Electronic Theses and Dissertations (Masters)

Permanent URI for this collectionhttps://hdl.handle.net/10539/38012

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Start date: 2023Subject: search.filters.subject.SDG-13: Climate action

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    Nutrient and Salinity Loading Based On The Temporal And Spatial Water Quality Data In The Upper Crocodile River Basin
    (University of the Witwatersrand, Johannesburg, 2024-03) Mistry, Nikhil Jayant; Ali, K. Adam; Abiye, Tamiru
    The Upper Crocodile River Basin has undergone a drastic change through anthropogenic factors such as rapid urban growth, industrial activities, agriculture and mining in the past thirty-eight years. This has led to an increase in nutrient and salinity loads with decreasing water quality. The Upper Crocodile River Basin wastewater treatment works struggle to maintain loading rates, causing partially treated wastewater to enter the river systems that increased the salinity loads. Water chemistry and discharge data from the DWS were collected, cleaned and processed; data were summated across the necessary river channels in which they are located to determine the nutrient and salinity loads in all rivers in the Upper Crocodile River Basin. The results indicated that the Hennops, Jukskei and Crocodile Rivers are responsible for the largest nutrient and salinity loading rates. Changes in land use activities and climate over the past thirty-eight years, since 1980, have drastically impacted the rate at which nutrient and salinity loads enter into the UCRB. During the early 1980s to 1990s a significant drop was observed in nutrient and salinity loading rates, spiking in the late 1990s and early 2000s, influenced by changes in water management and climatic events like the La Niña and the El Niño phenomena. The inter-basin transfer in the early 2000s and subsequent two decades have led to an overall rise in nutrient and salinity loading rates, posing serious water quality and health risks to people in the UCRB area. Mining activities, poor landfill management and leaking tailing storage facilities have resulted in increased sulphate loading rates into the UCRB. Nitrogen loading has risen due to uncontrolled waste disposal from informal settlements, industrial activities and sewage spills in the Johannesburg region. Phosphorus loading rates have risen due to agricultural fertiliser runoff, with the Jukskei River being the largest contributor to these loads in the Upper Crocodile River Basin. The loads entering the Hartbeespoort dam during summer and winter seasons in the 2016-2018 period for sulphate is 6819.24 kg/hr, 4873.62kg/hr; for nitrogen 4179.24 kg/hr, 4021.55 kg/hr and for phosphorus 40.08 kg/hr, 34.724 kg/hr, respectively. Salinity loads entering the Hartbeespoort dam during summer and winter are 42952.87 kg/hr and 27548.39 kg/hr, respectively. According to the findings, water resource management must act quickly to improve the overall quality of the water; in the upcoming ten years, as loading rates are expected to rise exponentially as a result of increased demand and stressed water use, which will lead to poor water quality. This will pose serious health and economic risks to the people of the Upper Crocodile River Basin and the populace of South Africa.
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    Palaeoclimate Reconstruction Using Charcoal from a Mid-Holocene Stratum 4b, Wonderwerk Cave, South Africa
    (University of the Witwatersrand, Johannesburg, 2024-06-18) Hlophe, Busisiwe; Bamford, Marion
    Caves are often sources for palaeoenvironmental information in the dry interior regions of southern Africa. The Wonderwerk Cave, located in Northern Cape, is a national heritage site with a well-preserved, nearly complete record of the local Holocene LSA techno-complexes and past environmental indicators. Hence, it has the potential to provide valuable insights into past human behaviour as well as the local palaeoclimate and vegetation. This study examined wood charcoal from stratum 4b, Excavation 1 of the Wonderwerk Cave. The aim was to evaluate the taxonomic composition and the physiognomy of the charcoal to understand the environment around the cave 6.9-5.9 ka. The study also investigated the modern uses of the vegetation to infer how humans may have utilized the woody plants around them during that period. The results indicate the landscape cover included woody plants adapted to dry conditions and summer rainfall. However, the archaeological taxa identified also included two species that thrive in moist environments, Halleria lucida and Olinia ventosa, suggesting fluctuations in climate. The taxonomic composition also suggests an environment similar to the modern bushveld found near the cave. The low conductivity capacity as well as vulnerability and mesomorphy indices of the woods support the implication that the vegetation was adapted to low water availability or aridity. The cave's inhabitants likely used the identified plants for firewood, magical and medicinal purposes, and more between 6.9 and 5.9 ka.
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    Assessing aquifer vulnerability to landfill pollution using drastic method in Gauteng, South Africa
    (University of the Witwatersrand, Johannesburg, 2023) Mphaphuli, Idah; Abiye, Tamiru
    This study integrated the DRASTIC method and field investigations into mapping the degree of vulnerability of aquifers to landfill pollution in the Gauteng Province, which is one of the most populated provinces in South Africa. In order to investigate the aquifer vulnerability of Gauteng's heterogeneous and complex geology, the DRASTIC method was used to generate intrinsic and specific vulnerability maps. Three vulnerability classes were generated from the DRASTIC index, namely, low vulnerability, moderate vulnerability and high vulnerability, which covered 46%, 37% and 17% of the study area, respectively. The highly-vulnerable areas were associated with the karst aquifer of Malmani dolomite, permeable vadose zone, high hydraulic conductivity and loamy sand/sandy loam soil type, whilst moderately-vulnerable areas were associated with fractured/weathered aquifers, high recharge and low topography. The intrinsic vulnerability was validated using average NO3+NO2-N (nitrate + nitrite as nitrogen) and the results of water samples from field investigations conducted in Marie Louise and Robinson landfill sites. Elevated NO3+NO2-N concentration (9.85-16.03 mg/l) was observed in the highly-vulnerable areas. Water samples were collected, in order to analyse the water chemistry, stable isotopes and radioactive isotopes (tritium). Gibbs and Piper diagrams were used to evaluate the main mechanism controlling the groundwater chemistry and the dominant major ions that influence it. Pollution by leachate was detected in the Marie Louise landfill site, where the groundwater showed high tritium and ammonia concentration. The main hydrochemical facies detected in Marie Louise were Mg SO4, Ca-SO4, Na-SO4 and Na-Cl. The hydrochemical facies detected in Robinson were Na-SO4, Ca-HCO3, Na-Cl and Ca-Cl. The DRASTIC method was shown to be effective in assessing groundwater vulnerability on a regional scale, provided that there is adequate input data.
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    The tectonic evolution of the Bredasdorp Basin and its implications for oil and gas formation
    (University of the Witwatersrand, Johannesburg, 2023-10) Tau, Rethabile; Enslin, Stephanie; Manzi, Musa; Saffou, Eric
    The Bredasdorp Basin is an offshore rift basin located in the southernmost tip of Africa, within the larger Outeniqua Basin. Previous studies have indicated the presence of hydrocarbons, as well as structures or evidence that allude to the presence of hydrocarbons, where the basin has not yet been extensively drilled or explored. In this study, seismic attributes applied to high resolution pre-stack time migrated 3D seismic data are analyzed, in conjunction with well logs, specifically the gamma ray logs. By employing these methods, the study aims to delineate the presence of hydrocarbons and their migration, as well as deduce the evolution of the basin based on the structures observed. Using artificial neural network (ANN) to predict the lithologies and analyzing the patterns in the gamma ray logs, the stratigraphic results show that the basin begins with a marine dominated environment from the Valanginian age to Aptian age. From the Aptian to Albian age, there are consistent changes in sea level and sedimentation, caused by thermal sag and uplift. Past the Albian age to present age, the deposition environment is dominated by sandstones and coarse sediments. This is due to the evolving basin moving from a distal to a proximal environment of deposition. Using seismic attributes such as envelope attribute, edge detection and variance attribute, structures such as paleo pockmarks and fluid escape structures are identified. These identified paleo pockmarks have diameters ranging from 400m to 900m. In addition to these structures, erosive features were observed which could be classified as submarine channels or slump structures, with the dominating channel having depths of up to 1585 m. Using variance and ant-tracking, the fault structures observed of the study areas revealed two dominating phases of rifting. The first phase has horsts and grabens bounded by normal faults trending E-W, with implications that the rifting propagated N-S in this phase of rifting. This phase of rifting ends during the Aptian age. The next phase of rifting begins during the Santonian age, with the fault bound horsts and grabens trending N-S, which indicate an E-W rifting direction.