river water. Similar trends were observed with total coliform counts, high coliform counts 170 000 cfu mL-1 in the upstream which remained detectable even downstream and beyond the Hartbeespoort Dam, despite the dilution effects within the dam. The dam was identified as the primary repository for pollution originating upstream. Grab sampling followed by solid phase extraction (SPE) and the passive sampling using a Polar Organic Integrative Sampler (POCIS), were employed as sample preparation methods for preconcentration of methocarbamol, etilefrine, nevirapine, carbamazepine and venlafaxine from river water with subsequent analysis on Liquid Chromatography coupled to quadrupole time of flight mass spectrometry. Both methods yielded good figures of merit with limits of quantification in the range of 0.57 to 2.12 ng mL-1 for POCIS and 0.19 to 1.82 ng mL-1 for SPE. The compounds were detected in the water but at low levels (µgL-1 ), with detected concentrations of carbamazepine in the range 0.62 ng mL-1 – 0.32 ng mL-1 , methocarbamol detected in the range 0.11 ng mL-1 - 0.14 ng mL-1 and venlafaxine 0.50 ng mL-1 – 0.44 ng mL-1 using POCIS. The detected concentrations using SPE were in the range 0.13 ng mL-1 – 0.19 ng mL-1 for carbamazepine, while nevirapine and venlafaxine were detected although below limit of quantification. This underscores the advantage of using passive samplers, which enable the detection of fluctuating contaminant concentrations over time, in contrast to the one-time measurements obtained through grab sampling. In the case of microplastics in the water and sediment samples, five polymer types were identified: polyethylene (PE), polypropylene (PP), high density polyethylene, (HDPE), polyester and polystyrene. The predominant polymer type in surface water was PE (48.6 %), and that in sediment was PP (52.7 %). PE and PP were the most abundant polymer types in both phases, and as these also the leading polymers in plastics production. 80% of the identified microplastics were found to be fibre with most dominant sizes of 1-2 mm for sediments and 0.5-1 mm in water samples. The conducted tests deemed the river water not suitable for irrigation, drinking or recreational purposes and not capable to support aquatic life.
Acid[c]ity - Undamning the Dam: Wicking of the Harmony Gold Mine Dam Through Algae Exploration
(University of the Witwatersrand, Johannesburg, 2024-02) Le Pere, Justine; Doermann, Kirsten; Daskalakos, Christos
This project discusses the need to help fight against the effects of mining on water, and to help the surrounding environment and community. A large emphasis is placed on the use of algae to treat the water from the Harmony Gold Mines’ tailings dams, and the facility plays host to this natural water treatment method. The facility provides the space for water resource management and water treatment education to take place. The community of Tshepisong Phase 2 lies north of the facility and acts as the activator of the facility. Without the community needing to collect water for use at home, the facility would not have a strong sense of integration into the township. The layout of the facility allows the layers of privacy to help aid the program, and the program allows the facility to be transparent to its visitors and the neighbouring township.
Addressing high dimensionality in water quality modelling in water distribution networks
(University of the Witwatersrand, Johannesburg, 2024-02) Machweu, Morongwa Ednah; Taigbenu, Akpofure
Water quality models are the most effective tools for characterizing water quality conditions, assessing the effects of water pollution, and supporting decision-makers with water quality management. They can be utilised for detecting the variations in the water quality parameters. Despite the usefulness of water quality models, an appropriate and simple water quality descriptor for a particular application, considering the high dimensionality of various water quality parameters, remains a challenge (Chapman, 1992). To address this high dimensionality, a single dimensionless index is commonly used to describe water quality for a particular application. While pollution loads at various points in a river reach have been widely assessed by studies using water quality indices, little research has been done on water distribution networks with service reservoirs and a variation of loading conditions. In a water distribution network, service reservoirs function similarly to rivers in that they have complicated mixing mechanisms, are subject to a variety of water quality factors, and are sized and located differently. The most common water quality indices require the formation of subindices and weights to avoid ambiguity, eclipsing and rigidity. The Canadian Council of Ministers of the Environment Water Quality Index (CCME WQI) does not require the formation of sub-indices and weights, thus providing a simplified way of describing water quality. This study investigates the use of the CCME WQI to address high dimensionality in water quality modelling of water distribution networks, taking into consideration the locations of multiple service reservoirs. This study was carried out primarily for decision-making and design optimization purposes only. Using EPANET 2.2, four hydraulically optimised solutions (which satisfied minimum pressure requirements) were further analysed for water quality performance. This was achieved by incorporating simulated data on three water quality variables (chlorine residual, water age and THM concentration) into the CCME WQI for a hypothetical water distribution network, Anytown. The results indicate that two of the four hydraulically optimised solutions achieved excellent water quality levels. This study has demonstrated the usefulness of a dimensionless index as a proxy for multiple water quality variables of a water distribution system in facilitating decision-making.
Adoption of constructed wetlands in informal settlement
(University of the Witwatersrand, Johannesburg, 2023-08) Jetha, Hemal Girish; Thatcher, Andrew
The study aimed to assess the effectiveness of constructed wetlands as a solution to greywater treatment in the context of water use in Setswetla, Alexandra, an informal settlement in Johannesburg that is characterized by makeshift housing, poor sanitation, and a lack of proper greywater treatment facilities. The lack of such facilities has resulted in the disposal of contaminated greywater across the settlement, which poses serious health risks to its people. The installation of constructed wetlands was considered a feasible solution, given that they can be built without displacing the population. However, the successful implementation of this solution would require a change in the behaviour of the population regarding greywater disposal. Therefore, this study aimed to evaluate the adoption of constructed wetlands which were installed in one portion of Setswetla, Silvertown to gain a better understanding of whether installing constructed wetlands helps with greywater disposal. The study also sought to determine if there was any difference in water use behaviour before and after the installation of the constructed wetlands. The research revealed that there was not much behaviour change pre- and post-installation of the constructed wetlands. Some of the significant differences found was that more people reported that they do collect the same amount of water during both summer and winter. More participants indicated that they do not collect the same amount of water during the week and weekend. Less participants reported that they could collect water during the day and night.
Benchmarking the technical efficiency of south African municipal water utilities: a double bootstrap DEA approach
(University of the Witwatersrand, Johannesburg, 2023) Matutu, Amanda; Dikgang, Johane
Efficiency enhancement in the water sector can help to optimise the use of available resources and mitigate the impact of climate change on water resources, while promoting sustainable water usage. Ultimately, this can lead to cost savings that may be channelled into enhancing service delivery and expanding access to water. Benchmarking is considered a useful method for improving water sector efficiency. The production frontier approach is the most commonly used technique for benchmarking, which can be computed using either non-parametric techniques, including data envelopment analysis (DEA), or parametric methods, including stochastic frontier analysis (SFA). A review of the literature reveals that DEA has become the most frequently used method for efficiency analysis in the water sector. Though a predictable approach, the DEA method may be influenced by measurement errors and anomalies, and it cannot be used to draw statistical conclusions. To address this problem, the double-bootstrap DEA technique was introduced, which permits statistical inference in DEA models. This technique helps the researcher to estimate efficiency scores that have been corrected for bias, and also identifies the factors that influence efficiency. For these reasons, this research employs double-bootstrap DEA to evaluate the efficiency scores of municipal water utilities in the South African water sector. The truncated double-bootstrap regression outcomes show that water consumer debt, consuming units receiving free water, and the effects of climate change (such as temperature variation and altered rainfall patterns) all impact the relative efficiencies of municipal water utilities. The results indicate notable distinctions in rankings and efficiency scores between the double-bootstrap DEA model and the traditional DEA model for both urban and rural municipal water utilities. Using the regression model, this research discovered that water consumer debt and consuming units receiving free water are significant factors influencing the efficiency of urban and rural municipal water utilities. These findings raise concerns about the prospects of South African municipal water utilities, particularly their ability to strike a balance between supporting indigent households and securing revenue for maintenance and future water infrastructure development, as well as efficiently managing water consumer debt and addressing the effects of climate change to deliver desired results consistently and sustainably.
Benchmarking the Technical Efficiency of South African Municipal Water Utilities: A Double-Bootstrap Dea Approach
(University of the Witwatersrand, Johannesburg, 2023-03) Matutu, Amanda; Dikgang, Johane
Efficiency enhancement in the water sector can help to optimise the use of available resources and mitigate the impact of climate change on water resources, while promoting sustainable water usage. Ultimately, this can lead to cost savings that may be channelled into enhancing service delivery and expanding access to water. Benchmarking is considered a useful method for improving water sector efficiency. The production frontier approach is the most commonly used technique for benchmarking, which can be computed using either non-parametric techniques, including data envelopment analysis (DEA), or parametric methods, including stochastic frontier analysis (SFA). A review of the literature reveals that DEA has become the most frequently used method for efficiency analysis in the water sector. Though a predictable approach, the DEA method may be influenced by measurement errors and anomalies, and it cannot be used to draw statistical conclusions. To address this problem, the double-bootstrap DEA technique was introduced, which permits statistical inference in DEA models. This technique helps the researcher to estimate efficiency scores that have been corrected for bias, and also identifies the factors that influence efficiency. For these reasons, this research employs double-bootstrap DEA to evaluate the efficiency scores of municipal water utilities in the South African water sector. The truncated double-bootstrap regression outcomes show that water consumer debt, consuming units receiving free water, and the effects of climate change (such as temperature variation and altered rainfall patterns) all impact the relative efficiencies of municipal water utilities. The results indicate notable distinctions in rankings and efficiency scores between the double-bootstrap DEA model and the traditional DEA model for both urban and rural municipal water utilities. Using the regression model, this research discovered that water consumer debt and consuming units receiving free water are significant factors influencing the efficiency of urban and rural municipal water utilities. These findings raise concerns about the prospects of South African municipal water utilities, particularly their ability to strike a balance between supporting indigent households and securing revenue for maintenance and future water infrastructure development, as well as efficiently managing water consumer debt and addressing the effects of climate change to deliver desired results consistently and sustainably.
Comparative Analysis of Water Hyacinth Efficiency as Biosorbent and Phyto remediating Plant for Removal of Lead (Pb) Water Contaminants
(University of the Witwatersrand, Johannesburg, 2023-08) Nwagbara, Victor Uzoma; Parrini, Francesca; Newete, Solomon
One of the major problems facing the modern society is the issues of water contamination. The ability of aquatic plants to serve as both heavy metal biomarkers and phytoremediators has been advocated for many years. The purpose of this study was therefore to compare the efficacy of water hyacith as a biosorbent and phytoremediating plant for removal of lead from contaminated waters. Dry and fresh water hyacinth biomass were exposed to Pb-contaminated water at different time intervals of 1, 7, 14 and 21 days. The results showed that with the increase of the exposure time, the Pb removal capacity of the plant biomass also increased. The Pb water concentration in day 1 and day 7 were significantly different from those in day 14 and day 21 which were not significantly different from each other. The average Pb removal from the Pb-treated waters for the different time exposure of 1, 7, 14 and 21 days in the fresh water hyacinth biomass were 40%, 56%, 78 % and 79%, respectively, the highest reduction being in the latter. The biomass of the freshwater hyacinth roots had the highest Pd concentration compared to the shoot. On The other hand the average Pb removal by the dry water hyacinth biomass were 78.9 %, 78.5%, 78.3 % and 78.3% for day 1, 7, 14 and 21 respectively, showing no significant difference between the different time series exposure. This suggests the instant adsorption of Pb by the dry plant material from the first day of exposure, after which the active sites for adsorption saturates to accommodate any further Pb ion uptake. There were some plant stresses such as leaf chlorosis, and significant decrease in biomass weight and length of leaf-2 petiole in the lead-treated fresh water hyacinth plants compared to the controls (Pb-free water hyacinth plant). Thus, this study confirms that the largest removal by the dry water hyacinth biomass, occurred in the first day as opposed to the last day (day 21) by the freshwater hyacinth biomass.
Effect of pipeline pigging on raw water pipeline flow rate and energy consumption
(University of the Witwatersrand, Johannesburg, 2024-02) Phillip, Neil Claude; Ndiritu, John
Pipeline pigging is a widely used method of pipeline cleaning to improve the hydraulic efficiency of a pipeline system, reduce deposits within a pipeline, reduce operational costs and improve water quality. With insufficient pipe cleaning, pipeline deposits accumulate within the pipeline which reduces the cross-sectional flow area of the pipeline and increases the friction losses in the pipeline. This subsequently reduces the operating flow rate, increases the pumping cost of the system, and reduces the water supply to the surrounding area. Therefore, the study aimed to investigate the hydraulic improvements and operational cost savings of a pipeline system after pigging and to determine when pigging should be done. A case study of the Tayside high lift pump station in South Africa was used for this investigation. Results indicate that pigging removes deposits and sediments from the pipelines thereby increasing the flow rate while reducing the cost of pumping substantially. The increase in flow rate calculated from the case study was 23.9% after one of the pigging operations in 2016. In addition, the pigging operations completed yearly also indicated a flow rate increase after pigging. The study showed that the increase in sediment levels of the raw water in the rainy season led to a reduction in the hydraulic capacity of the pipeline indicating an increase in sediment deposition in the pipeline. Life cycle cost analysis of the case study system obtained annual cost savings of R991,800.59 over a 50-year period. Based on the findings, a flexible routine for pigging based on the reduction in the hydraulic capacity of the pipeline is proposed to cater for the variability in levels of sediment in the raw water in alignment to the rainfall and streamflow patterns. This allows the pipeline to operate at the lowest energy cost and at the highest possible flow rate.
Evaluating the Effectiveness of Green Drop Audit Criterion in Relation to Its Link to Enforcement Protocol in South Africa
(University of the Witwatersrand, Johannesburg, 2022-08) Tshongweni, Olwethu Lenox; Tutu, Hlanganani; Richards, Heidi L.
The Green and Blue Drop programs are incentive-based regulatory systems based on the Department of Water and Sanitation's (DWS) realization that rewarding positive behaviour is more efficient and effective than penalizing undesirable behaviour. The Green Drop was developed for the Wastewater Quality Management Regulation certification program. In contrast, the Blue Drop was developed for the certification program for the Drinking Water Quality Management Regulation (Burgess, 2021). Most municipalities have accepted them and have raised awareness about the need for better efficiency in the wastewater sector. The Sand River, in Polokwane wastewater treatment works (WWTWs), was chosen as the research area for this study. This particular river was selected based on the premise of continuous non-compliance of the wastewater treatment plant and the resulting pressure it puts on the Sand River by compromising its quality, with the DWS not having a successful way of regulating and enforcing the water user to abide by the rules of the license that has been issued. This study aims to evaluate the effectiveness of the Green Drop Program audits and assessments about their link to the regulatory system within the DWS. Additionally, a risk assessment and cumulative risk rating are used to assess wastewater discharge into the Sand River in the Limpopo Province. Based on the observation made during the study, it appears that within the DWS organizational arrangements, the lack of coordination among the sectors (compliance monitoring, water quality management, the green drop program, and enforcement), lack of accountability, and the regulatory requirement of cooperation within DWS sectors have hindered implementation. Some of the non-compliance factors may be due to the misuse of funds meant for infrastructure development and difficulties relating to capacity, procurement, and management of the WWTWs. Moreover, DWS's absence of interactive data management systems and business processes contributes to non-compliance. The Polokwane WWTW, directly linked to the Sand River, is overloaded and needs to comply with the Water Use Licence (WUL) conditions. For example, the 21 August 2022, this facility was found to be non-compliant by 69.01%, collectively with administration and technical conditions of the WUL issued to the facility (DWS, 2022c). In addition, this investigation discovered that the Polokwane facility, which has been operating outside of regulations for the past four years, therefore, as calculated in equation 7 could be responsible for 72.3% of the hazards to people's health, the quality of the river's water, and the aquatic ecosystem life in the Sand River in a single month. As much as some municipalities do not perform according to the desired standards, there have been a few noticeable, well-performing ones reported in the green drop report released in 2022. These include Langebaan WWTW (90%), Riebeek Valley WWTW (97%), Gansevallei WWTW (84%), and Wellington WWTW (95%), and this illustrates that the Green Drop Certification is achievable if the municipalities follow and adhere to the Water Use Authorization (WUA) issued them (DWS, 2022b). The DWS must integrate the internal structures or link sectors responsible for monitoring and regulating municipal water service facilities and incentivize performing facilities to improve their performance. Additionally, facilities with minor compliance issues, such as water quality, must be referred to the Water Quality Management (WQM) unit for further investigation and recommendations. However, those non-compliances of authorized wastewater treatment facilities that require regulatory attention must be referred to the compliance monitoring sector through the system for compliance monitoring. Lastly, those facilities that are not authorized must be directed to enforcement for further action. Therefore, using the Integrated Regulatory Information System (IRIS) as the umbrella body for both database and work-based information has an imperative role that can curb some of the issues faced by the DWS. Standard operating procedures (SOPs) should guide all interactions between these systems.
Improving the Penalty-Free Multi-Objective Evolutionary Design Optimization of Water Distribution Systems
(University of the Witwatersrand, Johannesburg, 2024-02) Kambalame, Emily; Ndiritu, John
Water distribution networks necessitate many investments for construction, prompting researchers to seek cost reduction and efficient design solutions. Optimization techniques are employed in this regard to address these challenges. In this context, the penalty-free multi-objective evolutionary algorithm (PFMOEA) coupled with pressure-dependent analysis (PDA) was utilized to develop a multi-objective evolutionary search for the optimization of water distribution systems (WDSs). The aim of this research was to find out if the computational efficiency of the PFMOEA for WDS optimization could be enhanced. This was done by applying real coding representation and retaining different percentages of feasible and infeasible solutions close to the Pareto front in the elitism step of the optimization. Two benchmark network problems, namely the Two-looped and Hanoi networks, were utilized in the study. A comparative analysis was then conducted to assess the performance of the real-coded PFMOEA in relation to other approaches described in the literature. The algorithm demonstrated competitive performance for the two benchmark networks by implementing real coding. The real-coded PFMOEA achieved the novel best-known solutions ($419,000 and $6.081 million) and a zero-pressure deficit for the two networks, requiring fewer function evaluations than the binary-coded PFMOEA. In previous PFMOEA studies, elitism applied a default retention of 30% of the least cost-feasible solutions while excluding all infeasible solutions. It was found in this study that by replacing 10% and 15% of the feasible solutions with infeasible ones that are close to the Pareto front with minimal pressure deficit violations, the computational efficiency of the PFMOEA was significantly enhanced. The configuration of 15% feasible and 15% infeasible solutions out performed other retention allocations by identifying the optimal solution with the fewest function evaluations.
Inclusion of nano-silver compounds in RO membranes as solutions to fouling by microbes and natural organic matter during seawater desalination
(University of the Witwatersrand, Johannesburg, 2023-08) Nchoe, Obakeng Boikanyo; Moloto, Nosipho; Sikhwivhilu, Keneiloe; Tetyana, Phumlani
The access to safe and potable water has become a salient discussion for governments across the globe. This is due to pronounced levels of the decline in volumes of available freshwater. Attributions to this phenomenon are mainly climate change, eutrophication, discharge of untreated effluent, heightened irrigation, and industrialization. Currently exploited freshwater sources are rivers, lakes, dams, glaciers, and aquifers. However, inconsistent rainfall patterns have rendered some of these sources as ‘stressed’, which is exacerbated by exponential population growth and misallocation of available freshwater. In hindsight, seawater was identified as a possible source of potable water. However, the high levels of salinity and miscellaneous contaminants (i.e., pathogens and natural organic matter) necessitates treatment of seawater prior its usage. Therefore, the purpose of this work is to develop rugged polyamide thin film nanocomposite (TFN) reverse osmosis (RO) membranes with antifouling properties for seawater desalination. TFN were fabricated by the inclusion of silver-based (i.e., silver sulfide) nanoparticles during interfacial polymerization of the polyamide active layer. Silver compounds are known to have superior antibacterial and photocatalytic properties, due to plasmonic and photo absorption properties. For this reason, silver oxide (Ag2O), silver sulfide (Ag2S), and silver chloride (AgCl) nanoparticles (NPs) were colloidally synthesized. These were then characterized and evaluated in photocatalytic and antibacterial applications. Cytotoxicity studies were also done to determine which of these NPs pose less risk to human health. The consolidation of data from these applications advised which of these NPs would be suitable for incorporation into the polyamide layer to produce fouling resistant TFN. Microscopic analysis depicted well-defined shapes, with average sizes of 23.0±5.7 (Ag2O), 30.6±7.4 (Ag2S), and 10.6±7.2 nm (AgCl). X-ray diffraction determined Ag2O, Ag2S, and AgCl NPs to have cubic, monoclinic, and cubic lattices, respectively. Optical spectroscopy determined Ag2O, Ag2S, and AgCl NPs to have band gap energies of 2.97, 3.11, and 3.05 eV, respectively. These observations inferred that crystalline NPs that exhibit surface plasmon resonance (SPR) in the visible region were successfully synthesized. SPR is a desired characteristic for photocatalysts, and indeed Ag2O, Ag2S, and AgCl NPs achieved humic acid degradation (HA) efficiencies of 86.2, 88.1, and 76.5%, respectively. In antibacterial studies, the broth micro-dilution method indicated that the minimum inhibitory concentration (MIC) values against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) for Ag2O, Ag2S and AgCl NPs were 0.03125, 0.125, and 0.125 mg/mL, respectively. The well-diffusion tests showed that Ag2O NPs had the largest zones of inhibition (ZOI), followed by Ag2S, then AgCl NPs. These observations demonstrated the concentration-dependent mitigation of bacterial cell proliferation. The NPs were further tested for cytotoxicity against human embryotic kidney 293 (HEK 293) cells. It was found that the cytotoxic concentration that rendered 50 % viability (CC50) were 0.0302, 0.3606 and 0.3419, and were obtained for Ag2O, Ag2S and AgCl NPs, respectively. This data implied that Ag2O NPs were the most toxic, while Ag2S and AgCl NPs were least toxic. In light of the above, Ag2S NPs were selected to be incorporated into TFN RO membranes. TFN RO membranes were fabricated by the addition of three different concentrations of Ag2S NPs in the aqueous phase to form the active polyamide (PA) layer on a polysulphone (PSF) support, namely 20, 30, and 50 mg. Fourier transform infrared (FTIR) spectroscopy detected vibrational peaks at 1659 cm-1 (amide I C=O stretch), 1542 cm-1 (amide II C-N stretch) 1481 cm-1 (C-H bend), 1385 cm-1 (C-O stretch), 1242 cm-1 (C-N stretch), and 779cm-1 (aromatic C-H and C=C wagging). The presence of aromatic and amide functional groups corroborated the formation of the TFN active layer, which is responsible for RO filtration of dissolved ions in water. Moreover, atomic force microscopy (AFM) revealed that average surface roughness decreased with increased Ag2S NP loading. TFN loaded with 20, 30, and 50 mg Ag2S NPs recorded water contact angles (WCA) of 54.1, 45.4, and 43.3°, respectively. The WCA of thin film composite membranes (TFC) without Ag2S NPs was recorded to be 73.5°. This demonstrated that the inclusion of Ag2S NPs increased surface hydrophilicity. In addition, salt rejection and water flux were higher for 30 mg loaded TFN (98 % and 32.7 L/m2h) compared to those of TFC (97% and 24.8 L/m2h). The bacterial growth inhibition was observed to be significantly high for 30 mg loaded TFN (80 %) compared to that of TFC (38 %). These observations indicate that the inclusion of Ag2S NPs significantly enhanced the performance of RO membranes and cost effectiveness of desalination.
Tailored Fabrication of MXene/Chitosan Nanocomposites as Efficient Adsorbents for Heavy Metals Removal from Wastewater
(University of the Witwatersrand, Johannesburg, 2023-08) Ibrahim, Yassmin Ahmed Ismail; Eid, Kamel; Ozoemena, Kenneth Ikechukwu
MXene (Ti3C2Tx) has been extensively utilized in water purification systems, including toxic metal ions removal, owing to the unique layered structure and abundant oxygen surface groups. However, challenges such as aggregation and solubility of Ti3C2Tx nanosheets in water have prompted the need for innovative strategies. In this study, we introduce a i3C2Tx-incorporated chitosan matrix (MX/CS) adsorbent designed to address solubility concerns during water treatment. MX/CS adsorbents are tested towards the capture of “cadmium” (Cd 2+) and “Zinc” (Zn2+) ions in aqueous solutions at varied pH values (i.e., acid, neutral and alkaline), initial ions concentrations (25, 50 and 100 ppm), and varied Ti3C2Tx loading (i.e., 1, 5 and 10), to study the optimization adsorption parameters. In addition, the Ti3C2Tx nanosheets were activated/alkalinized at ratio (2:1, i.e., 2MX:OH/CS), where more negative-ions sites are provided, thus, enhancing the preferential sorption for heavy metal ions in terms of high adsorption capacities, and kinetics than the non-activated samples (MX-10/CS). Freundlich isotherms are predominated for the Cd2+ and Zn2+ ions adsorption on both adsorbents. A selectivity study reveals that Zn2+ ions got adsorbed faster on the adsorbents than Cd2+ ions because of its low atomic radii and electronegativity. Finally, the adsorbents will be generated and prepared for additional adsorption cycles to test their stability. The second part of this work is to present the novel fabrication of multifunctional hydrophobic polymeric foam MX nanocomposites for large-scale ultrafast wastewater treatment. Likewise, the foam nanocomposite will be tested for the adoption of multi-ions solution over wide pH rage to demonstrate the applicability of the novel adsorbent for large-scale applications. Overall, this research contributes to the advancement of water treatment technologies by enhancing the stability of MXene-based adsorbents and introducing an innovative fabrication method for hydrophobic polymeric foam MX nanocomposites. The outcomes demonstrate the applicability of these novel adsorbents for efficient and scalable water purification solutions.
The characterisation of borehole water properties and soil salinity across seasons for the period 2016-2020 with some links to rainfall and sugarcane yield in the Makhathini Irrigation Scheme, KwaZulu-Natal
(University of the Witwatersrand, Johannesburg, 2024) Ndwamato, Ramabulana Cassius; Scholes, Mary
The sugar business in South Africa has a strong socioeconomic development focus in rural regions, creating jobs, giving a source of revenue, and constructing transportation and communication networks. Despite its benefits, the sugar sector has faced several obstacles mostly by Small-Scale Growers (SSGs), which have led to a decline in sugarcane production. This study analysed borehole water properties such as electrical conductivity, water levels, and temperature at the Makhathini Irrigation Scheme in KwaZulu-Natal. The quality of water from the Jozini/Pongola Dam used for irrigation was also analysed, in addition to the salinity levels of the soil at the irrigation scheme. Water from nineteen (19) boreholes within the irrigation scheme between 2016 and 2020 was collected every three months from January and tested. Annual water quality data collected upstream (PR1) and downstream (PR2) of the dam were obtained from the Department of Water and Sanitation. One kilogram of soil was collected from six sampling points, respectively, within the Makhathini Irrigation Scheme and sent for testing at the Agricultural Research Council Institute of Soil Water and Climate. Rainfall data and annual sugarcane yield data were obtained and analysed. The ANOVA results showed a significant (p < 0.05) difference in electrical conductivity (EC) between all 19 boreholes in the five-year data. The Tukey test also confirmed the electrical conductivity’s significant (p < 0.05) variation across all boreholes during dry and wet seasons. The borehole water level analysis shows that no significant (p > 0.05) difference was observed in dry seasons, but there was a significant difference in the wet seasons. The Tukey test also confirmed that the borehole water levels varied significantly during the wet season for the five-year study period, suggesting that the water levels were shallow in the wet seasons compared to the dry season. The borehole water temperature analysis indicates no significant (p > 0.05) difference for all seasons from 2016 to 2020. The water collected at PR1 suggests that the water from the dam is of acceptable quality for irrigation, while the return flow to the Pongola River at sampling point PR2 had high SAR, EC, and PO4 - concentrations. Samples collected downstream (PR2) show signs of pollution. This suggests that water contamination occurs when water passes through the Makhathini Irrigation Scheme. A t-test analysis reveals that pH, NO3 - , and NO2 have no significant (p > 0.05) difference, but SAR, EC and PO4 - were significant (p < 0.05). The measured parameters were compared to the Department of Water Affairs and Forestry standards for the quality of water used in agricultural irrigation. The correlation analysis between rainfall, borehole electrical conductivity, borehole water levels, and sugarcane yields revealed that while rainfall influenced borehole electrical conductivity, water levels, and sugarcane yield, the effect was minimal, possibly due to irrigation volumes. Rainfall had a positive effect on sugarcane production and EC but a negative effect on water levels. Soil salinity analysis demonstrated an increase in the soil's electrical conductivity with each passing year. The ANOVA analyses for sugarcane yield and soil salinity reveal statistically significant differences (p < 0.05). The accumulation of salts in the soil at the Makhathini Irrigation Scheme, also seen by the contaminated return flow to the Pongola River, reduces sugarcane yields. Water properties of the sugarcane irrigation water affect the soil salinity in the irrigation scheme and, consequently, the decline in sugarcane production by small-scale growers.
Trends in reporting on climate change, water and COVID-19 by JSE listed companies
(University of the Witwatersrand, Johannesburg, 2022) Seedat, Zakiyyah; Lange, Yvette; Maroun, Warren
Environmental, social and governance (ESG) information is increasingly demanded by stakeholders as companies face risks and opportunities due to ESG issues, such as climate change, water and COVID-19. ESG disclosure helps reduce information asymmetry for users of company reports and helps companies maintain their social licence to operate. Disclosure is voluntary and this introduces differences in the information disclosed by companies. This study analysed the annual, integrated and ESG reports of the top 40 Johannesburg Securities Exchange (JSE) listed companies. These reports were analysed following an interpretive approach to determine the extent of disclosure on climate change, water and COVID-19 in 2018, 2019 and 2020. This study also considered the change in disclosure on climate change and water over these three years. A disclosure checklist has been developed using professional literature. Content analysis has been used to codify the disclosed information with disclosures being scored using an ordinal scale. Descriptive statistics have been used to analyse and graphically present the data. Exploratory factor analysis has been used for the identification of major disclosure themes. This study contributes to existing research by considering the current state of ESG disclosure at a time when notable developments in the reporting environment have occurred. The findings indicate that companies have focused on quantitative and strategy-related disclosure, indicating the adoption of similar reporting practices by companies. The study also found that there was no significant change in climate change and water disclosure from 2018 to 2020
Trimetallic nanoparticles immobilised on polymeric membranes for the degradation of organic pollutants in water
(University of the Witwatersrand, Johannesburg, 2021) Kgatle, Masaku; Moloto, Nosipho; Sikhwivhilu, Keneiloe; Ndlovu, Gebhu
Water is one of the most essential resources in the world, but its scarcity has become an issue of global concern. The scarcity of water is largely the result of climate change, water pollution and increasing population growth which limits the availability of water resources. Moreover, South Africa has been making headlines since 2010 due to water shortages experienced. It is, therefore crucial to find cost-effective ways to expand the water supply and address the issue of water pollution. This study seeks to tackle the problem of water pollution emanating from textile industries. Over the last few years, nanotechnology and membrane technology have appeared as some of the most widely used methods for the mitigation of water pollution problems. Particularly, nanoscale zerovalent iron (nZVI) has emerged as one of the most broadly used nanoparticles in wastewater treatment and remediation owing to its low-cost and high effectiveness. However, because of its ease of aggregation and consequent loss of reactivity, nZVI is coupled with one or more transition metals to produce multimetallic systems. Nanoparticles alone quickly agglomerate and form large micro-scale particles owing to the magnetic forces thus losing their mobility and chemical reactivity. To avoid these issues, the nanoparticles are stabilized on polymeric membranes. In this study, two trimetallic nanoparticle systems were synthesized, characterized and tested for catalytic activity. The polyvinylpyrrolidone (PVP)-stabilized Fe/Cu/Ag nanoparticles were synthesized by the sodium borohydride chemical reduction method. These nanoparticles were characterized using XRD, XPS, EDX and TEM. The XRD, EDX and XPS techniques showed the presence of all three metals, including iron oxides due to the oxidation of iron in air. The obtained TEM images showed the characteristic core-shell morphology of the nZVI-based nanoparticles. The evaluation of the catalytic activity of the nanoparticles was conducted using methyl orange (MO) dye as the model pollutant and this showed a remarkable degradation efficiency within few minutes. The effect of parameters such as MO solution pH, initial MO dye concentration and nanoparticle dosage in MO degradation was investigated. The nanoparticles were found to have performed better at lower pH, lower initial MO dye concentration and higher nanoparticle dosage. The degradation of MO dye was monitored using UV-Vis analysis and occurred within 1 min. The degradation was found to follow a pseudo first-order kinetic model and was vastly influenced by the studied parameters. The analysis of by-products and reaction pathway were done using LC-MS and this further confirmed that the degradation of MO was indeed rapid. The Fe/Cu/Ag trimetallic nanoparticles were demonstrated as suitable and effectual alternative for the remediation of textile dye wastewater. For the second trimetallic system, three different trimetallic nanoparticles (Fe/(Zn/Ag), Fe/Zn/Ag and Fe/ Ag/Zn) with different metal addition sequences were synthesized. The prepared nanoparticles were characterized using XRD, EDX and TEM analyses. The techniques proved successful synthesis of the nanoparticles and XRD and EDX showed the presence of the three metals together with the oxides. The evaluation of the catalytic reactivity of the nanoparticles was conducted in a series of batch experiments using MO dye as the model pollutant. About 100% of the MO dye was degraded by Fe/ Ag/Zn trimetallic nanoparticles within 1 min and the second-order rate constant obtained was 0.0744 ppm- 1min-\ the rate of reaction was higher than that of the other trimetallic systems. Using Fe/ Ag/Zn trimetallic nanoparticles, parametric tests were conducted at different MO solution pH, initial MO concentration and nanoparticle dosage. The results showed that the reactivity of the Fe/Ag/Zn trimetallic nanoparticles was highly dependent on the aforementioned parameters. Like the Fe/Cu/Ag system, the Fe/Ag/Zn performed better at lower pH, lower initial MO dye concentration and higher nanoparticle dosage. The overall kinetic study showed the removal of MO using Fe/Ag/Zn system to follow a second-order kinetic model. The elucidation of the degradation pathway and MO by-products identification were done using LC-MS and the mechanism of degradation displayed the degradation of methyl orange to proceed via azo-bond cleavage. Moreover, the Fe/ Ag/Zn nanoparticles proved to be effective at degrading methyl orange dye and can be used to treat azo-dye wastewater from textile industries. The Fe/Cu/ Ag trimetallic nanoparticle system was immobilized on a polymethacrylic acid grafted polyethersulfone (PMAA-g-PES) membrane to minimize the issue of recoverability and nanoparticle agglomeration. The nanocomposite membranes were prepared by loading different quantities of Fe/Cu/Ag trimetallic nanoparticles onto the PMAA-g-PES membrane for optimization purposes. Characterization was performed using FTIR, NMR, XPS, SEM/EDS and AFM analyses. The PMAA g-PES and nanocomposite membranes were found to have a porous top layer and a rough surface. Moreover, the addition of nanoparticles did not cause any significant changes in the membrane structure, however, further addition of nano particles led to the blockage of pores. The performance of the synthesized membranes was tested using pure water flux and MO (anionic dye) and methylene blue (MB) (cationic dye) dye removal capacity. The negatively charged membranes were found to have more affinity for MB dye than the MO dye and this was ascribed to the charge interaction between the membrane surface and the dyes. The nanocomposite with 5% Fe/Cu/Ag trimetallic nanoparticle loading on PMAA-g-PES membrane (M4-5% membrane) was found to have the best adsorption capacity with about 60% MB dye removal efficiency. Furthermore, the effect of process parameters such as pH, temperature and H2O2 concentration on the removal of MB was studied. The removal efficiency was found to be higher at higher pH and lower temperature. About 100% removal efficiency was obtained when the process was performed at pH 9 in the presence of H2O2 via adsorption and Fenton degradation. This showed that a hybrid of processes was convenient for the removal of MB dye by adsorption (primarily) and degradation using the nanocomposite membrane. Adsorption equilibrium data were assessed using the Langmuir, Freundlich and Temkin models; the Temkin model was the most convenient to explain the adsorption of MB onto M4-5% membrane. Moreover, lcinetic studies were performed on four kinetic models: pseudo first-order, pseudo second order, intraparticle diffusion and elovich models. The pseudo second-order was found to be the best suitable to explain the adsorption of MB onto M4-5% membrane. Thus, the adsorption of MB onto the nanocomposite membrane is an exothermic chemical process that occurs on a heterogeneous surface. Therefore, the nanocomposite membrane has the prospective to be applied in the removal of cationic textile dyes in the presence of an oxidiser.
Use of Multispectral Satellite Imagery to Monitor the Decant Pond of Tailings Dams
(University of the Witwatersrand, Johannesburg, 2023-08) O’Donovan, Christopher Galen; Adam, Elhadi; Torres-Cruz, Alberto
Tailings dam failures, such as the Jagersfontein failure in the Free State province and the Fundão and Feijão failures in Brazil, have brought into question the ability of the mining industry to operate safely, threatening its social license. To improve the safety of tailings dams, leading indicators of dam safety should be monitored. The location and historical behaviour of the tailings decant pond provides insight into several such leading indicators and can be used as a proxy to flag potential construction issues. This work investigates the use of public multispectral data collected by the Sentinel-2 satellite mission to monitor the supernatant tailings dam decant pond. This is achieved by leveraging the cloud-based Google Earth Engine platform and open-source GIS tools. Sentinel-2 acquires visible and near infrared spectrum data with a spatial resolution of 10 m and a revisit time of 5 days. Pond data is obtained by visual assessment and automated thresholding of Sentinel-2 imagery. Thresholds of near-infrared (NIR) reflectance and the normalised difference water index (NDWI) obtained by a least square error analysis are investigated. Implementation of the method at three South African tailings dams, constituting four decant ponds, illustrates the capabilities and limitations of Sentinel-2 imagery. High spatial resolution (<5 m) multispectral satellite imagery and natural colour aerial orthophotos (<0.25 m) serve as reference data. Visually assessed Sentinel-2 pond data presented a bias towards slight over estimation of the pond area compared to reference data. Other leading indicators did not show systematic bias across all sites. In general, the deviation between Sentinel-2 and the reference measurements was high, indicating that Sentinel-2 imagery should be used with caution for measurements critical to dam safety. Site-specific thresholds of NIR and NDWI indicated that automated thresholding of the NDWI is superior to NIR reflectance alone. It is shown that Sentinel-2 timeseries imagery can be used in tailings dam monitoring to supplement existing construction surveillance frameworks and provide historical pond data in the absence of such information.
Water for Firefighting in Sol Plaatje Municipality, Northern Cape, South Africa
(University of the Witwatersrand, Johannesburg, 2023) Thage, Tumelo MacAurthur; Ilemobade, Adesola
In South Africa, SANS 10090 (SABS, 2018a) and the Red Book (DHS & CSIR, 2019) recommend that for firefighting municipal water distribution systems must have and maintain the capacity to provide water for firefighting purposes. van Zyl & Haarhoff (2007) state that the provision of water for firefighting is a dominant design consideration as it influences the sizing and outputs of critical components. Scheepers (2012) argues that fire flows acts ‘as the most limiting demand condition’ as when it required it is extracted in large quantities for a short period. The most commonly used fire flow values in the SANS 10090 have largely remained unchanged for several decades. In other words, these values have not been revised to take account of the evolution of municipal water consumption over more than 30 years. This suggests that the recommended water requirements for firefighting may no longer be fit for purpose. The literature review revealed that the fire flows in the Red book violates the same in the SANS 10090 - this is illegal as the SANS 10090 specifies enforceable absolute limits. Furthermore, the Red book and SANS 10090 provide different fire risk classifications and values for the different parameters and as such, inconsistent and lack uniformity. It is important for design engineers to have accurate input data when planning and designing for fire flow requirements as any deficiency in basic design information could lead to an insufficient capacity to fight fires or an over-design of water supply infrastructure. A question arose from these observations, which provided inspiration for this study: Are fire flows in the SANS 10090 and Red book appropriate for current firefighting efforts? In answering this question, the first step of this study was to identify participating municipalities that were willing to release their datasets on firefighting for this study. Sol Plaatje municipality was one of the willing municipalities. This study thereafter categorised and analysed information contained in the 3236 fire incident reports that occurred within Sol Plaatje Municipality during the period 21 July 2017 to 21 August 2020, and compared actual fire flow volumes and flow rate data against the SANS 10090, Red book and previous South African studies. In order to provide context and aid better understanding of the datasets, structured interviews were conducted with municipal officials responsible for firefighting operations at Sol Plaatje municipality. Key highlights of this study indicated: ∼ 93.3% of fires in Sol Plaatje municipality were extinguished using 7 Kℓ or less of water. This result is similar to previous studies- In a 2014 study more than 90% of fires in 5 Western Cape Towns were extinguished using less than 10 Kℓ of water; In a 2019 study, 75% of fires in the City of Johannesburg were extinguished using less than 6.60 Kℓ of water; and In a 2022 study, 87% of fires in the City of Johannesburg were extinguished using 10 Kℓ or less of water. Overall, 75%-93% of fires were extinguished in the various study areas using 10 Kℓ or less of water. For large fires in Sol Plaatje municipality, the average water volume used to extinguish 85 large Category 2 fires was 8.56 Kℓ or less of water. This finding is similar to that of the Western Cape 2014 study and the 2022 City of Johannesburg study that found that 8.6 Kℓ and 9.63 Kℓ or less of water extinguished 77 and 89 large category 2 fires, respectively. What is evident from the results is that the volumes of water used in Sol Plaatje and previous studies are significantly less that the specified values in SANS 10090 and the Red book. An adverse consequence of higher values is that it leads to an over-design of water supply infrastructure as it increases the volume of municipal storage required for firefighting and consequently, increases the total capacity of municipal storage. Increased storage capacity increases resources that are expended, as well as water retention times, which negatively affects water quality. This study validates the recommendations of previous studies that the fire flows in the SANS 10090 and Red book need to be revised to enable the efficient conservation of scarce water resources and optimal design of water systems.
Water innovation and the circular economy in special economic zones in South Africa
(University of the Witwatersrand, Johannesburg, 2022) Bedessy, Kiara; Soumonni, Diran
In light of the planned economic recovery identified by the South African government, the applicability of various mechanisms, principles and theories which enable economic development should be considered, particularly in the context of growing urbanisation and water scarcity challenges. The first mechanism considered in this study relates to the use of special economic zones to drive industrial growth and as a mechanism of attracting foreign direct investment. The second mechanism relates to the adoption of alternative economic models such as the circular economy (CE) which addresses both economic development and resource challenges. The third mechanism relates to expedition and exploration of technologies aligned to the current technological revolution which is information, communication and technology (ICT) based and is expected to result in a new social and economic paradigm or techno-economic paradigm (TEP). The final mechanism for economic development is related to the promotion of all types of innovation which historically have been linked to economic development. This research report explores these selected recovery mechanisms with a focus on ICT-led circular water innovation and its impact on economic development and developing a green economic paradigm. There is a need to understand the meaning and impact of the CE on economic development in South Africa in light of the economic recovery considerations and the constraints related to water. CE innovation, in all categories, is important given the positive relationship innovation has with economic development and the opportunity to use all types of innovation and not just original innovation as a developing country. In addition, a better understanding of the current global technological revolution is required in order to determine its applicability for the South African context, particularly given its expected culmination into a green techno-economic paradigm which will have a beneficial societal and economic impact. The role of SEZs as a showcase on how circular economy innovation and water technologies have been adopted in an environmentally and economically beneficial manner will assist in providing practicality to the study. Seven of the ten SEZs in South Africa were used as a sample with qualitative, semi-structured interviews conducted with SEZ representatives and water specialists. All interviewees were familiar with the topics of water, innovation and the circular economy in SEZs. Interviews were supplemented with document analyses of water innovation in industries in South Africa. The major findings of this study are that water innovation in the circular economy has a positive environmental impact through the reduction of pollution and improved water security. The socio-economic impact primarily relates to job creation both in new industries that are emerging from offtakes and new service models and there is potential for green jobs. There are many types of ICT enabled water innovation adopted within the SEZs with water monitors being the most prevalent. From a techno-economic paradigm perspective when measured against the TEP criteria of low cost, opportunities for entrepreneurship and organisational change, only the criterion of cost reduction has been observed in this study with entrepreneurship and organisational change lagging. However, the potential exists to create clusters of innovation which include water monitors, robotics and data analytics as a cluster or desalination, renewable energy (hydro and solar power) and low-cost membranes as another cluster. These clusters when coupled with government support through entrepreneurship incubation and policy incentives, have the potential to hasten the technological revolution through increased innovation, adoption and diffusion of technologies. This is however a collaborative effort wherein both the private and public sector need to work together to build an ICT enabled circular economy to create new green growth and economic development
Water quality assessment at Vaalkop Dam in North-West Province using multispectral remote sensing data
(University of the Witwatersrand, Johannesburg, 2022) Mthimkulu, Lindy Ndzumbululo; Adam, Elhadi
Water is a life-sustaining resource for all organisms. As much as nature share the value of water with human being it cannot supersede how human have become dependent on water for drinking, sanitation, farming, mining, and other industrial purposes such as power generation. Water is perceived as a vital component in the fight against poverty, the foundation of any successfully growing and developed country is also measured on water and sanitation provision (Basson et al., 1997). The water law in South Africa stresses that essential human and ecological necessities must be given (DWAF, 1998) and that the misuse of water from all perspectives should be feasible (New, 2002).

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Browsing 4. Electronic Theses and Dissertations (ETDs) - Faculties submissions by SDG "SDG-6: Clean water and sanitation"

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