3. Electronic Theses and Dissertations (ETDs) - All submissions
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Item An experimental and thermodynamic study of iron catalyst activation and deactivation during Fischer Tropsch synthesis(2016) Gorimbo, JoshuaOne gram amounts of a commercial iron based catalyst were loaded into three reactors and reduced with syngas, hydrogen and carbon monoxide respectively. Fischer Tropsch experiments on the three reactors in parallel with the same operating conditions, namely 60 mL(NTP)/min, 1 bar gauge and 250 °C, were then conducted for extended periods and the gaseous products analysed. Initially (for about 150 hours) the three catalysts had quite different carbon monoxide conversions. After this until about 1000 hours the conversions were similar. However the distribution of products for the differently reduced catalyst was significantly different. This suggested that permanent changes had been done to the catalysts by the different reducing conditions. To try to understand what the differences during the reduction process might be, a thermodynamic analysis of the solid phases after reduction was done. Unfortunately because all the thermodynamic data for the possible carbides was not available this analysis was of limited value. However it did suggest that hydrogen reduced catalyst might contain more oxides and the carbon monoxide reduced catalyst might contain more carbides. Some electron microscope and XRD experiments supported these ideas and might account for the different selectivities of the differently reduced catalysts. Runs after about 5000 hours were done at different flowrates (60, 30 and 15 mL(NTP)/min) of syngas and again the big effects were on differences between the selectivities, the big effects being when going to the lowest flowrate. After about 12000 hours regeneration of the catalysts was then done by oxidation and then the same syngas reduction on all the catalysts. Runs were then done at different pressures (1, 10 and 20 bar gauge) and again selectivities were the biggest effects that remained, clearly showing the initial reduction had made permanent changes. In the final section some novel plots were used to try to make more sense of the results. It was shown that for all the catalysts the Olefin to Paraffin ratios were tied to each other under all conditions and that they were mainly a function of the conversions with much higher values at low conversions.Item Thermodynamic analysis techniques for the study of combustion in compression ignition engines with application to methanol/dimethyl ether fuelling(1991) Cipolat, DanieleThermodynamic analysis techniques for the study of combustion in compression ignition engines were developed and refined. The techniques were validated against test runs of diesel fuelling, and were then applied to the almost unexplored case of combustion of aspirated dimethyl either (DME) acting as ignition promotor and supplementary fuel, and injected methanol as main fuel. Combustion chamber pressure versus crank angle data were captured for single engine cycle on normal fuelling (methanol and DME), fuelling with DME alone and pure motoring (no fuel) all at essentially identical engine conditions. These data were analysed by a number of mutually complementary techniques.Item An ethanol conversion study over titania supported catalysts(1992) Chen, Yao-KuanThe ethanol conversion to hydrocarbons over acidic catalysts proceeds with high activity and selectivity and has hence generated considerable interest. In this thesis an investigation of the use of a range of supports, loaded with metals as potential catalysts for the ethanol transformation reaction, is reported. In particular, Ti02 was investigated as a support and the addition of a secondary component to the catalyst was examined with respect to product selectivities. [Abbreviated Abstract. Open document to view full version]Item Carbothermic reduction of alumina into a metallic solvent phase(1998) Caizergues, DerekExperiments have been conducted at around 17000C to determine the whether carbothermic reduction of alumina is possible at these temperatures. Total pressure of the system was reduced to around 30 kPa and various metallic solvents such as copper, nickel, iron and tin were used to dissolve the metallic aluminium produced. The use of a solvent (and hence decreasing the activity of metallic aluminium) and a lower pressure are thermodynamic requirements to increase the extent of reduction under a given set of conditions. This enables the use of lower temperatures than are required under atmospheric conditions. The highest recovery of aluminium was achieved with the nickel solvent decreasing in order from iron, copper and tin. This ranking was also in accord with the extent of deviation from ideality in the respective binary solutions of these solvents with aluminiur, The nickel-aluminium system displays the largest negative deviation from ideality whereas the till, aluminium system showed a positive deviation. The rate and extent of the reduction was found to be highly dependent on temperature and pressure. The pseudo first order reaction rate was found to be the primary order for the reduction of aluminium in all the solvents used. It is also suggested that the reduction rate was controlled primarily by chemical reaction rate father than by transport processes. This is due to the extreme sensitivity of the rate and extent of the reaction to temperature.Item High temperature packed bed thermal storage for solar gas turbines(2016) Klein, PeterSolar powered gas micro-turbines present opportunities for off-grid power generation. Due to the intermittent nature of the solar energy supply, existing Solar Gas Turbine (SGT) plants employ hybridisation with fossil fuels to generate dispatchable power. In this work sensible heat and latent heat storage solutions are investigated as a means of increasing the solar share of a SGT cycle, thus reducing the consumption of diesel fuel. The sensible heat storage concept was based on a pressurised packed bed of spherical ceramic particles, using air as the heat transfer fluid. An axisymmetric, two-phase heat transfer model of the system was developed, based on the continuous solid phase approach. The model was successfully validated against experimental data from a packed bed of alumino-silicate particles over the temperature ranges of gas turbine cycles (350-900 °C and 600-900 °C). The validated numerical model was utilised to conduct a parametric design study of a six hour (1.55 MWhth) storage system for a gas micro-turbine. The results show that a high storage efficiency and high utilisation factor can be achieved when combining sensible heat storage in alumina with fossil fuel hybridisation, with somewhat lower values without hybridisation. An analysis of different inventory geometries showed that a packed bed of spherical particles is best suited to pressurised sensible heat storage. The latent heat storage concept was based on a pressurised packed bed of Encapsulated Phase Change Material (EPCM) particles. Sodium sulphate was identified as a suitable phase change material for the gas turbine cycle. The sensible heat storage model was extended to account for intra-particle temperature gradients and phase change within the particles. The intra-particle phase change model was validated against published experimental data for a single EPCM sphere heated and cooled by convection. The full EPCM storage model was further successfully validated against experimental data from a packed bed of macro- encapsulated sodium sulphate particles with alumina shells, up to a temperature of 950 °C. A comparison of the two storage concepts for a 7 m3 bed shows that a packed bed of en- capsulated sodium sulphate particles would have a 36% lower energy storage capacity than a bed of solid alumina particles. This is due to the limited melt fraction in the EPCM bed when a temperature limit is placed on the base. Increasing the packed bed volume to 10.5 m3 would provide a comparable thermal performance to the 7 m3 solid alumina bed, at a 12% lower storage mass. A hybrid three-layer packed bed is proposed to increase the volumetric energy storage density. Modelling shows that this concept could provide a small increase of 5.3% in the amount of energy discharged above 850 °C, compared to the solid alumina particles only.Item Vacuum boiling of water in a steam jet refrigeration system(2014-05-30) Mitchley, Stephen RonaldThis experim ental project aims to describe the influencing factors in the vacuum boiling o f w ater in w ater vapour refrigeration system s Testing was conducted using a 2 kW three-stage steam je t ejector system, w ith barom etric condensers, as the com pression device. Three direct-contact evaporators were used to investigate the boiling phenom ena. T hese were : a through-flow evaporator w here heal and mass transfer rates were established for boiling m echanism s at various positions within the evaporator; a vertical cylinder where small quantities o f w ater were subjected to rapid decom pression and the effects m easured, and a sim ple channel for photographic studies o f the process. Boiling in direct-contact water vapour systems is described herein The vacuum boiling proo ss was found to be controlled by a com bination o f the w ater surface tem perature and the hydrostatic pressure gradient, these being governed by the w ater vapour flow geometry between the w ater surface and ejector suction and convective heat transfer below the boiling region. The contributions o f the various boiling regim es to the total heat transfer are discussed. Heat and mass transfer coefficients and their applicability to evaporator design are presented