Electronic Theses and Dissertations (PhDs)

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Browsing Electronic Theses and Dissertations (PhDs) by Keyword "Karibib district"

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    Pegmatite investigations in the Karibib district, South West Africa
    (University of the Witwatersrand, Johannesburg, 1963) Roering, Christian
    The outer pegmatitie zone of variable thickness which is essentially a very coarse-grained granite consisting of larger perthite phenocrysts lying in a matrix of albite, quartz and muscovite. The inner portions of this zone may reveal a great enrichment of perthite, so much so, that it may grade into a giant perthite zone, e. g. Rubicon main ore-body; Karlsbrunn close to the Li-bearing ore zones. This outer portion of the pegmatite may also reveal a subdivision into two distinct units: an outermost zone of albite-quartz-muscovite and an inner zone of albite-perthite-quartz-muscovite. This sequence of essentially granitic crystallization is often abruptly broken by the appearance of a zone consisting essentially of cleavelandite with minor quartz and muscovite. This zone is characterized by the appearance of numerous accessory minerals often in economic quantities, e. g. beryl, columbite-tantalite-frondellite, topaz and apatite. The zone is generally of the order 1-5 feet depending on the original size of the pegmatitie and the degree of fractionation. That it is not a late replacement unit is confirmed by observations at Rubicon where corroded crystals of beryl belonging to this zone are found lying in a matrix of lepidolite and albite which is the next unit to form. The lepidolite-albite zone in fact replaces the beryl-bearing zone. The striking symmetry alone of the Rubicon body testifies to this zone preceeding in crystallization sequence the Li-ore zones. The significant fact about this zone is that it marks a distinct break in the crystallization history of the pegmatite, i. e. it marks the change from crystallization of essentially granitic components to the formation of late phase constituents, viz. Li-bearing and associated minerals. It possibly marks the break from magmatic crystallization to late-magmatic conditions when pneumatogenic and even hydrothermal processes begin to operate. The next group of minerals to form are noticeably rich in Li and are frequently associated with sugary albite. The major minerals are petalite, lepidolite and albite, while minor amounts of amblygonite also occur. There is a definite spacial relationship sequence in the formation of these minerals. Petalite crystallizes first and collects in the upper part of this unit generally forming a hood. Amblygonite, albite, quartz, may occur at the same time. Immediately below this petalite hood, and at a somewhat later stage, fine-grained lepidolite crystallizes together with albite and minor quartz. The final phase to form at this general stage is sugary albite which collects at the bottom of the still non-crystalline portion of the magma chamber. The sugary albite phase is able to behave diapirically and can intrude, brecciate, and replace any of the previously crystallized zonal constituents. Each successive stage here can assume corrosive relationships to previously consolidated units. No assessment is made as to the amount of replacement that may take place as the criterion commonly used for such diagnosis are somewhat subjective. During this entire process of complex diffusions and crystallization, silica is apparently being concentrated in the residual fractions of the pegmatite magma. The next zone to form is a cleavelandite-rich rock confined to the quartz core margin. This cleavelandite is able to vein and brecciate and corrode the immediately adjacent lying lepidolite and is often associated with minerals such as beryl, columbite, tantalite, tourmaline, topaz and apatitie. Amblygonite may also belong to this stage of mineralization though in general it tends to be associated close in time with the petalite stage of mineralization. The final stage of the crystallization sequence is the quartz core. Quartz veinlets emanating from the core have been observed to cut across adjacent lepidllite-rich and amblygonite-albite zones. Euhedral crystals of columbite and beryl at the core margin are completely surrounded by quartz. These observations may suggest that quartz, although concentrated in the centre of the dyke, probably existed in some unconsolidated state (e. g. a gel as Brotzen (1959) has suggested). The development of a gas phase at certain stages of the pegmatites consolidation history possibly accounts for the vertical fractionation found in these pegmatites. Finally details of the more important pegmatite minerals are given together with chemical analyses.