Faculty of Engineering and the Built Environment (Research Outputs)
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Item Recovering phosphorus as struvite from anaerobic digestate of pig manure with ferrochrome slag as a magnesium source(Elsevier, 2023-04) Moyo, L.B.; Simate, G.S.; Mamvura, T.A.; Danha, G.The circular economy initiative has driven the agriculture and agro-based industry to beneficiate from waste,thus closing the material loop towards enhancing economic and environmental performance. In this study, the aim was to recover phosphorus from anaerobic digestate of piggery wastewater (ADPW) using ferrochrome slag (FCSL) as the magnesium source to improve the environmental and economic sustainability of struvite precipitation. This was achieved by leaching 100 g L− 1 of ferrochrome slag with 5 M HCl where 14.02 g L− 1 of magnesium ions were extracted, and this acid-leachate of ferrochrome slag also contained 2650 mg L− 1 of total iron. To simultaneously remove both high concentrations of organic matters in ADPW and iron in FCSL which are known to be detrimental to struvite precipitation, hydrogen peroxide (H2O2) at an H2O2/Fe molar ratio of 0.75 and pH 4.0 was added to the mixture of ADPW and FCSL. After the Fenton reaction, removal efficiencies of chemical oxygen demand (COD) and total iron reached 95.06% and 94.00%, respectively. Then COD and an iron-reduced mixture of ADPW and FCSL were added with a satisfying Mg:N:P molar ratio of 1.2:1:1.15 at pH 9.5 to produce struvite in 1 h. From 1 L of ADPW (2.6 g NH3–N), 0.5 L of FCSL (5.34 g Mg2+), and 6.62 g of PO4 3− P, were consumed to produce 45.57 g of struvite precipitate. Additionally, the economic feasibility of ferrochrome slag was assessed by estimating the chemical costs of FCSL against that of magnesium chloride which is commercially used. It was observed that using FCSL was cheaper as compared to using commercial MgCl2. Response surface methodology coupled with the central composite design was applied as a statistical tool to determine the effects of the key parameters (N:P; Mg:PO4; pH) on phosphorus recovery. Second-order polynomial equations were determined to correlate the parameters. ANOVA was applied and showed that p values for all the investigated parameters were less than 0.05 showing that they had a statistically significant effect on the phosphorus recovery. The study confirmed that it was possible to recover phosphorus as struvite from anaerobic digestate of pig manure with ferrochrome slag as a magnesium source.Item Adsorptive removal of BTEX compounds from wastewater using activated carbon derived from macadamia nut shells(IWA Publishing, 2023-01) Melaphi, Kedibone; Sadare, Olawumi O.; Simate, Geoffrey S.; Wagenaar, Stephan; Moothi, KapilIn this study, adsorptive removal of benzene, toluene, ethylbenzene and xylenes (BTEX) from synthetic water using activated carbon adsorbent derived from macadamia nut shells was investigated. The surface functional groups of the synthesized adsorbents were assessed by Fourier transform infrared spectra. The specific surface area, pore size and pore volume at 77 K nitrogen adsorption, surface morphology, and the crystalline structure of the adsorbents were determined using Brunauer-Emmett-Teller, scanning electron microscopy and x-ray diffraction, respectively. Batch adsorption mode was used to evaluate the performance of the activated carbon. The stock solutions of synthetic wastewater were prepared by dissolving 100 mg/L of each of the BTEX compound into distilled water in a 250 mL volumetric flask. Effect of initial concentration of BTEX compounds, contact time, and mass of adsorbent on the removal of BTEX compounds from the synthetic wastewater was investigated. The macadamia nut shell–derived activated carbon (MAC) proved to be an effective adsorbent for BTEX compounds, with a large surface area of 405.56 m2 /g. The exposure time to reach equilibrium for maximum removal of BTEX was observed to be 20 min. The adsorption capacity of the BTEX compounds by MAC followed the following adsorption order: benzene > toluene > ethylbenzene > xylene.Item Design and Analysis of Consequent-Pole Permanent Magnet Vernier Motor With Cancellation of Even-Order Harmonics(IEEE Transactions on Magnetics, 2023-11) Hsieh, Min-Fu; Chang, Chia-Yuan; Huynh, Thanh-Anh; Dorrell, D. G.This article develops a method for the cancellation of the inherent even-order harmonics in consequent-pole permanent-magnet vernier motors (CP-PMVMs) to improve the performance. Vernier motors can achieve high torque density; however, their high pole number means a high amount of rare-earth permanent magnet (PM) usage at a high cost. The consequent-pole design can reduce PM material cost but leads to high even-order harmonics and torque ripple. This article analyzes two winding configurations in order to develop the method for even-order harmonics cancellation in the CP-PMVMs. Two CP-PMVMs with different slot–pole combinations are analyzed to verify the proposed method. The effect of magnetic barriers on the torque output of the CP-PMVM with canceled even-order harmonics is evaluated. Finally, a multi-objective genetic algorithm is used to optimize the motor. Finite element analysis (FEA) is used to validate the design, with subsequent confirmation of simulations through prototype testing.Item An assessment of the artificial modelling elements approach to the pressure-driven analysis of water distribution networks(IWA Publishing, 2023) Tanyimboh, Tiku T.; Sivakumar, P.; Gorev, Nikolai B.; Nivedita, S.; Suribabu, C. R.; Gupta, RajeshEPANET 2.2 is a newly introduced upgraded version of EPANET 2 that can be used for both pressure-driven analysis (PDA) and demanddriven analysis (DDA) of water distribution networks. Moreover, it has certain limitations concerning the minimum and required pressure head parameters used for PDA, which leads to inaccurate simulation results. Another limitation of the PDA option of EPANET 2.2 is its inability to simultaneously consider pressure-dependent demands with pressure-independent fire demands. In this article, the reason for the spurious convergence is identified, and it is shown that the spurious convergence of EPANET 2.2 can be addressed by extending the energy balance convergence criterion to include the virtual demand links employed in the EPANET 2.2 formulation of PDA. On the other hand, interest in the methods that use artificial modelling elements in EPANET 2 for PDA is increasing rapidly. The implementation of the method presented in this paper (termed the alternative PDA approach) allows an extended period simulation of large networks with complex demand patterns, multiple tanks, reservoirs, pumps, valves, and thousands of pipes. Two benchmark networks and two real-world networks were analysed by both the alternative PDA approach and EPANET 2.2 and the results were compared.Item Adaptive-Mode PAPR Reduction Algorithm for Optical OFDM Systems Leveraging Lexicographical Permutations(MDPI, 2023-06) Niwareeba, Roland; Cox, Mitchell A.; Cheng, LingIn direct current optical orthogonal frequency division multiplexing (DCO-OFDM) systems, the high peak-to-average power ratio (PAPR) has been a significant challenge. Recently, lexicographical symbol position permutation (LSPP) using random permutations has been introduced as an efficient solution to reduce high PAPR. In this paper, we aim to evaluate the effectiveness of LSPP by comparing both adjacent and interleaved lexicographical permutation sequences with random lexicographical permutation sequences. Our findings demonstrate that random permutation yields superior PAPR reduction performance results when compared to adjacent and interleaved permutation. However, in scenarios with a limited number of sub-blocks, the use of adjacent and interleaved permutation becomes more favorable, as they can eliminate the possibility of generating identical permutation sequences, a drawback of random permutation. Additionally, we propose a novel algorithm to determine the optimal number of candidate permutation sequences that can achieve acceptable PAPR reduction performance while adhering to computational complexity constraints defined by the system requirements.Item The valorisation of platinum group metals from flotation tailings: A review of challenges and opportunities(Elsevier, 2023-06) Gibson, Borbor A.K.K.; Nwaila, Glen; Manzi, Musa; Ndlovu, Sehliselo; Ghorbani, Yousef; Petersen, JochenFlotation tailings from South Africa’s platinum group minerals (PGM) represent complex polymetallic orebodies comprising a low-grade platinum group elements (PGE) content and complex mineralogical composition. Nevertheless, given the valuable mineral potential in the tailings, it is understandable that the substantial historic tailings deposits and sizeable annual production volume from primary processes represent a potential secondary resource. For several decades, valorising the PGM tailing materials received very little interest due to limitations associated with extractive metallurgical technology to achieve economically viable PGE extraction. The early 21st century saw the coming online of technologies, including but not limited to ultrafine grinding, suitable to meet challenges in primary metallurgical treatment processes to recover valuable minerals from ultrafine particle fractions, which could not otherwise be recovered. More so, such processes were critical in improving the liberation of partially liberated particles without compromising additional ultrafine generation. These technologies led to the development of re-treatment pilot tests and subsequent industrial re-treatment recovery processes. The current industrial re-treatment approach – via tertiary scavenging flotation circuits – renders profit in small increments up to 1 ~ 2% additional recovery relative to the primary plant head grade. These small increments relate to about ~12–30% PGE recovery of the feed grade to the re-treatment circuit, thereby enhancing the primary plant’s overall economics as well as aiding the supply of critical metals to meet global demands. With a focus on South Africa, this review provides an overview of (a) the current and future drivers of the precious metals global demand; (b) proffers discussion on the PGM characteristic mineralogy and the metallurgical value chain; (c) relates the parent orebodies (“reefs”) mineral characteristics to the inherent processed tailings; (d) estimates the economic potential these massive processed waste materials contain, (e) provides an overview of existing technologies that are industrially used in tailing re-treatment plants; and (f) outlines a comprehensive understanding of the nature of value minerals rejection to tailings.Item Comparative analysis of coal and coal-shale intrinsic factors affecting spontaneous combustion(Springer Open, 2018-09) Onifade, M.; Genc, B.Coal and coal-shales tend to undergo spontaneous combustion under favourable atmospheric conditions. Spontaneous combustion liability index and intrinsic properties of coals and coal-shales varies between (above and below) coal seams. The spontaneous combustion liability index (obtained from the Wits-Ehac Index) and intrinsic properties (obtained from proximate, ultimate, and petrographic analysis) of fourteen samples representative of in situ coal (bituminous) and fourteen coal-shales obtained in Witbank coalfield, South Africa were experimentally studied. Comparative analysis of the relationships between the spontaneous combustion liability index and intrinsic properties of coals and coal-shales were established to evaluate their effects on self-heating potential. The intrinsic properties show linear relationship with spontaneous combustion liability and therefore, identifies the factors affecting spontaneous combustion of these materials. The influence of coal-shales intrinsic properties towards spontaneous combustion liability shows higher correlation coefficients than the coals. Both coals and coal-shales show inertinite maceral as major constituents than the vitrinite and liptinite macerals, hence the reactivity of inertinite macerals may show greater influence on spontaneous combustion liability. A definite positive or negative trends exists between the intrinsic properties and spontaneous combustion liability index. This research is part of a larger project which is considering the influence of intrinsic properties of coals and coal-shales on spontaneous combustion liability.Item Modelling spontaneous combustion liability of carbonaceous materials(Springer Open, 2018-06) Onifade, M.; Genc, B.This paper presents predictive models to determine spontaneous combustion liability of carbonaceous materials (coals and coal-shales) using statistical analysis. The intrinsic properties and spontaneous combustion liability index were determined by testing 14 coals and 14 coal-shales from Witbank coalfields, South Africa. The relationship between these intrinsic properties (obtained from proximate, ultimate and petrographic analysis) and spontaneous combustion liability indices (the Wits-Ehac Index and Wits-CT Index) were established. The influence of the intrinsic properties of coal-shales in relation to coal properties affecting spontaneous combustion has been established using a statistical method. The linear regression analysis indicates better linear relationships between some of the selected intrinsic properties and spontaneous combustion liability index and thus, identifies the major intrinsic factors affecting their liability toward spontaneous combustion. It was found that a definite positive or negative correlation coefficient exists between the intrinsic factors and spontaneous combustion liability. A set of models to predict the spontaneous combustion liability was derived. The best significant correlation along with the most appropriate model as indicated by R-squared values, the coefficient of correlations and standard error was used to predict the incident of spontaneous combustion.Item Optimizing Structures with Semi‑Rigid Connections Using the Principle of Virtual Work(Springer, 2018-04) Elvin, Alex; Strydom, JohnnieIn this paper, the virtual work optimization method (VWOM) has been generalised to consider structures with semi-rigid connections. The VWOM is an automated method that minimizes the mass of a structure with a given geometry, multiple deflection criteria, and load cases while adhering to design code requirements. In the optimization process, members are selected from a discrete database to meet all strength and stiffness criteria. Connections are modelled using rotational springs, allowing some moment transfer. The rotational stiffness of each connection can be varied from rigid to pinned. The example of a pitched roof frame is used to explain the method. Two case studies are considered: (i) (i) a three-storey two-bay and (ii) a four-storey three-bay office building. The VWOM produced results up to 26.7% lighter than results in the literature. Furthermore, the structures were optimized for a range of rotational stifness, where all connections in the structure were assumed to have the same rotational stiffness. Characteristic jumps in the optimized mass versus rotational stiffness were observed.Item Minimising the risk of thermally induced cracking in mass concrete structures through suitable materials selection and processing(Springer, 2018) Ballim, YunusThe hydration of cement is an exothermic reaction which generates around 300 kJ/kg of cement hydrated. In mass concrete structures such as dams and large foundations, this heat of hydration causes a significant rise in temperature in the internal sections of the concrete. If thermal gradients between the internal sections and the near-surface zone of the concrete element are sufficiently large, the thermal stress can cause cracking of the concrete. This cracking may cause functional or structural problems in the operation of the structure. In order to minimise the potential for such cracking, it is necessary to minimise the rate and amount of heat that is evolved, particularly during the early period of the hydration process. This can be achieved by design engineers and concrete technologists through judicious selection and processing of concrete-making materials. This paper presents the observations and results obtained over a number of years from adiabatic testing of concretes, computational modelling of temperature development in large concrete structures and direct temperature measurements in actual structures, with a view to understanding the effects of concrete-making materials on temperature development in concrete. The paper considers the effects of different types of rock aggregates, different types of Portland cement, fineness of grinding of the cement, the addition of supplementary cementitious materials and variations in the concrete starting temperature on temperature development in a large concrete element over time. The results indicate that using a coarser ground cement, adding significant amounts of supplementary cementitious materials and cooling the concrete mixture before placing has a more significant effect in reducing the risk of cracking than varying the aggregate type of the Portland cement type.