Riba, Mpho Mahlatse2023-11-212023-11-212022Magwede, Chimwemwe Edith. (2023). The Role of Chiefs in Land Management in Peri-Urban Customary Areas Of Blantyre, Malawi: The Case of Mpemba. [Master's dissertation, University of the Witwatersrand, Johannesburg]. WIReDSpace. https://hdl.handle.net/10539/40119. https://hdl.handle.net/10539/37049https://hdl.handle.net/10539/37049A dissertation submitted in fulfilment of the requirements for the degree of Master of Science in Environmental Sciences to the Faculty of Science, University of the Witwatersrand, Johannesburg, 2022South Africa’s coal-fired power plants (CFPPs) produce about 34.4 million tons of fly ash (FA) per annum, as a by-product of the coal combustion process, which is stockpiled adjacent to these CFPPs. This FA contains traces of heavy metals (HMs), as a result it is a potential environmental hazard. The purpose of this study was, therefore, to establish the effects of (‘FA’) on the growth of maize (Zea mays L.), as well as its potential commercial use in agriculture due to its nutrient content, instead of maintaining the status quo. Another aim of the study was also to determine the phytoextraction abilities of the HMs (Mn, Cr, Ba and Mo) from contaminated soils by the maize plants. The study was conducted by planting maize seeds in five soil substrates with 0 %, 20 %, 40 %, 55 % and 60 % FA treatment, on mass basis. The ANOVA indicated that there were significant differences when comparing most of the mean stem length, number of leaves, root length and the mean mass of total plant dry biomass, across all the FA treatments, after 122 days of growth. The mean stem lengths after 122 days of growth were 86.67  20.55 cm, 148.33  13.87 cm, 154.17  18.10 cm, 121.17  14.99 cm and 149.50  24.20 cm for maize plants grown in 0 % , 20 %, 40 %, 55 % and 60 % FA treatments, respectively. The mean number of leaves were 12  1.87, 16  2.34, 18  2.83, 12  1.87 and 14  1.79 across all treatments, respectively. The key finding was that the growth of these plants improved with the amount of FA in the soil, with the plants that were grown in the 40 % FA treatment yielding the best results. The same observation was made with the root length and the mean masses of total plant biomass (roots, stems and leaves). Another important finding was that the accumulation of the HMs (Mn and Cr) in the plants increased, across the FA treatments, while their concentrations in the soil decreased across the FA treatments. The accumulation of Ba and Mo in the plants also increased, across the FA treatments, while Ba remained slightly constant and Mo increased in the soil. This indicated that the maize plants can potentially remediate Mn and Cr contaminated soils, through phytoextration, but are retained in the root system.en©2022 University of the Witwatersrand, Johannesburg. All rights reserved. The copyright in this work vests in the University of the Witwatersrand, Johannesburg. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of University of the Witwatersrand, Johannesburg.Fly AshMaize plant growthHeavy MetalsSDG-8: Decent work and economic growthDissertationUniversity of the Witwatersrand, Johannesburg