School of Geosciences (ETDs)

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Assessing aquifer vulnerability to landfill pollution using drastic method in Gauteng, South Africa
(University of the Witwatersrand, Johannesburg, 2023) Mphaphuli, Idah; Abiye, Tamiru
This study integrated the DRASTIC method and field investigations into mapping the degree of vulnerability of aquifers to landfill pollution in the Gauteng Province, which is one of the most populated provinces in South Africa. In order to investigate the aquifer vulnerability of Gauteng's heterogeneous and complex geology, the DRASTIC method was used to generate intrinsic and specific vulnerability maps. Three vulnerability classes were generated from the DRASTIC index, namely, low vulnerability, moderate vulnerability and high vulnerability, which covered 46%, 37% and 17% of the study area, respectively. The highly-vulnerable areas were associated with the karst aquifer of Malmani dolomite, permeable vadose zone, high hydraulic conductivity and loamy sand/sandy loam soil type, whilst moderately-vulnerable areas were associated with fractured/weathered aquifers, high recharge and low topography. The intrinsic vulnerability was validated using average NO3+NO2-N (nitrate + nitrite as nitrogen) and the results of water samples from field investigations conducted in Marie Louise and Robinson landfill sites. Elevated NO3+NO2-N concentration (9.85-16.03 mg/l) was observed in the highly-vulnerable areas. Water samples were collected, in order to analyse the water chemistry, stable isotopes and radioactive isotopes (tritium). Gibbs and Piper diagrams were used to evaluate the main mechanism controlling the groundwater chemistry and the dominant major ions that influence it. Pollution by leachate was detected in the Marie Louise landfill site, where the groundwater showed high tritium and ammonia concentration. The main hydrochemical facies detected in Marie Louise were Mg SO4, Ca-SO4, Na-SO4 and Na-Cl. The hydrochemical facies detected in Robinson were Na-SO4, Ca-HCO3, Na-Cl and Ca-Cl. The DRASTIC method was shown to be effective in assessing groundwater vulnerability on a regional scale, provided that there is adequate input data.
Hydrogeological assessments and investigation of inflow sources at Lumwana Copper Mine, Zambia
(University of the Witwatersrand, Johannesburg, 2023) Mbilima, Mike; Abiye, Tamiru
This Research Report presents results of integrated field and desktop-based hydrogeological investigations at the Lumwana Mine, Zambia. Groundwater occurrence in the mine poses challenges with effective mining operations and slope stability. The primary aim of this study was to establish the sources of groundwater inflows and to establish the nature of surface water and groundwater interaction within the Lumwana Mine hydro-geotechnical units. The Lumwana hydrogeological investigation has been achieved through the integration of multi-disciplinary data types, which include geology, structures, hydrochemistry, meteorological data (rainfall, temperature, humidity and evapotranspiration), environmental isotopes, dewatering pumping records, groundwater level monitoring, water temperature, general hydrogeological data and surface hydrology. The investigation has confirmed the presence of hydraulic connections between different surface water bodies such as dams, diversion channels, streams and open pit excavation, and has proven to be a useful approach in tracing the source of mine inflows. Rainfall, groundwater and surface water samples have similar δ18O and δ2H isotopic signatures thus lamenting the existence of a hydraulic link between groundwater and surface water. Recharge estimation through Water Table Fluctuation method (WTF) determined 8% of mean annual precipitation (MAP). The dominant hydrochemical facies are Ca-Mg-HCO3 and Ca-Mg-SO4. The local geology and geochemistry of the tailings are the main controllers of groundwater chemistry through rock-water interaction. The geology of the study area consists of older metamorphosed gneisses, schists, migmatites, amphibolites and granitoids. Integrated assessment of the Lumwana hydrogeological environment has enabled the development of the Lumwana Mine hydrogeological conceptual model. In the shallow, highly to moderately weathered zones, groundwater flows from south towards low topographic regions in the northwest mimicking the general topography. The hydraulic test conducted at Lumwana Mine has revealed the saprock units have higher hydraulic conductivity by several orders compared to the saprolites and the fresh bedrock, where groundwater flow is mainly controlled by the occurrence and distribution of the fracture network.