Effects of ozonation on cooling water systems

dc.contributor.authorMosugelo, Keneetswe Lilian
dc.date.accessioned2010-07-26T12:14:44Z
dc.date.available2010-07-26T12:14:44Z
dc.date.issued2010-07-26T12:14:44Z
dc.description.abstractCooling water systems are needed to dissipate heat. The mist from open system cooling towers has been implicated as a source of infections of Legionella pneumophila. As a result biocide is added to cooling water systems, but the addition of biocide worsens biofouling, scaling and corrosion. Increasing environmental pressure has resulted in a move away from biocides which are usually chlorine based chemicals, so that the use of ozone instead has recently been reported as a way of controlling microbiological growth. This study aims to compare the corrosion rates (using calculated and measured surface areas) of different metals exposed to chemically treated and ozone treated cooling water in an industrial cooling water system. The types of corrosion were also observed and recorded. The scales from different components of the cooling systems as well as scale from chemically and ozone treated D tower water were characterized qualitatively using X-ray diffraction (XRD), Thermo gravimetric Analysis (TGA) and Atomic Absorption Spectroscopy. The D tower is a cooling water circuit in which the cooling water is from the Vaal River. As expected, the stainless steel has the lowest corrosion rate of 0.000 milli inches/year followed by brass with 1.531 milli inches/year and lastly mild steel (2.098 milli inches/year). Water quality rather than the presence or absence of ozone determines the corrosion rate. This confirms the findings reported in the literature. Scale from chemically treated water contains many different compounds while scale from ozone treated contains only different polymorphs of CaCO3, which is present in the water source and magnesium calcite.en_US
dc.identifier.urihttp://hdl.handle.net/10539/8306
dc.language.isoenen_US
dc.subjectCooling water systemen_US
dc.subjectOzoneen_US
dc.subjectBiocidesen_US
dc.subjectBiofoulingen_US
dc.subjectCorrosion rateen_US
dc.subjectX-ray diffractionen_US
dc.subjectThermo gravimetric analysisen_US
dc.titleEffects of ozonation on cooling water systemsen_US
dc.typeThesisen_US
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