Browsing by Author "Sebola, Mandy-Jane Tlou"

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The influence of beneficiation on the petrographic, geochemical & physical properties of metallurgical coal from the Soutpansberg Coalfield, South Africa
(2024) Sebola, Mandy-Jane Tlou
The Soutpansberg Coalfield hosts South Africa's Hard Coking Coal (HCC) reserves, however it is relatively understudied and underdeveloped compared to other coalfields in the country. The Makhado Project, located within the central Tshipise sub-basin of the Soutpansberg Coalfield, is the current focus for the re-establishment of Hard Coking Coal production in South Africa by MC Mining Limited. This study investigated the properties of a 10% ash metallurgical coal product derived from the beneficiation of a wide diameter drill core (LD57) from the Soutpansberg Coalfield, South Africa. The research was conducted in two parts. Part one of the research entailed testing of LD57 by means of drop shatter, dry tumble and wet tumble tests to estimate the breakage expected during the transportation, handling and processing of the coals. Float-sink testing was conducted to determine suitable washability conditions for the production of a primary metallurgical product of 10% ash content. The fine size fraction (1+0.25 mm) floats yielded the desired 10% ash metallurgical product hence, the fine size fraction floats were selected for further characterisation in terms of their petrographic and geochemical properties in Part two of the research. These fine-sized float samples were analysed for their petrographic composition, coal quality (proximate analyses and total sulphur), mineralogy (X-Ray Diffraction), trace element and rare earth element (REE) composition (X-Ray Fluorescence and Inductively Coupled Plasma Mass Spectrometry), and carbonization (Free Swelling Index) properties. The breakage tests indicate partitioning of daughter particles will be predominantly into coarse particles, 60% on average. The washability analysis shows clean coal for the desired 10% ash metallurgical product could theoretically be obtained in the 1+0.25 mm size fraction of the Makhado seams, with yields up to 78% at 1.55-1.70 g/cm3 . Simple to moderate separation conditions at ± 0.10 NGM are predicted under these separation parameters. The fine float samples (metallurgical product) are classified as Medium Rank Bituminous C coals (0.88 %RoV) and are highly vitrinitic in composition (97 vol% mmf). All 1+0.25 mm samples reported FSI values of 9. However, further beneficiation of these samples is necessary for minor reduction of the sulphur content, alkali content and phosphorus content to acceptable industry standards for metallurgical coal. Trace element and REE concentrations in the ashed fine float samples are highly enriched relative to the crustal abundance values. Furthermore, all but samples SU and SMU were found to be a promising source of REE as the total REE concentrations exceeded the 1000 ppm cut-off grade
Weathering of coals from the Waterberg and Limpopo Coalfields, South Africa
(2018) Sebola, Mandy-Jane Tlou
This study investigated the effects of weathering on coal from the Waterberg and Limpopo Coalfields with the aim to understand how the quality of these coals changed during the early stages of oxidative weathering under dry and wet conditions. Coal was sampled from freshly exposed seams in both coalfields to provide, as best as possible, an un-weathered parent sample from which the extent of weathering could be determined. The Middle Seam was sampled from the Limpopo Coalfield whereas Benches 3, 5, 9B and 11 were sampled from the Waterberg Coalfield. This suite of samples enabled investigation into the impact of weathering on coals with similar properties but originating from different localities (Waterberg Coalfield vs Limpopo Coalfield), as well as coal with different properties originating from the same locality (Benches 3, 5, 9B and 11). Furthermore, the impact of weathering was studied on the coking properties (Middle Seam vs Bench 3) and heating properties using thermal coal (Bench 5). The experiment was conducted over a duration of six months during which a subset of the samples from each coalfield was kept dry in perforated containers, whilst the remaining samples were frequently watered to simulate the effect of rainfall under controlled settings. The particle size of the samples was reduced to -1mm to enhance the surface area for a more rapid reaction. Thereafter the samples were left to weather outdoors, on the roof of a building at the University of the Witwatersrand, Johannesburg. The average temperature conditions affecting the samples during the research period ranged between 9.40-27.23 °C. Several conventional coal analyses (proximate analysis, ultimate analysis, coal petrography, XRF & XRD) were used in conjunction with advanced techniques (EMPA, FE-SEM & Raman spectroscopy) to detect early signs of weathering on the organic and inorganic coal constituents. The impact of weathering on technological properties of the coal samples were investigated using calorific value, thermogravimetry and free swelling index. After six months of weathering, very small changes were observed in the coal quality due to weathering. The chemical and petrographic composition of the coals remained relatively unaffected by weathering, whereas the mineral matter and swelling properties of the coals were more susceptible to weathering under wet conditions. The alteration of minerals was more evident in the samples that were watered throughout the experiment, irrespective of their original locality. These samples were characterized by the precipitation of gypsum on the surface of the wet coals, as well as the appearance of red calcite grains. Analysis of the red calcite grains revealed rare growth rims associated with the precipitation of siderite. Although the findings of the thermogravimetric analysis suggested that the reactivity of the thermal coal had been slightly reduced by weathering (especially by weathering under wet conditions), the CV trend for this coal did not appear to be impaired. Hence, the effect of weathering on the heating properties of this sample are inconclusive. Ultimately, after 6 months of exposure to weathering the quality of the coals remained very similar to their fresh parent samples. However, the swelling properties of the coking coals from each coalfield were diminished. Therefore, caution is advised for the stockpiling of the coking coals outdoors, which should not exceed longer than 4-6 months, especially in the case of the Waterberg coking coal.