Testing and validation of coal combustion prediction indices from conventional laboratory analyses
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Date
2009-07-02T07:12:10Z
Authors
Masuku, Happing
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Abstract
This study reports on the testing and validation of
combustion prediction indices derived from the
conventional laboratory analyses of coal. This involved
the actual testing of coal samples using the pilotscale
combustion test rig, the Drop Tube Furnace (DTF),
petrographic analysis and the normal conventional
laboratory analysis. The indices covered in the study
were Fuel Ratio (FR), Hydrogen to Carbon ratio (H/C
ratio) and maceral-based indices. The anomalies
encountered in the study were also investigated.
The investigation was based on ten low-grade Bituminous
coal samples (A-J). Each of the ten samples was subdivided
into two; the bulk sample of approximately 1.2
tons was taken for the pilot-scale combustion tests and
the remainder for the laboratory bench-scale tests. A
portion of the laboratory sample was used for DTF and
petrographic analyses. All ten bulk samples were fired
in the combustion test rig. An attempt was made to keep
all major combustion parameters constant for all
samples. The fineness of all samples was kept at
approximately 70% -75μm particles and the excess oxygen
at approximately 6%. The burnout times of both the
parent feed coals and their char products were used to
test the indices.
There was no clear correlation between the burnout
times of the parent coals in the combustion test rig
and the indices obtained from the conventional
laboratory test results, viz. FR and H/C ratio. There
was also no clear correlation between the burnout times
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of chars in the DTF and the above indices. This can be
attributed to the fact that the conventional laboratory
analyses, on which these indices are based, are
performed at lower temperatures as compared with
combustion conditions in the combustion test rig and
the DTF. However, the char burnout times in the DTF
showed a strong linear correlation (R2 = 0.89) with the
Fuel Ratio obtained from DTF volatile matter, which was
corrected by subtracting the mineral volatiles. This
relationship was not obtained from the burnout of
parent coals in the combustion test rig. This proved
that the high temperature combustible volatile matter
relates better to high temperature combustion
performance in the DTF.
The petrographic nature and rank of most parent coal
samples had a strong influence on the combustion
performance in the combustion test rig. Namely, there
was a strong correlation between the burnout times of
the parent coals and the maceral-based indices, i.e.
Burnout times versus vitrinite content showed a linear
correlation (R2) of 0.91, burnout times versus
Reactivity Index (RF) showed a linear correlation (R2)
of 0.96 and burnout times versus Maceral Index (MI)
showed an exponential correlation of 0.85. However,
there was no clear correlation between the above
indices and the char burnout times in the DTF.
Of the ten coals tested, three showed consistently
anomalous correlations including burnout results, i.e.
coals E, H and J.
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The relatively slow burnout time of Coal E (1.20
seconds) in the combustion test rig was not
commensurate with the high vitrinite content of 42.2%
and the volatile matter of 22.5%. The full survey of
the analytical results indicated that Coal E, apart
from having the highest proportion of -75micron fines
in the feed sample (85%), the lowest Abrasive Index (22
mgFe), the highest Hardgrove Grindability Index (67)
and possessing a significant proportion of weathered
and oxidised particles, most notably exhibits a range
of rank that extends from Sub-bituminous to well into
the Mid Bituminous coking range of rank (0.5 to 1.3
RoVr%). This evidence indicates (a) that the coals
which fall normally in the Low Rank Bituminous C range,
have been heated relatively significant and (b) most
importantly, have passed into the range in which
vitrinite macerals become “cokified”. This infers that
the vitrinite in the higher ranking coking range would
soften, swell, become porous, fuse with other particles
and then harden. During this process the texture of the
walls of the gas pores become semi-crystalline,
developing mosaic structures (a form of semigraphitisation)
on exposure to high temperatures
Thus, due to the high vitrinite content and extended
rank into the coking range, it has been concluded that
a significant proportion of the coaly material has
become “cokified” and semi-graphitised. Such lower
rank material, which is normally highly reactive to
combustion in the presence of oxygen at lower
temperatures, becomes inert above a specific
temperature after undergoing severe molecular reordering
and resolidification. This unusual condition,
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in addition to the presence of oxidised materials in
this coal, is considered to be responsible for the
anomalously long burnout time of a supposedly reactive
coal.
Coal H exhibited a longer burnout time of 1.55 seconds
in the combustion test rig. This has been attributed to
the fact that this coal has a significant quantity of
long-term weathered and oxidised material as indicated
by the highest proportion of discoloured coaly
particles (9.2%) along with the relatively high
cracking and fissuring (20.6%) that arises with
weathering. This is commensurate with the fact that
this sample was derived from an old stockpile as
indicated in Table 3.1. The long burnout time of this
coal is considered to be due to the presence of
weathered material which gives rise to limited volatile
release, slow ignition and slower rates of combustion.
Coal J possessed the shortest burnout time in the
combustion test rig (0.75 seconds) but it also
possessed, by far the highest proportion of coaly
material exhibiting abnormal conditions (55.6% compared
to the next highest value, 37% in sample H) of which
29.6% was heat-affected and 17.4% cracked and fissured
and possibly desiccated. This sample also possessed a
low vitrinite content (11.2%), the lowest MI value
(0.028), the lowest volatile matter content (17.7%
based on proximate analyses) and the widest range of
vitrinite reflectance (0.5 to 2.2 RoVmr%) thereby
confirming the extensive levels to which the coal had
been burnt. The unexpectedly fast burnout time of what
would otherwise have been considered a relatively slow
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burning, difficult to ignite coal appears, in this
case, to be attributable to the combustion response to
high temperature exposure of the extensively heataffected,
desiccated and cracked material in the
combustion test rig. Thermal shock is therefore
considered to have taken place, namely, material such
as that described above has been known to explode and
shatter into smaller particles when exposed to instant
high temperatures. The result is the provision of small
particles with higher surface areas which leads to
rapid and efficient combustion. This process has been
identified in other similar South African coals, as
reported by Falcon (1992). This has been termed
‘deflagration’. The occurrence of the highest flue gas
temperature as reported in the combustion test rig
tests when burning this coal further confirms the
presence of higher rank (burnt) coals.
The results of this work therefore indicate that coal
combustion performance in the combustion test rig is
most closely correlated to the petrographic parameters,
i.e. vitrinite content, Maceral Index (MI) and
Reactivity Index (RI), except when coals are oxidised,
burnt, high ash or liable to potential deflagration due
to incipient cracking in the original coal.
The conventional laboratory analyses, and the Fuel
Ratio (FR) and Hydrogen to Carbon Ratio (H/C) derived
from them, cannot be correlated with coal combustion
performance in either the DTF or the large scale
combustion test rig.
Furthermore, the burnout results of the chars tested in the DTF cannot be correlated with the burnout results of the normal parent coals obtained in the combustion test rig. This is considered to be due to the differences in sample preparation prior to testing and to variations in combustion conditions between the two test units.