Assessing aquifer vulnerability to landfill pollution using drastic method in Gauteng, South Africa

dc.contributor.authorMphaphuli, Idah
dc.contributor.supervisorAbiye, Tamiru
dc.date.accessioned2024-11-27T11:03:33Z
dc.date.available2024-11-27T11:03:33Z
dc.date.issued2023
dc.descriptionA Research Report submitted in partial fulfilment of the requirements for the degree of Master of Science (in Hydrogeology), to the Faculty of Science, School of Geosciences, University of the Witwatersrand, Johannesburg, 2023.
dc.description.abstractThis study integrated the DRASTIC method and field investigations into mapping the degree of vulnerability of aquifers to landfill pollution in the Gauteng Province, which is one of the most populated provinces in South Africa. In order to investigate the aquifer vulnerability of Gauteng's heterogeneous and complex geology, the DRASTIC method was used to generate intrinsic and specific vulnerability maps. Three vulnerability classes were generated from the DRASTIC index, namely, low vulnerability, moderate vulnerability and high vulnerability, which covered 46%, 37% and 17% of the study area, respectively. The highly-vulnerable areas were associated with the karst aquifer of Malmani dolomite, permeable vadose zone, high hydraulic conductivity and loamy sand/sandy loam soil type, whilst moderately-vulnerable areas were associated with fractured/weathered aquifers, high recharge and low topography. The intrinsic vulnerability was validated using average NO3+NO2-N (nitrate + nitrite as nitrogen) and the results of water samples from field investigations conducted in Marie Louise and Robinson landfill sites. Elevated NO3+NO2-N concentration (9.85-16.03 mg/l) was observed in the highly-vulnerable areas. Water samples were collected, in order to analyse the water chemistry, stable isotopes and radioactive isotopes (tritium). Gibbs and Piper diagrams were used to evaluate the main mechanism controlling the groundwater chemistry and the dominant major ions that influence it. Pollution by leachate was detected in the Marie Louise landfill site, where the groundwater showed high tritium and ammonia concentration. The main hydrochemical facies detected in Marie Louise were Mg SO4, Ca-SO4, Na-SO4 and Na-Cl. The hydrochemical facies detected in Robinson were Na-SO4, Ca-HCO3, Na-Cl and Ca-Cl. The DRASTIC method was shown to be effective in assessing groundwater vulnerability on a regional scale, provided that there is adequate input data.
dc.description.sponsorshipSouth African National Space Agency (SANSA).
dc.description.sponsorshipEnvironmental Resources Management (ERM).
dc.description.submitterMMM2024
dc.facultyFaculty of Science
dc.identifier0000-0003-0432-6529
dc.identifier.citationMphaphuli, Idah. (2023). Assessing aquifer vulnerability to landfill pollution using drastic method in Gauteng, South Africa. [Master's dissertation, University of the Witwatersrand, Johannesburg]. https://hdl.handle.net/10539/42934
dc.identifier.urihttps://hdl.handle.net/10539/42934
dc.language.isoen
dc.publisherUniversity of the Witwatersrand, Johannesburg
dc.rights©2023 University of the Witwatersrand, Johannesburg. All rights reserved. The copyright in this work vests in the University of the Witwatersrand, Johannesburg. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of University of the Witwatersrand, Johannesburg.
dc.rights.holderUniversity of the Witwatersrand, Johannesburg
dc.schoolSchool of Geosciences
dc.subjectGroundwater vulnerability
dc.subjectLandfill leachate
dc.subjectGroundwater pollution
dc.subjectDRASTIC method
dc.subjectUCTD
dc.subject.otherSDG-13: Climate action
dc.titleAssessing aquifer vulnerability to landfill pollution using drastic method in Gauteng, South Africa
dc.typeDissertation
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