Faculty of Science (Research Outputs)
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Item Kondo effect and enhanced magnetic properties in gadolinium functionalized carbon nanotube supramolecular complex(Nature Research, 2018-05) Ncube, S.; Coleman, C.; Strydom, A.; Flahaut, E.; de Sousa, A.We report on the enhancement of magnetic properties of multiwalled carbon nanotubes (MWNTs) functionalized with a gadolinium based supramolecular complex. By employing a newly developed synthesis technique, we find that the functionalization method of the nanocomposite enhances the strength of magnetic interaction, leading to a large effective moment of 15.79µB and nonsuperparamagnetic behavior, unlike what has been previously reported. Saturating resistance at low temperatures is ftted with the numerical renormalization group formula, verifying the Kondo effect for magnetic impurities on a metallic electron system. Magnetoresistance shows devices fabricated from aligned gadolinium functionalized MWNTs (Gd-Fctn-MWNTs) exhibit spin-valve switching behaviour of up to 8%. This study highlights the possibility of enhancing magnetic interactions in carbon systems through chemical modification, moreover, we demonstrate the rich physics that might be useful for developing spin based quantum computing elements based on one-dimensional (1D) channels.Item Compositions with a fixed number of inversions(Springer, 2018-05) Knopfmacher, A.; Mays, M. E.; Wagner, S.A composition of the positive integer n is a representation of n as an ordered sum of positive integers n = a1 + a2 + ··· + am. There are 2n−1 unrestricted compositions of n, which can be sorted according to the number of inversions they contain. (An inversion in a composition is a pair of summands {ai, aj} for which i aj .) The number of inversions of a composition is an indication of how far the composition is from a partition of n, which by convention uses a sequence of nondecreasing summands and thus has no inversions. We count compositions of n with exactly r inversions in several ways to derive generating function identities, and also consider asymptotic results.Item Seasonal Pollution Levels and Heavy Metal Contamination in the Jukskei River, South Africa(MDPI, 2025-03) Mukwevho, Nehemiah; Ntsasa, Napo; Chimuka, Luke; Tshilongo, James; Mothepane H. Mabowa; Mkhohlakali, Andile; Letsoalo, Mokgehle R.Monitoring river systems is crucial for understanding and managing water resources, predicting natural disasters, and maintaining ecological balance. Assessment of heavy metal pollution derived valuable data which are critical for the environmental management and regulatory compliance of the Jukskei River. Heavy elements were evaluated in the Jukskei River for seasonal impact, potential health risks, and contamination level with concentration levels ranging from 6900 mg/kg iron (Fe) to 0.85 mg/kg cadmium (Cd) in the dry sampling season and 6900 mg/kg Fe to 0.26 mg/kg Cd in the wet season. Enrichment factor analysis indicated high contamination levels of Fe and Pb in both dry and wet seasons. Moreover, pollution indicators revealed extremely high contamination of geo-accumulation and enrichment factors in the downstream to upstream in both seasons with a mild contamination factor for mercury (Hg). Principal Component Analysis revealed anthropogenic sources of arsenic (As), Cd, and Pb due to wastewater and agricultural pesticide application while Thorium (Th), uranium (U) and Hg were attributed as a results of gold mining activities. ANOVA and Pearson correlation analysis showed a high and moderate link between As–Pb, Cd–Pd, and As–Hg, which are significantly correlated. The potential ecological risk index assessment revealed a significant impact of heavy metals on the freshwater ecosystem.Item Chemical analysis of low grade gold from mine tailings after size fractionation and acid digestion using reverse aqua regia(Nature Research, 2025-03) Chimuka, Luke; Tshilongo, James; Mashale, Kedibone Nicholine; Sehata, James; Ntsasa, Napo GodwillThe growing interest in reprocessing mine tailings for gold recovery requires a suitable quantification method that is accurate, rapid, and not harsh to the environment. Acid digestion is often used to determination of gold; however, it often faces the challenge of incomplete digestion due to the presence of minerals such as quartz, and homogeneity is compromised due to small sample masses, which can result in low bias. This study investigated a shorter acid digestion method employing reverse aqua regia, both in the presence and absence of hydrofluoric acid. Before digestion, the sample was subjected to gold depot analysis, which showed that 78% was free-milling gold and that only 0.8% was associated with pyrite, increasing the chances of accurate quantifications. Furthermore, the size screening test showed that most of the gold could be recovered on the −38 μm screen. This proposed method provided good linearity (5–100 µg. L−1) and low detection limits (0.139–0.183 µg.kg−1). The concentrations obtained by the acid digestion was 0.258 g.t−1 with the recoveries ranging between 80% and 82%, which fit the criteria set. The method also worked well for the certified reference materials (CRM), AMIS 610 (accurate value=0.068 g.t−1) and AMIS 646 (accurate value=0.166 g.t−1), which are of a similar matrix and are also lower in grade compared to the sample. The method was also evaluated for uncertainty (±value) using the bottom-up approach, and the expanded uncertainty (k=2) was reported to be 0.258±0.092 g.t−1, which was comparable to that offered by the fire assay with the ICP‒OES finish, which was 0.28±0.10 g.t−1. This implies that the acid digestion method is suitable for quantifying gold from mine tailings without large uncertainties.Item Topological rejection of noise by quantum skyrmions(Nature Research, 2025-03) Ornelas, Pedro; Forbes, Andrew; de Mello Koch, RobertAn open challenge in the context of quantum information processing and communication is improving the robustness of quantum information to environmental contributions of noise, a severe hindrance in real-world scenarios. Here, we show that quantum skyrmions and their nonlocal topological observables remain resilient to noise even as typical entanglement witnesses and measures of the state decay. This allows us to introduce the notion of digitization of quantum information based on our discrete topological quantum observables, foregoing the need for robustness of entanglement. We compliment our experiments with a full theoretical treatment that unlocks the quantum mechanisms behind the topological behavior, explaining why the topology leads to robustness. Our approach holds exciting promise for intrinsic quantum information resilience through topology, highly applicable to real-world systems such as global quantum networks and noisy quantum computers.Item The IGCP 714 Project “3GEO– Geoclimbing & Geotrekking in Geoparks”– Selection of Geodiversity Sites Equipped for Climbing for Combining Outdoor and Multimedia Activities(Springer, 2025-07) Knight, Jasper; Bollati, Irene Maria; Masseroli, Anna; Mohammed, Al Kindi,; Cezar, Lucas; Chrobak-Žuffová, Anna; Dongre, Ashish; Fassoulas, Charalampos; Fazio, Eugenio; Garcia-Rodríguez, Manuel; Matthews, Jack J.; Fraga de Araújo Pereira, Ricardo Galeno; Viani, Cristina; Williams, Mark; Amato, Giuseppe M.; Apuani, Tiziana; de Castro, Emanuel; Fernández-Escalante, Enrique; Fernandes, Magda; Forzese, Martina; Gianotti, Franco; Goyanes, Gabriel; Loureiro, Fabio; Kandekar, Avinash; Kolendrianou, Maria; Maniscalco, Rosanna; Nikolakakis, Emmanouel; Palomba, Mauro; Pelfini, Manuela; Tronti, Gianluca; Zanoletti, Enrico; Zerboni, Andrea; Zucali, MicheleThe IGCP 714 project “3GEO – Geoclimbing & Geotrekking in Geoparks” is financed by the International Geoscience Programme (IGCP) and supported by the International Union of Geological Sciences (IUGS). In this paper, we report on the results of the first phase of the project focused on the criteria to be adopted to select geodiversity sites equipped for climbing or trekking. The selection of geoclimbing sites and geotrekking routes is aimed at combining multimedia tools and outdoor activities for Geosciences promotion and conservation in UNESCO Global Geoparks, aspiring geoparks or geoparks project, and also in protected areas featuring geoheritage sites. Indeed, both outdoor activities and multimedia tools favour the pursuing of many of the United Nations Sustainable Development Goals (e.g., 3, 4, 8, 11). An international consortium of geoscientists from 12 different countries selected, through the proposed procedure, 22 geoclimbing sites, and then they also detected 30 geotrekking routes mirroring Earth geodiversity. At some test sites (geoclimbing and geotrekking) multimedia tools and digital outcrop models have been developed through different methodological approaches (e.g., Structure from Motion and Multi-View Stereo photogrammetry), to open the way to the second part of the project still in progress. These sites and the relative virtual models are herein also shown. The fnal aim of the IGCP 714 project is indeed to create an open data repository (digital outcrop models, videos, virtual tours, photos, scientific information, and interpretations) to upload data of the selected sites to mirror Earth geodiversity for different users including tourists and school groups.Item Draft genome sequence of the fungal pathogen Penicillium expansum (PPRI25879) isolated in South Africa(Elsevier, 2025-02) Chan, Wai Yin; Rauwane, Molemi; Figlan, Sandiswa; Ntushelo, KhayalethuObjectives: Penicillium expansum, a necrotrophic plant pathogen with a wide range of fruit hosts, is an important causal agent of blue mold rot. The fruit business suffers significant financial losses because of blue mold rot that occurs during fruit storage, transportation, and sale. The objective of this work was to generate a high-quality draft genome assembly of P. expansum, which will contribute to enhancing the management of blue mold, especially in stone and pome fruits, including grapes, by improving our understanding of the epidemiology of the pathogen and its interactions with the host. Data description: Here, we describe the genome sequence of Penicillium expansum isolate PPRI25879, one of the most virulent strains isolated from grapes in South Africa. Sequencing reads from P. expansum produced approximately 3.5 Gb. The assembly generated a draft genome of size 32.1 Mb, consisting of 1648 contigs, with an N50 of 508 KB. Examination of the genome completeness with Benchmarking Universal Single-Copy Orthologs (BUSCO) showed the draft genome carries 97.9% of the 746 genes in the Eurotiomycetes_odb10 database. The draft genome sequence will allow improved genomic comparisons among the most important pathogens belonging to the Penicillium genus, with the aim of improving our knowledge of their plant-pathogen interactions, population biology, and control.Item Deep-crustal layered mafic complexes in the Mesoproterozoic oceanic-arc of the Tugela Terrane, South Africa(Elsevier, 2025-03) Wilson, Allan H.Layered mafic intrusions are important in understanding the generation of continental crust in oceanic arcs. The Mesoproterozoic (c. 1200 Ma) Tugela Terrane in southeast South Africa is made up of a series of thrust slices of varied rock-types purported to have been derived in oceanic arcs prior to accretion onto the southern margin of the Archean Kaapvaal Craton. They are not ophiolites. Mafic intrusions in two adjacent thrust slices are known as the Tugela Rand and Mambula Complexes. Both intrusions are intensely layered on scales of centimetres to several tens of metres but clear cyclic units are not apparent and crystal fractionation is limited indicating these were open systems with magma chamber through-flow. Tugela Rand is made up of dominantly olivine-bearing rocks ranging from dunite and pyroxenite to gabbro. In contrast, Mambula is dominantly gabbroic with only rare olivine-bearing rocks and is more evolved with layers of titaniferous-magnetite. Primary magmatic structures in both complexes include graded bedding, slumping and erosion features. Relatively high pressure of formation is indicated by the aluminous nature of the pyroxenes and corona textures by reaction between plagioclase and olivine. Chromitites in Tugela Rand range from massive to podiform with the rare orbicular variety indicating complex controls on chromite accretion. They include the high-Al compositional variety. There are no other similar chromitite occurrences in South Africa. The complexes, together with their enclosing rock-types, draw striking parallels with the lower arc crust observed in the late Cretaceous Kohistan arc complex in NE Pakistan. The Tugela Rand Complex shares many similarities with the Chilas Complex in that terrane, while the Mambula Complex is considered to be a more evolved derivative of the same magma. This study shows that generation of juvenile continental crust formation in mature island arc systems may have been firmly established by the Mesoproterozoic.Item Spatio-temporal trends in daily precipitation extremes over the Enkangala escarpment of South Africa: 1961–2021(Springer, 2025-02) Abubakar, Hadisu Bello; Scholes, Mary C.; Engelbrecht, Francois A.The Intergovernmental Panel on Climate Change in its Sixth Assessment Report reported that increases in extreme weather events can already be detected in every region in the world. For eastern southern Africa the report provides evidence of an increasing trend in extreme precipitation events, but more research is needed to understand how this change is manifesting over regions as diverse as South Africa’s eastern escarpment and northern Mozambique. This study evaluates the trends in extreme precipitation over the Enkangala Escarpment, part of South Africa’s eastern escarpment, over the period 1961 to 2021. Daily precipitation data covering 22 stations with fewer than 10% missing values over 61 years were obtained from the South African Weather Service. A total of twelve extreme events precipitation indices were computed using the ClimPACT2 package, and a time series trend analysis was performed using the Trend Free Whitening Mann Kendal test and a field significance test. The results indicate significant increasing trends in nine out of the twelve extreme events indices that were investigated. The three indices which have shown significant decreasing trends include Consecutive Wet days (CWD) at (0.03 day/year total annual rainfall (PRCPTOT) (0.61 mm/decade) and the annual count of days when precipitation≥10 mm (R10mm) of 0.32 days/decade. Indices such Rx1 days, Rx3 days and Rx5 days exhibited increasing trends of 0.2 days/decade each. Other indices with an increasing trend are CDD (3.6 day/decade), R20mm (0.2 days/decade) and R30mm (0.2 days/decade). The R95p (11.2 mm/decade) and R99p (6.0 mm/decade) indices, and Simple Daily Intensity Index(0.4 mm/decade) also exhibit positive trends over the study period. Overall the analysis is indicative of a change in the nature of rainfall over the Enkangala escarpment of South Africa, with annual rainfall totals, the number of consecutive wet days and the frequency of events with smaller thresholds such as 10 mm/day decreasing, but with extreme events of larger thresholds occurring more frequently. That is, when it rains, it tends to rain more intensely than in the past. The use of a field significance test was useful to formalise when relatively small but spatially homogeneous trends detected at separate weather stations yield statistical significance. The findings of the paper are relevant to decision and policy in multiple of socio-economic sectors active in South Africa’s eastern escarpment.Item A Technique to Solve a Parabolic Equation by Point Symmetries that Incorporate Initial Data(Springer, 2025-03) Jamal, Sameerah; Maphanga, RivoningoIn this paper, we show how transformation techniques coupled with a convolution integral can be used to solve a generalised option-pricing model, including the Black–Scholes model. Such equations are parabolic and the special convolutions are extremely involved as they arise from an initial value problem. New symmetries are derived to obtain solutions through an application of the invariant surface condition. The main outcome is that the point symmetries are effective in producing exact solutions that satisfy a given initial condition, such as those represented by a call-option.