Majors Appendix table A1: Major element compositions wt.% USE USE Tugela Rand Complex Sample* Anal 10 anal 11 anal 12 TR33A* TR549 TR550 TR552 TR553 TR8 103.13 TR8 110.16 TR8 110.16 TR8 113 TR8 114.8 TR8 116.73 TR8 131 TR8 169.5 TR8 199.8 TR8 204 TR8 21.5 TR8 215.7 TR8 225 TR8 231.6 TR8 238.6 TR8 245.65 TR8 40 TR8 49 TR8 62 TR8 71.5 TR8 84 TR8 92.2 TR8 96.69 TR82/10 TR82/11 TR82/12A TR82/13-2 TR82/14 TR82/14A TR82/14A TR82/15-1 TR82/15A TR82/16-1 TR82/17 TR82/17 TR82/17 TR82/17A TR82/17hons TR82/18-1 TR82/18-2 TR82/19-2 TR82/20-2 TR82/21-2 TR82/21A TR82/22 TR82/23* TR82/23 TR82/24 TR82/25 TR82/26 TR82/27 TR82/28 TR82/28? TR82/29 TR82/30 TR82/31 TR82/32 TR82/35 TR82/36 TR82/37 TR82/38* TR82/39* TR82/4 TR82/40 TR82/41 TR82/42 TR82/45 TR82/46 TR82/47 TR82/48 TR82/49 TR82/50 TR82/51 TR82/52 TR82/53 TR82/55 TR82/56 TR82/57 TR82/58 TR82/59 TR82/61 TR82/62 TR82/63 TR82/64 TR82/67 TR82/69 TR82/70 TR82/71 TR82/72 TR82/73 TR82/74 TR82/75 TR82/76 TR82/77 TR82/78 TR82/79 TR82/80 TR82/81 TR82/82 TR82/83 TR82/84* TR82/85 TR82/87 TR82/88 TR82/89 TR82/90 TR82/91 TR82/92 TR82/93 TR82/94 TR82/95 TR82/96 TR82/97 TR82/98 TR82/99 Area Central South Mid east N. Central N. Central N. Central N. Central N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east N east South South South South South South South South South Central S. west S. west S. west N. east N.east N.east N.east N.east N.east N. central N. central N. central North North North North North North North North North North North North E.central E.central E.central East East East East East S.west S.west S.west S.west S.west W.central W.central central W.central Central W.central W.central W.central S.west Wall rocks East East E.Central North N.central N.central West West E.central E.central E.central E.central E.central E.central W.central W.central W.central North North N.Central N.Central West West West Central West Central Central South East S.central S. Central South S. Central Domain D1 D5 D2 D2 east D1 D1 D1 D2 D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D5 D5 D4 D4 D4 D4 D4 D4 D4 D1 D4 D3 D3 D2 D2 D2 D2 D2 D2 D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2A D2 D2 D2 D3 D3 D2 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D1 D2 D1 D3 D3 D3 D3 D3 D3 D3 D4 D2A D2A D2A D2 D2 D2 D2 D3 D3 D3 D3 D2 D2 D2 D2A D2A D2A D2A D3 D3 D3 D1 D3 D1 D1 D4 D2D3 D3 D3 D4 D3 Rock-type Weh troct webs border Dunite Pyrox Weh Weh Pyrox Pyrox Pyrox Pyrox Dunite Dunite Pyrox Dunite Pyrox Pyrox Pyrox Pyrox Dunite Pyrox Dunite Dunite Pyrox Pyrox Pyrox Pyrox Pyrox Pyrox Pyrox Troct troct Harz Ol gab Ol gab Anorth ol gab ol gab Lherz Wehr Ol gab Dunite ol Gab Troct Ol gab Webst Webst F. dunite wehrlite Webst Webst Ol. Webst Ol. Webst. Gab.nor. Lherz. Lherz. Harz. Webst Webst. Webst. ol webst Gabbro Gabbro Feld.pyrox. Feld.pyrox. Wehrl Wehrl Feld. Pyrox Ol. Gab Troct Ol. Gab Ol. Gab Ol. Clinop Ol.gab Dunite Dunite Ol.clinop Wehrl Ol.gab Ol.webst Dunite Webst Dunite Ol.gab F.Wehr Ol.gab Ol.clinop Diorite Gab F.pyrox Wehrl Ol.norite Harz Ol. Pyrox Ol.clinopy Webst Webst Wehrl Ol.webst Orthopy Pyrox Gabbro Ol.clino Ol.gab Ol.gab F.webst Ol.ortho Ol. Amph.* Ol.nor ol.web ol.gab ol.gab wehrl Ol.gab Dunite Dunite F.pyrox Ol.webst Ol.gab F.dunite Ol.gab Ol.webst Setting Field Field Field Field Field Field Field Field Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Core TR8 Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field SiO2 42.29 49.99 51.62 45.49 41.77 50.15 42.65 46.25 52.45 52.46 49.87 53.2 44.59 42.37 45.82 40.35 52.66 51.49 50.8 52.43 41.5 45.17 41.82 40.4 53.17 52.28 53.26 51.86 53.11 52.4 52.36 46.32 47.33 43.48 47.72 49.43 49.84 48.58 52.52 42.75 43.5 49.78 36.55 50.22 49.99 36.92 52.56 51.74 42.71 41.25 49.73 50.88 50.21 50.18 51.88 43.72 52.83 45.15 52.97 51.43 50.2 50.84 51.81 52.44 51.23 49.29 42.48 44.91 51.15 49.69 47.48 50.92 49.89 49.69 49.73 36.81 34.37 49.63 46.23 49.83 43.05 42.29 52.82 42.86 50.33 42.56 49.91 50.17 56.86 50.26 52.55 43.7 51.67 42 47.32 50.87 51.62 51.98 49.57 52.24 52.9 52.95 52.02 51.83 51.07 50.66 50.31 43.74 50.3 47.26 49.8 47.76 50.03 43.71 49.98 44.18 40.68 52.02 49.26 50.5 42.98 48.88 49.37 Al2O3 0.86 18.42 5.96 8.12 1.8 4.1 5.47 3.11 4.68 3.68 3.08 3.66 2.33 1.37 2.56 2.63 4.55 4.6 19.25 4.61 1.49 3.2 1.58 1.83 6.83 3.99 4.42 4.96 7.77 4.6 4.72 21.29 25.35 7.9 17.11 21.6 30.61 22.04 16.96 7.57 6 18.35 8.82 18.2 18.42 8.66 4.07 4.02 4.67 1.87 7.2 8.05 4.47 4.54 15.71 2.73 4.08 3.19 4.23 5.82 5.27 3.91 17.2 17.65 10.11 9.39 5.67 5.37 8.92 16.56 20.64 17.09 18.03 4.88 17.67 8.13 10.15 8.24 5.95 12.1 5.49 0.86 4.74 0.86 18.34 3.73 17.92 5.9 18.44 17.39 4.62 6.64 17.05 1.91 4.38 4.62 5.96 4.09 3.81 4.03 4.37 10.97 18.2 4.18 22.31 16.83 7.86 2.3 8.51 20.53 5.22 19.32 16.79 6.02 19.59 0.73 1.04 8.3 14.58 16.74 7.1 18.65 6.99 Fe2O3 1.46 0.56 0.72 1.43 1.35 0.59 1.26 0.91 0.94 1.16 1.27 1.13 1.42 1.62 1.29 1.55 0.77 0.78 0.52 0.96 1.64 1.38 1.63 1.68 0.96 1.22 1.02 0.83 0.93 0.92 0.87 0.55 0.39 1.29 0.75 0.51 0.1 0.56 0.69 1.19 1.33 0.56 1.26 0.56 0.56 1.26 0.92 0.95 1.38 1.64 0.75 0.74 1.01 1.42 0.65 1.64 1.1 1.4 1.09 1.08 0.75 1.07 0.62 0.73 0.91 0.81 1.26 1.49 1 0.73 0.74 0.55 0.61 0.72 0.5 1.25 1.37 0.69 0.99 0.69 1.37 1.46 1 1.51 0.41 1.43 0.5 0.78 0.71 0.7 0.87 1.19 0.67 1.62 1.06 0.75 0.72 0.79 1.26 1.06 1.11 0.81 0.46 0.55 0.39 0.52 0.85 1.49 1.1 0.61 0.76 0.53 0.48 1.19 0.44 1.42 1.44 0.84 0.49 0.55 1.14 0.6 0.81 FeO 11.79 4.55 5.85 11.55 12.18 5.28 11.31 8.2 7.64 9.43 10.27 9.19 11.5 13.13 10.42 12.58 6.25 6.34 4.19 7.77 13.31 11.18 13.18 13.64 7.8 9.87 8.3 6.76 7.56 7.47 7.05 4.43 3.15 10.45 6.05 4.09 0.85 4.53 5.56 9.62 10.75 4.56 10.24 4.56 4.57 10.24 7.44 7.7 11.17 13.25 6.05 5.96 8.17 11.49 5.24 13.25 8.9 11.36 8.81 8.74 6.06 8.64 5 5.9 7.36 6.58 10.2 12.08 8.13 5.92 6.02 4.43 4.97 5.81 4.02 10.16 11.08 5.58 8.03 5.61 11.11 11.79 8.06 12.21 3.33 11.55 4.02 6.3 5.75 5.67 7.02 9.63 5.44 13.11 8.6 6.06 5.85 6.4 10.17 8.59 9.03 6.53 3.76 4.47 3.17 4.21 6.91 12.06 8.89 4.92 6.12 4.31 3.85 9.61 3.56 11.52 11.68 6.8 3.94 4.45 9.26 4.89 6.56 TFe2O3 14.56 5.61 7.22 14.27 13.54 5.87 12.57 9.11 9.43 11.64 12.68 11.34 14.2 16.21 12.87 15.53 7.72 7.83 5.18 9.6 16.43 13.81 16.28 16.84 9.63 12.19 10.24 8.34 9.33 9.22 8.71 5.47 3.89 12.9 7.47 5.06 1.04 5.59 6.87 11.88 13.28 5.63 12.64 5.63 5.64 12.64 9.19 9.51 13.79 16.37 7.47 7.36 10.09 14.19 6.47 16.37 10.99 14.03 10.88 10.79 7.49 10.67 6.18 7.29 9.09 8.12 12.6 14.92 10.04 7.31 7.43 5.47 6.13 7.18 4.97 12.54 13.68 6.89 9.91 6.92 13.72 14.56 9.96 15.08 4.11 14.27 4.97 7.78 7.1 7 8.67 11.89 6.72 16.19 10.62 7.49 7.22 7.9 12.56 10.61 11.15 8.07 4.64 5.52 3.91 5.2 8.53 14.89 10.98 6.08 7.56 5.32 4.76 11.87 4.4 14.22 14.42 8.4 4.87 5.5 11.43 6.03 8.1 MnO, 0.16 0.1 0.17 0.2 0.23 0.12 0.18 0.15 0.2 0.22 0.22 0.22 0.22 0.21 0.21 0.21 0.71 0.18 0.1 0.2 0.18 0.21 0.23 0.22 0.18 0.21 0.21 0.18 0.18 0.2 0.18 0.08 0.05 0.19 0.11 0.09 0.01 0.08 0.14 0.18 0.2 0.09 0.14 0.09 0.1 0.14 0.18 0.19 0.2 0.22 0.16 0.15 0.19 0.34 0.12 0.22 0.21 0.21 0.21 0.22 0.16 0.24 0.11 0.13 0.17 0.15 0.18 0.22 0.18 0.13 0.1 0.11 0.11 0.15 0.1 0.18 0.16 0.14 0.16 0.14 0.2 0.16 0.21 0.13 0 0.2 0.1 0.16 0.12 0.12 0.19 0.17 0.13 0.17 0.18 0.16 0.17 0.18 0.22 0.21 0.21 0.16 0.09 0.12 0.06 0.1 0.18 0.22 0.22 0.08 0.16 0.08 0.09 0.19 0.08 0.12 0.14 0.17 0.1 0.11 0.16 0.1 0.15 MgO 42.31 11.05 19.53 25.21 41.21 20.35 33.96 30.23 23.4 29.46 32.2 28.4 36.56 41.02 33.67 40.82 20.16 19.89 11.23 24.5 41.6 34.63 40.56 40.09 23.96 29.92 25.29 20 23.88 22.78 21.64 14.3 8.16 29.91 16.29 8.31 0.69 9.7 9.88 31.07 33.1 10.59 39.71 10.59 11.05 39.7 22.94 21.93 36.56 40.47 18.59 18.17 22.52 15.22 12.64 34.59 28.93 34.85 24.66 17.85 20.35 18.91 10.33 9.25 16.18 17.02 36.64 30.81 13.89 10.4 11.32 10.57 12.45 19.45 10.72 40.48 40.34 17.94 26.33 14.77 34.66 42.31 22.81 41.72 10.6 38.49 11.08 20.47 4.56 10.67 22.64 32.89 9.91 40.42 27.18 18.92 19.53 21.31 32.16 25.54 28.69 20.18 11.28 19.83 7.24 11.41 16.61 36.59 14.79 14.04 20.23 14.04 13.5 32.84 11.36 42.16 43.38 20.98 13.7 10.5 32.65 11.75 19.37 CaO 0.12 12.75 14.2 6.73 0.07 17.17 4.22 10.17 9.98 2.64 2.82 3.55 3.02 0.22 5.68 1.12 15.38 14.99 12.55 8.06 0.13 2.93 1.15 1.36 6.71 2.5 6.97 14.56 6.54 10.8 12.14 11.34 12.6 5.5 10.53 13.22 12.51 12.1 11.92 5.49 4.53 13.14 0.2 13.15 12.75 0.2 11.07 11.47 3.27 0.15 15.67 15.02 12.89 15.92 12.33 2.84 2.55 2.13 6.91 12.68 15.24 14.38 12.31 11.62 12.06 15.35 2.59 4.08 13.2 13.79 11.89 12.9 11.75 16.68 15.16 0.33 0.25 15.73 10.55 14.4 3.77 0.12 9.3 0.12 14.76 1.74 14.66 15.01 7.31 12.15 10.25 5.43 11.92 0.19 10.6 17.45 14.2 13.51 2.03 6.5 2.73 7.16 12.34 18.05 12.07 13.79 14.08 2.39 13.05 11.09 15.4 11.89 12.6 4.79 13.26 0.12 0.17 9.62 15.5 14.23 5.42 12.58 14.35 Na2O 0.05 1.97 0.49 1.11 0.05 0.34 0.08 0.22 0.62 0.01 0.12 0.4 0.46 0 0.06 0 0.27 0.39 1.7 0.64 0.38 0.08 0.03 0.36 0.45 0.1 0.63 0.65 0.42 0.67 0.39 1.62 1.98 0.69 1.39 2.17 2.6 2.13 2.38 0.53 0.18 1.88 0.1 1.88 1.97 0.1 0.26 0.26 0.37 0.1 0.62 0.9 0.67 0.75 1.65 0.33 0.3 0.06 0.36 0.64 0.42 0.52 1.88 2.04 1.04 0.93 0.24 0.47 1.55 1.71 1.7 1.73 1.82 0.5 1.7 0.28 0.06 1 0.52 1.48 0.33 0.05 0.6 0.25 1.7 0.2 1.73 0.94 4.37 2.05 0.45 0.27 2.26 0.27 0.46 0.54 0.49 0.51 0.43 0.28 0.14 1.06 1.35 0.34 2.92 1.34 0.97 0.24 1.14 1.68 0.38 1.38 1.68 0.39 2.02 0.19 0.87 0.73 1.14 1.97 0.25 1.91 0.54 K2O 0.06 0.01 0.1 0 0 0 0 0 0.01 0 0.01 0 0.02 0 0 0.02 0.08 0.05 0.02 0 0 0.02 0.01 0 0 0.02 0.03 0 0 0.02 0.14 0.18 0.06 0.12 0.17 2.56 0.11 0.16 0.02 0.04 0.05 0 0.05 0.06 0 0.02 0 0.03 0 0.03 0.05 0.02 0 0.07 0.02 0.02 0.01 0.02 0.04 0.03 0 0.11 0.11 0.06 0.03 0.03 0.09 0.52 0.22 0.21 0.08 0.08 0.02 0.13 0 0 0.03 0.02 0.08 0.02 0 0.03 0 0.08 0.01 0.09 0.05 0.9 0.14 0 0.02 0.1 0 0 0 0.01 0.01 0.02 0 0.02 0.05 0.08 0.02 0.12 0.07 0.07 0.02 0.08 0.11 0 0.06 0.07 0.03 0.15 0 0.05 0.04 0.04 0.08 0.05 0.08 0.01 TiO2 0.05 0.16 0.32 0.29 0.12 0.32 0.07 0.17 0.33 0.23 0.18 0.23 0.12 0.09 0.18 0.14 0.4 0.42 0.22 0.3 0.08 0.18 0.11 0.11 0.28 0.22 0.29 0.39 0.23 0.34 0.35 0.14 0.13 0.49 0.17 0.26 0.15 0.14 0.32 0.31 0.18 0.16 0.08 0.17 0.16 0.09 0.31 0.35 0.16 0.12 0.35 0.37 0.38 1.22 0.32 0.15 0.24 0.19 0.37 0.46 0.36 0.49 0.27 0.31 0.49 0.46 0.19 0.28 1.01 0.59 0.22 0.27 0.19 0.4 0.28 0.1 0.09 0.4 0.29 0.38 0.17 0.05 0.34 0.04 0.18 0.09 0.26 0.35 0.63 0.36 0.32 0.09 0.26 0.01 0.22 0.32 0.32 0.27 0.14 0.29 0.23 0.21 0.19 0.32 0.12 0.21 0.74 0.14 0.75 0.12 0.37 0.14 0.17 0.11 0.12 0.02 0.03 0.25 0.22 0.24 0.11 0.19 0.36 P2O5 0.01 0.02 0.01 0.03 0.02 0.01 0.02 0.01 0.01 0.01 0.02 0.02 0.02 0.03 0.02 0.02 0.01 0.01 0.02 0.02 0.03 0.02 0.03 0.04 0.01 0.01 0.02 0.02 0.01 0.01 0.02 0.03 0.03 0.02 0.02 0.04 0.03 0.02 0.02 0.04 0.03 0 0 0 0.02 0 0.02 0.01 0.02 0.02 0.02 0.02 0.02 0.03 0.01 0.02 0.01 0.02 0.02 0.02 0.02 0.01 0.02 0.01 0.01 0.02 0.03 0.04 0.2 0.05 0.02 0.02 0.01 0.02 0.01 0.03 0.03 0.02 0.02 0.02 0.03 0.01 0.02 0.02 0.02 0.01 0.02 0.02 0.22 0.04 0.02 0.01 0.02 0.02 0.01 0 0.01 0.02 0.01 0.02 0.02 0.01 0 0.02 0.03 0.02 0.05 0.02 0.04 0.02 0.01 0.02 0.07 0.03 0.01 0.01 0.02 0.02 0.02 0.01 0.02 0.02 0 Cr2O3 0.82 0.1 0.49 0.23 1 0.94 0.53 0.48 0.6 0.55 0.43 0.59 0.34 0.25 0.48 1.32 0.45 0.49 0.25 0.81 0.53 1.2 0.5 0.74 0.47 0.48 0.55 0.63 0.42 0.54 0.55 0.04 0.22 0.35 0.15 0.15 0.02 0.08 0.1 0.42 0.38 0.1 1.87 0.1 0.13 1.87 0.35 0.39 0.48 0.88 0.44 0.43 0.49 0.02 0.14 0.51 0.48 0.75 0.49 0.41 0.69 0.5 0.08 0.03 0.4 0.34 0.37 0.17 0.04 0.22 0.18 0.09 0.12 0.7 0.24 2.16 1.73 0.71 0.55 0.24 0.44 0.82 0.17 0.63 0.21 0.32 0.18 0.56 0.03 0.08 0.21 0.41 0.03 0.05 0.55 0.64 0.49 0.64 0.89 0.55 0.49 0.28 0.14 0.91 0.05 0.17 0.43 0.47 0.34 0.05 0.71 0.13 0.2 0.18 0.21 0.48 0.71 0.18 0.37 0.1 0.68 0.14 0.42 NIO 0.33 0.01 0.03 0.14 0.29 0.09 0.25 0.13 0.1 0.14 0.17 0.14 0.22 0.28 0.18 0.32 0.09 0.08 0.05 0.12 0.27 0.2 0.26 0.31 0.11 0.19 0.13 0.12 0.11 0.11 0.1 0.06 0.03 0.16 0.03 0.02 0 0.03 0.02 0.22 0.2 0.03 0.03 0.03 0.03 0.03 0.05 0.06 0.34 0.06 0.07 0.07 0 0.04 0.19 0.19 0.29 0.12 0.04 0.09 0.02 0.03 0.02 0.06 0.07 0.27 0.21 0.03 0.03 0.03 0.02 0.04 0.09 0.03 0.08 0.15 0.03 0.18 0.33 0.05 0.28 0.03 0.23 0.02 0.09 0.01 0.03 0.05 0.2 0.01 0 0.14 0.1 0.03 0.1 0.24 0.09 0.12 0.05 0.04 0.08 0.01 0.04 0.06 0.26 0.03 0.05 0.08 0 0.05 0.19 0.05 0.34 0.32 0.07 0.04 0.03 0.23 0.04 0.07 TOTAL 100.25 99.74 99.4 100.63 100.09 99.47 100 100.04 100.95 99.99 100.65 100.74 100.81 100.61 100.57 101.06 101.71 99.74 100.93 100.44 101.14 100.38 101.1 100.78 100.93 100.99 101.1 100.99 101.16 100.83 100.39 100.34 99.61 100.49 100.44 100.06 99.97 100.1 100.66 99.4 100.42 99.29 99.01 99.6 99.81 99.21 100.19 99.07 101.01 100.31 99.67 100.8 101.12 101.13 100.8 100.21 99.84 99.61 100.26 99.43 99.64 99.54 99.77 100.24 100.08 100.44 100.16 100.22 99.82 100.04 100.55 98.79 100.07 99.11 100.29 99.91 99.62 100.19 99.79 99.76 100.82 100.25 100.14 100.63 99.99 100.57 100.49 100.8 99.92 99.66 99.19 100.65 99.47 99.77 100.7 100.43 99.4 99.81 100.95 99.4 100.06 100.43 99.94 100.72 99.57 99.37 99.12 99.94 99.23 100.56 99.24 99.66 99.57 99.27 100.83 101.29 100.53 100.01 99.4 99.51 100.05 99.83 99 Total based on 0.9 total Fe as FeO; * TR8 is drill core with metres Extrem S Extrem S S S w contact S central Extrem S S central S central NE NE NE NE NE ?? NE NE next granite NE N N N N N N N ext N N Extr E Extr E Extr E Extr E Extr E Extrem S Extr E SW W dunit mass W dunit mass cent W cent W cent W cent W cent W cent W cent dunite cent W cent W cent W cent W E contact SE SE SE Extr N Central N Central N Central N Central N Central N Central N NW NW NW NW N central N central Extr N Extr N NW NW central W central W central W central W central W cent dunit cent dunit SE central central central S central Mambula Complex Sample* WMB82/1 WMB82/3 WMB82/6 WMB82/7 WMB82/9 WMB82/10 WMB82/11 WMB82/13A WMB82/13B WMB82/13C WMB82/13D WMB82/13E WMB82/14 WMB82/15 WMB82/19 WMB82/21 WMB82/23 WMB82/25 WMB82/26 WMB82/27 WMB82/28 WMB82/29 WMB82/30 WMB82/31 WMB82/34 WMB82/35 WMB82/37 WMB82/38 WMB82/39 WMB82/41 WMB82/43 WMB82/44 WMB82/45 WMB82/46 WMB82/47 WMB82/48 WMB82/52 WMB82/53 WMB82/55 WMB82/56 WMB82/57 WMB82/60 MB91/1 MB91/2 MB001 MB002 MB003 MB004 MB004A MB005 MB006 MB007 MB008 MB009 MB010 MB011 MB011A MB012 MB013 MB014 MB015 MB016 MB017 MB018 MB019 MB020 MB021 MB022 MB023 MB024 MBH 26.31 MBH 42.94 MBH 51.3 MBH 72.46 MBH 91 MBH 94.76 MBH 119.44 MBH 121.67 MBH 122.12 MBH 144.2 MBH 154.74 MBH 157.1 MBH 159.03 MBH 162.67 MBH 171.41 MBH 184.63 MBH 188.02 MBH 193.12 MBH 193.27 MBH 194.63 MBH 197.25 MBH 214.18 MBH 224.85 MBH 225.34 MBH 225.61 MBH 228.35 MBH 229.67 MBH 240.22 MBH 247.18 MBH 251.64 MBH 254.53 MBH 255.53 MBH 258.65 MBH 262 MBH 262.65 MBH 262.84 MBH 265.04 MBH 267.09 MBH 269.31 MBH 270.7 MBH 281.49 MBH 281.75 MBH 287.15 MBH 302.58 MBH 303.57 MBH 305.02 MBH 309.57 MBH 309.85 MBH 315.68 MBH 318.38 MBH 319.11 MBH 343.48 MBH 349 MBH 352.16 MBH 357.06 MBH 358.2 MBH 361.9 MBH 373.05 MB035 MB037 MB044 MB045 MB046 Setting Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Core MBH Report Report Report Field Field Field Field Field Core m 26.31 42.94 51.3 72.46 91 94.76 119.44 121.67 122.12 144.2 154.74 157.1 159.03 162.67 171.41 184.63 188.02 193.12 193.27 194.63 197.25 234.28 224.85 225.34 225.61 228.35 229.67 240.22 247.18 251.64 254.53 255.53 258.65 262 262.65 262.84 265.04 267.09 269.31 270.7 281.49 281.75 287.15 302.58 303.57 305.02 309.57 309.85 315.68 318.38 319.11 343.48 349 352.16 357.06 358.2 361.9 373.05 SiO2 51.53 49.96 49.48 54.07 27.83 11.96 49.41 43.62 44.42 49.02 49.56 48.54 48.35 49.25 48.85 45.53 49.39 49.93 52.22 49.85 49.38 13.36 44.28 43.73 45.02 48.47 51.85 43.44 45.1 23.95 49.88 54.58 50.74 49.79 49.76 50.01 51.02 47.25 11.26 15.73 12.85 50.31 49.64 48.36 50.29 48.07 12.89 15.66 15.44 49.27 12.47 3.73 49.56 50.46 6.16 50.02 50.31 48.45 49.82 3.08 48.48 49.75 22.22 56.54 17.14 50.12 14.87 4.86 52.66 47.3 50.36 43.99 41.93 44.52 40.93 41.83 41.56 46.02 44.7 42.37 23.89 15.8 39.99 49.41 43.8 51.21 41.15 49.93 50.31 49.85 49.76 42.71 46.7 48.13 54.52 43.25 43.82 42.86 41.11 51.11 49.71 50.02 49.41 42.55 49.21 49.92 49.24 50.18 53.57 54.65 50.39 41.4 40.66 53.92 48.88 38.53 18.31 11.2 13.04 46.23 47.59 41.09 43.04 40.32 50.5 51.09 54.26 52.98 47.56 50.01 10.1 47.78 52.7 49.29 11.31 53.7 Al2O3 16.46 6.24 5.1 27.48 10.77 7.62 16.48 12.31 13.25 9.43 23.34 27.69 7.08 6.66 19.65 16.82 4.43 4.16 29 4.61 4.22 10.14 21.59 13.07 21.67 14.48 28.39 4.87 4.51 10.13 5.74 22.72 21.11 4.95 4.94 17.62 19.54 17.79 7.58 8.38 8.35 6.16 19.78 17.99 19.63 19.87 9.38 8.92 9.4 7.57 8.62 6.22 22.34 6.49 6.93 6.06 6.78 18.31 6.01 6.05 17.19 7.45 9.07 15.97 9.04 8.28 8.13 7.18 28.57 18.85 21.52 22.31 22.99 23.15 22.18 21.96 21.67 16.36 15.53 21.6 11.45 9.23 18.25 16.61 20.49 12.88 21.43 7.99 9.08 9.03 7.69 22.69 18.04 19.04 23.51 20.77 15.17 22.21 16.23 18.91 8 8.47 8.11 20.56 6.94 7.36 6.52 9.19 24.22 25.92 8.26 21.35 22.27 23.29 18.77 15.47 10.3 9.07 8.97 20.09 21.12 21.65 21.7 18.29 21.02 11.25 23.63 20.61 17.66 16.11 7.92 5.58 29.39 8.63 8.64 22.45 Fe2O3 0.86 1.29 1.43 0.18 4.07 6.52 1.13 1.57 1.55 1.39 0.55 0.34 1.49 1.29 0.7 1.52 1.42 1.44 0.06 1.37 1.44 6.17 1.75 1.95 1.7 1.35 0.18 2.11 1.96 4.61 1.36 0.33 0.76 1.38 1.34 0.96 0.87 1.28 6.73 6.18 6.48 1.42 0.72 0.87 1.19 1.31 6.28 5.94 5.94 1.31 6.36 7.74 0.91 1.34 7.25 1.39 1.38 1.12 1.42 7.84 1.15 1.23 5.01 1 5.66 1.21 6.03 7.43 0.12 1.35 0.95 1.83 2.01 1.64 2.08 2.12 2.13 1.48 1.75 2 4.38 6.04 2.31 1.26 2.02 0.99 2.09 1.24 1.17 1.2 1.28 1.91 1.5 1.42 0.45 1.84 1.88 1.9 2.22 0.88 1.23 1.23 1.25 1.91 1.32 1.3 1.36 1.22 0.32 0.22 1.27 2.12 2.07 0.4 1.24 2.47 5.56 5.96 6.34 1.39 1.19 2.15 1.8 2.19 0.89 1.05 0.47 0.59 1.27 1.41 41.02 1.26 0.09 1.24 6.23 0.39 FeO 6.95 10.47 11.59 1.42 32.96 52.84 9.16 12.74 12.58 11.27 4.43 2.78 12.02 10.43 5.66 12.33 11.55 11.67 0.49 11.12 11.65 49.97 14.2 15.78 13.74 10.96 1.45 17.11 15.87 37.33 11.04 2.68 6.14 11.14 10.85 7.79 7.03 10.39 54.39 50.1 52.45 11.48 5.81 7.01 9.67 10.6 50.87 48.14 48.08 10.6 51.55 62.7 7.34 10.83 58.72 11.26 11.15 9.06 11.47 63.42 9.34 9.93 40.58 8.1 45.88 9.78 48.76 60.14 0.94 10.92 7.73 14.83 16.24 13.3 16.87 17.16 17.24 11.97 14.15 16.18 35.44 48.89 18.68 10.19 16.39 8.01 16.94 10.07 9.5 9.7 10.38 15.44 12.14 11.48 3.67 14.9 15.23 15.42 18 7.11 9.98 9.92 10.1 15.44 10.66 10.52 10.99 9.89 2.62 1.82 10.28 17.13 16.75 3.22 10.01 20.03 45.01 48.24 51.35 11.25 9.61 17.44 14.55 17.73 7.19 8.46 3.79 4.74 10.3 11.4 24.3 11.34 0.85 11.2 56.07 3.55 TFe2O3 8.58 12.93 14.31 1.76 40.7 65.25 11.31 15.73 15.53 13.92 5.47 3.43 14.85 12.88 6.99 15.22 14.26 14.41 0.6 13.73 14.39 61.71 17.53 19.49 16.97 13.53 1.79 21.13 19.6 46.1 13.63 3.31 7.58 13.76 13.4 9.62 8.68 12.83 67.18 61.86 64.77 14.18 7.18 8.66 11.94 13.09 62.82 59.44 59.38 13.09 63.65 77.42 9.07 13.38 72.51 13.9 13.77 11.19 14.17 78.32 11.53 12.27 50.11 10 56.65 12.08 60.22 74.27 1.16 13.49 9.54 18.31 20.06 16.42 20.83 21.19 21.29 14.78 17.48 19.98 43.77 60.38 23.07 12.59 20.24 9.89 20.92 12.43 11.73 11.98 12.82 19.07 14.99 14.18 4.53 18.4 18.81 19.04 22.22 8.78 12.32 12.25 12.48 19.07 13.17 12.99 13.57 12.21 3.23 2.24 12.7 21.16 20.69 3.98 12.36 24.73 55.58 59.57 63.41 13.89 11.87 21.53 17.97 21.89 8.88 10.45 4.68 5.86 12.6 0.94 12.45 62.32 3.95 MnO, 0.17 0.3 0.32 0.01 0.28 0.31 0.16 0.19 0.19 0.26 0.07 0.04 0.27 0.29 0.11 0.15 0.33 0.34 0.01 0.33 0.35 0.22 0.1 0.22 0.1 0.19 0.02 0.32 0.33 0.3 0.31 0.06 0.13 0.33 0.33 0.13 0.12 0.14 0.31 0.28 0.3 0.3 0.11 0.13 0.21 0.23 0.29 0.29 0.29 0.27 0.3 0.33 0.09 0.3 0.35 0.31 0.3 0.15 0.31 0.37 0.21 0.28 0.3 0.19 0.29 0.26 0.31 0.33 0.01 0.2 0.11 0.09 0.09 0.09 0.1 0.1 0.11 0.16 0.17 0.12 0.23 0.31 0.14 0.14 0.1 0.21 0.11 0.28 0.26 0.25 0.28 0.1 0.15 0.16 0.07 0.11 0.18 0.1 0.17 0.12 0.26 0.26 0.27 0.12 0.29 0.28 0.29 0.25 0.06 0.04 0.27 0.11 0.1 0.07 0.13 0.19 0.28 0.29 0.29 0.12 0.11 0.11 0.1 0.15 0.1 0.21 0.08 0.1 0.14 0.3 0.23 0.24 0.01 0.25 0.29 0.07 MgO 7.99 14.34 15.62 0.26 6.53 4.94 6.9 12.48 11.84 12.43 4.12 2.21 13.31 13.79 10.53 6.76 15.32 16.09 0.15 15.36 16.06 6.05 1.93 7.38 2.08 8 0.56 13.46 14.9 6.19 14.93 2.79 5.76 14.95 14.92 6.04 5.48 5.79 4.56 5.13 4.66 15.74 9.76 10.88 4.58 4.76 4.83 5.15 4.88 13.24 4.68 2.93 3.06 14.87 3.95 15.26 14.99 5.89 15.19 3.52 9.31 13.22 6.48 5.09 5.81 12.97 5.55 3.75 0.3 5.36 4.2 1.75 1.3 1.77 1.55 1.86 2.04 6.4 6.52 2.31 5.7 4.57 3.73 7.99 2.2 10.35 2 13.44 12.46 12.57 13.58 1.59 6.1 5.88 3.97 3.29 7.42 1.78 5.78 5.69 13.61 12.79 13.37 3.04 14.23 13.94 14.24 12.65 3.15 1.98 13.51 2.28 1.9 3.59 6.01 6.02 5.26 5.17 4.94 4.37 3.94 2.25 2.35 4.47 4.74 11.69 3.74 4.58 5.57 5.52 2.97 14.48 0.23 12.39 4.5 3.56 CaO 12.47 15.09 14.39 10.11 6.67 2.09 12.2 11.33 11.42 13.19 12.56 13.58 14.89 15.97 11.76 12.32 15.82 14.8 11.71 15.59 14.78 3.25 8.31 11.87 8.42 12.03 12.14 14.78 13.91 5.59 14.85 10.77 10.51 15.37 16.14 12.76 10.84 12.36 2.01 2.74 2.16 13 11.17 12.23 9.89 10.73 3.11 3.52 3.27 14.51 2.83 0.03 10.85 14.26 0.48 13.69 13.07 12.08 13.78 0.02 10.83 15.11 5.22 8.97 3.84 15.04 3.6 0.38 12.02 10.14 9.52 8.21 7.96 8.98 8.07 8.06 8.32 12.62 12.25 8.55 6.05 3.18 8.57 10.24 7.55 13.19 8.2 15.03 14.6 15.17 14.73 8.47 9.66 9.22 9.12 8.88 10.59 8.33 9.33 11.06 14.82 15.04 15.21 8.7 15.14 15.05 15.53 14.3 10.49 9.55 15.15 8.7 8.55 10.29 9.86 9.82 4.39 2.19 3.29 11.01 11.2 8.52 9.02 9.7 10.77 13.19 8.17 11.72 12.55 12.86 0.63 16.79 12.22 13.95 2.72 10.88 Na2O 2.83 1.12 0.8 5.67 1.58 0.24 3.07 1.91 2.2 1.56 3.43 3.27 1.13 0.82 2.54 2.6 0.57 0.38 4.37 0.62 0.48 0.6 4.26 2.47 4.15 2.73 4.96 0.66 0.53 1.24 0.8 5.14 3.6 0.67 0.67 3.33 4 3.19 0.26 0.4 0.24 0.8 2.86 2.3 3.84 3.41 0.56 0.51 0.59 1.32 0.34 0 4 1.02 0 0.8 1.11 3.1 0.88 0.02 2.25 1.08 0.8 3.09 0.47 1.17 0.52 0 4.71 3.96 3.96 4.02 3.67 3.76 4.1 3.54 3.49 2.94 2.31 3.44 1.58 0.66 3.67 3.02 3.74 2.53 3.55 1.41 1.4 1.24 1.14 3.66 3.32 3.22 5.08 3.84 2.67 3.74 2.76 3.99 1.43 1.18 1.33 3.12 1.3 1.04 0.98 1.41 4.23 5.02 1.24 3.07 3.87 4.42 3.74 2.66 0.92 0.53 0.53 3.63 3.3 3.43 3.99 3.24 4.05 1.77 4.7 3.75 2.8 0.94 0.2 0.52 4.17 1.37 0.44 4.4 K2O 0.21 0.05 0.02 0.56 0.13 0.04 0.2 0.56 0.58 0.09 0.93 0.61 0.11 0.06 0.14 0.14 0.01 0.01 1.61 0.01 0.01 0.06 0.47 0.19 0.44 0.28 0.35 0.01 0.01 0.11 0.04 0.52 0.51 0.03 0.02 0.28 0.35 0.26 0.02 0.04 0.04 0.04 0.16 0.15 0.15 0.12 0.05 0.06 0.05 0.09 0.06 0.02 0.37 0.05 0.01 0.05 0.07 0.25 0.06 0.01 0.29 0.07 0.07 0.94 0.06 0.11 0.03 0.03 0.2 0.26 0.44 0.46 0.63 0.36 0.44 0.45 0.42 0.26 0.26 0.38 0.15 0.17 0.57 0.32 0.48 0.27 0.41 0.09 0.12 0.09 0.06 0.45 0.54 0.35 0.35 0.34 0.25 0.33 0.42 0.81 0.09 0.08 0.08 0.7 0.07 0.06 0.06 0.12 0.53 0.49 0.08 0.44 0.5 0.48 0.31 0.28 0.14 0.37 0.05 0.39 0.39 0.33 0.4 0.25 0.32 0.13 0.9 0.39 0.27 0.05 0.01 0.04 0.25 0.11 0.07 0.36 TiO2 0.54 1.02 1.14 0.29 8.29 12.71 1.21 2.29 2.22 1.51 0.52 0.49 1.32 1.26 0.25 1.89 2.21 1.06 0.06 1.1 1.06 9.5 3.33 3.71 3.1 1.71 0.3 3.35 2.91 9.49 1.03 0.28 0.72 1.08 1.1 1.18 0.95 1.72 12.4 10.87 11.97 0.95 0.22 0.31 0.67 0.77 11.39 11.12 11.25 1.12 12.01 15.2 1.4 0.99 14.97 1.01 0.98 1.51 1.1 14.71 1.1 0.98 9.64 0.35 10.19 0.97 11.49 14.4 0.16 1.53 1.15 2.74 3.27 2.51 3.28 3.17 3.2 1.91 2.32 3.17 7.12 10.07 3.29 1.18 3.05 0.74 3.14 0.97 0.91 0.96 0.97 3.04 1.84 1.7 0.21 2.63 2.65 3.25 3.28 0.75 0.96 0.97 0.99 2.83 1.05 1.02 1.07 0.92 0.19 0.11 0.98 3.25 3.15 0.26 1.33 3.73 9.19 10.16 10.64 1.82 1.61 3.22 2.7 3.21 0.97 0.72 0.24 0.41 1.73 0.96 11.7 1.34 0.11 1.03 11.37 0.3 P2O5 0 0.01 0.01 0.02 0 0 0.01 0 0 0.01 0.01 0 0.01 0.01 0 0 0.02 0.01 0.02 0.01 0.01 0 0.01 0.01 0.01 0.01 0.02 0.01 0.01 0 0.01 0.01 0.01 0.01 0 0.01 0.02 0.01 0 0 0 0 0.01 0 0.43 0.41 0 0 0 0.01 0 0 0.01 0.01 0 0.01 0.01 0.01 0.01 0 0.01 0.01 0 0.02 0 0.01 0 0 0.02 0.26 0.02 0.02 0.01 0.02 0.02 0.02 0.01 0.01 0.01 0.02 0.01 0.01 0.04 0.02 0.05 0.02 0.01 0.02 0.01 0.02 0.02 0.02 0.01 0.01 0.02 0.02 0.01 0.02 0.02 0.01 0.02 0.02 0.02 0.02 0.02 0.02 0.03 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.01 0.01 0.01 0.01 0.01 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.44 0.02 0.62 0.02 0.02 0.03 0.02 0.02 Cr2O3 0.02 0 0 0.02 0.02 0.04 0.01 0.03 0.02 0.01 0 0 0.01 0 0.04 0.02 0.01 0.01 0.02 0 0 0.03 0.01 0.02 0.01 0.07 0 0.05 0.07 0.04 0 0 0.01 0.01 0 0.02 0.02 0.02 0.05 0.04 0.05 0.01 0.02 0.04 0.01 0.02 0.04 0.04 0.05 0 0.06 0.04 0.01 0.01 0.04 0.01 0.01 0.02 0.01 0.04 0.03 0.01 0.03 0.02 0.05 0.01 0.04 0.05 0.01 0.01 0.01 0.02 0.02 0.02 0.04 0.02 0.02 0.01 0.02 0.03 0.03 0.06 0.01 0.02 0.02 0 0.03 0 0.02 0.02 0.02 0.02 0 0.01 0 0.01 0.01 0.02 0.01 0.01 0 0.01 0.01 0.01 0 0 0.01 0.01 0.01 0.01 0.02 0.03 0.01 0.02 0 0.02 0.05 0.03 0.06 0 0.02 0.02 0.01 0.01 0.01 0.12 0.01 0.02 0.06 0 0.01 0.06 0 NIO 0.01 0 0 0 0 0.01 0.01 0.02 0.01 0 0 0 0.01 0 0.02 0.01 0 0 0 0 0 0.01 0 0 0.01 0.01 0 0.01 0.02 0.01 0 0 0.01 0 0 0 0 0.01 0.02 0.02 0.01 0 0.02 0.02 0 0 0.02 0.01 0.01 0 0.01 0.01 0 0 0.01 0 0 0 0 0.02 0.01 0 0.01 0.01 0.01 0 0.01 0.02 0 0 0 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.03 0.02 0.01 0 0.01 0 0.01 0 0 0.01 0.01 0.01 0.01 0.01 0 0.01 0.01 0.01 0.01 0.01 0 0 0 0.01 0 0 0 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0 0.01 0.02 0.03 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.03 0 0.01 0.01 0 0 0.02 0 TOTAL 100.04 99.89 99.91 100.09 99.14 99.33 99.95 99.05 100.29 100.18 99.53 99.55 100 99.83 100.24 100.1 101.08 99.89 99.71 99.97 99.44 99.36 100.24 100.4 100.45 100.29 100.22 100.17 100.13 98.98 100 99.88 100.01 99.7 100.07 100.15 100.25 100.21 99.59 99.9 99.55 100.21 100.27 100.29 100.56 100.3 99.71 99.36 99.26 99.32 99.28 98.95 99.94 100.63 98.86 99.87 100.16 99.95 100.07 99.09 100.21 99.12 99.43 100.28 98.44 99.93 99.34 98.57 99.72 100.15 99.97 100.28 100.13 100.12 99.66 100.3 100.22 100.15 100.01 100.18 96.07 99.01 99.26 100.4 99.9 100.41 99.07 100.47 99.83 100.1 99.91 100.1 100 100.62 100.96 99.89 99.89 99.97 99.35 100.46 100.12 100 100.14 99.01 100.24 100.52 100.32 100.16 99.42 99.84 101.47 99.91 99.86 99.99 100.3 99.23 99.44 93.25 99.52 100.33 100.11 100.25 99.69 99.58 100.59 99.73 100.02 99.91 100.29 99.58 99.7 100.05 99.51 101.75 99.69 Total based on 0.9 total Fe as FeO; *MBH is drill core with metres Trace elements TUGELA RAND ICP-MS TRACE ELEMENTS Context Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Drill core Field Field Field Field Field Field Field Field Field Field Field Field Field Field m drill core 103.13 110.16 110.2 113 114.8 131 204 215.7 225 231.6 238.6 40 49 62 71.5 84 69 Field sample TR 82/13 TR 82/16 TR 82/21 TR 82/27 TR 82/30 TR 82/32 TR 82/39 TR 82/55 TR 82/56 TR 82/58 TR 82/69 TR 82/71 TR 82/83 TR 82/84 TR 82/87 TR 82/89 TR 82/90 TR 82/92 TR 82/94 TR 82/96 TR 82/98 TR549 TR550 TR552 TR553 TR82/11 TR82/14A TR82/15 TR82/21A TR82/42 TR82/46 TR82/50 TR82/53 TR82/61 TR82/74 TR82/75 TR82/80 TR82/82 TR82/91 Li 2.26 2.85 1.231 1.178 1.67 1.764 4.906 0.168 3.919 4.504 1.437 0.86 1.785 3.269 1.212 1.542 1.71 0.142 2.136 2.027 1.946 0.391 0.703 2.125 1.565 0.638 1.227 0.833 0.623 1.291 1.32 1.538 3.148 -0.036 1.324 0.236 1.31 1.142 0.692 1.321 0.853 0.807 1.755 2.203 7.311 1.456 1.612 0.674 3.439 2.83 4.21 1.574 0.911 1.347 2.235 1.717 P 43.276 63.012 25.737 18.943 28.24 32.313 194.4 39.936 31.694 45.914 43.803 19.965 53.922 126.768 26.491 31.282 47.762 37.973 27.098 22.001 38.697 48.596 19.591 42.827 26.424 29.704 19.404 34.113 33.921 49.824 36.121 47.759 34.337 57.536 41.933 59.065 36.545 41.168 16.813 28.384 30.534 32.411 103.57 60.233 56.482 59.412 47.177 76.535 44.35 34.647 967.135 48.21 30.698 66.673 161.896 47.514 Sc 15.134 11.798 47.066 33.904 30.919 38.777 33.288 4.849 29.169 36.599 4.27 58.057 12.831 46.913 50.378 23.444 13.503 4.188 39.665 34.962 21.792 9.751 51.017 9.189 32.539 42.788 27.061 20.269 27.527 14.744 21.721 51.826 34.482 5.813 13.826 6.375 40.274 28.295 25.388 56.912 33.119 50.953 4.663 12.944 35.018 55.007 60.542 3.873 45.754 57.857 15.149 21.979 41.104 14.734 57.019 19.515 Ti 968.783 908.975 2112.761 1948.236 1557.715 2716.629 3318.703 170.249 1110.422 1551.028 51.868 1908.162 693.687 4093.89 2097.267 955.311 537.288 80.157 1370.89 1393.557 1073.216 476.706 1773.083 299.959 857.713 1639.739 1164.388 784.067 1073.656 525.092 763.597 1977.03 1391.193 301.264 676.673 359.393 1616.539 1123.33 1454.73 2061.634 1230.716 1867.544 807.969 800.58 1847.372 2067.742 2251.279 438.09 2089.005 1948.435 3388.307 682.403 1506.146 682.211 4067.948 682.309 V 65.653 58.915 175.513 157.054 121.238 185.42 160.016 23.361 86.053 115.764 6.2 196.944 58.693 260.059 194.049 78.886 49.304 17.701 126.544 106.529 73.53 50.495 164.384 34.224 96.439 187.086 116.451 100.215 134.584 63.312 87.748 230.396 162.672 41 99.68 46.06 165.71 129.334 151.697 233.718 136.099 209.24 30.877 46.462 126.055 189.379 202.949 83.993 162.252 168.414 106.488 93.484 172.785 54.95 279.391 58.582 Cr 826.797 1632.906 2793.444 2966.154 438.29 2536.051 1293.248 2990.939 1319.062 1101.561 242.25 4334.773 2609.991 2137.157 4576.196 1203.288 992.625 2628.251 1069.905 562.369 799.738 5896.338 6142.183 2659.946 2989.621 3341.132 3108.535 2298.695 3131.769 1730.565 2377.096 2636.225 3960.637 2280.419 4870.726 2251.558 3011.487 2894.389 3086.162 3707.919 2630.392 3227.487 1445.81 488.657 574.663 2822.885 4687.836 12517.387 1486.916 1052.681 123.041 4381.748 3511.088 247.197 2841.017 1338.913 Co 86.727 116.658 64.191 103.178 50.349 78.743 43.065 136.446 52.577 76.204 145.476 56.259 140.744 88.339 85.184 62.487 126.608 136.027 101.028 81.37 58.939 144.84 52.397 120.805 87.449 63.104 90.195 96.838 78.731 122.497 99.267 46.957 63.354 137.439 105.27 118.766 73.88 103.259 75.981 59.125 70.648 60.02 34.213 44.705 70.482 54.495 60.177 184.269 48.727 69.874 27.911 103.511 75.158 30.264 51.562 38.98 Ni 246.857 1229.912 433.715 782.538 210.289 429.355 233.977 1706.846 273.593 179.128 1503.65 673.214 1605.746 213.63 577.337 340.286 1165.191 2023.077 499.657 203.909 274.381 1780.659 684.454 1625.271 851.281 649.68 944.909 1028.458 853.679 1349.619 1099.883 515.557 771.435 1510.609 1156.196 1472.006 716.683 1287.176 796.489 759.943 703.526 667.459 270.668 273.526 116.896 509.523 695.698 1847.643 198.001 350.427 79.454 1598.455 677.454 100.414 448.074 345.568 Cu 95.884 217.993 98.221 310.05 107.217 223.213 135.599 121.424 74.115 97.828 102.464 430.393 254.094 38.667 283.674 89.43 18.487 13.111 110.173 143.242 81.153 73.373 169.928 296.818 58.385 209.62 298.13 455.556 278.455 229.112 29.924 202.984 242.439 135.789 181.006 117.706 208.368 406.704 259.939 287.84 177.924 251.13 67.812 39.656 105.257 255.794 350.485 1065.845 22.056 22.033 23.478 445.211 209.545 3.34 121.951 4.288 Zn 40.953 67.824 36.596 65.169 38.243 55.034 44.018 72.521 20.384 28.008 96.196 34.108 87.387 76.281 36.656 28.816 60.753 70.873 50.19 39.533 42.883 120.203 25.064 66.109 42.608 46.656 71.833 58.55 59.36 69.216 58.69 33.71 47.975 74.924 66.204 81.773 56.043 66.453 57.421 37.022 49.878 42.218 24.924 33.042 43.632 34.275 35.355 102.854 33.883 57.599 80.134 60.823 58.407 21.952 53.058 27.328 Ga 8.46 4.102 6.196 5.357 11.073 8.895 12.543 1.473 10.324 10.316 1.002 5.109 2.503 10.167 5.266 9.003 3.254 1.228 6.28 10.655 10.229 2.461 4.193 2.909 2.681 4.601 4.343 2.998 3.973 1.932 2.237 4.608 4.293 1.78 3.342 1.698 5.757 4.174 4.782 5.236 5.466 4.907 12.121 12.006 11.609 6.647 5.561 6.961 8.373 5.636 20.718 4.15 4.739 13.459 8.794 9.92 Rb 1.18 0.715 0.371 0.351 1.281 0.557 2.668 0.059 1.066 2.205 0.023 0.221 0.529 1.32 0.379 0.502 0.726 0.026 0.613 0.586 0.701 0.039 0.271 0.474 0.132 0.461 0.641 0.827 0.377 0.224 0.459 2.803 0.942 0.14 0.313 1.044 0.371 0.271 0.643 0.801 0.433 0.642 3.237 0.933 2.193 0.431 0.884 0.02 1.835 0.924 8.504 0.542 0.179 0.785 1.511 1.99 Sr 302.953 194.703 129.669 26.687 481.096 198.249 404.545 0.89 503.057 432.303 4.121 49.102 10.091 210.416 48.35 299.129 102.272 0.659 172.322 499.856 375.778 1.014 28.623 14.423 21.186 24.8 12.499 12.654 14.483 14.985 21.805 147.124 34.473 2.741 8.831 4.946 63.44 13.818 26.191 33.402 85.462 38.463 440.299 490.331 417.208 153.536 64.273 4.175 306.221 87.729 739.252 8.232 9.629 1158.948 102.735 709.14 Y 3.051 2.217 8.533 6.216 4.93 8.983 9.954 0.394 3.945 5.366 0.139 8.218 1.936 12.994 8.369 3.004 1.709 0.139 4.495 5.199 3.457 1.511 7.007 0.889 3.911 6.079 2.642 2.187 2.882 1.836 3.234 8.948 4.984 0.968 2.029 1.013 4.519 2.581 4.939 8.904 3.462 7.431 2.034 2.26 5.878 8.227 9.337 0.466 7.486 6.219 10.655 1.248 4.882 2.199 14.404 2.624 Zr 6.211 3.937 11.953 9.311 6.974 16.787 31.851 0.869 5.108 8.52 0.217 8.924 4.607 28.421 13.09 5.301 2.962 0.379 6.574 6.284 5.616 1.934 7.505 1.283 15.6 8.211 5.069 3.225 4.479 3.411 3.939 13.05 8.033 2.866 3.364 3.489 6.52 3.891 6.678 11.935 4.902 9.262 9.378 3.895 9.258 19.76 13.477 1.36 12.365 7.721 23.37 1.844 5.748 2.607 37.558 7.388 Nb 0.11 0.19 0.08 0.247 0.07 0.194 1.04 0.01 0.15 0.19 0.008 0.02 0.183 0.1 0.156 0.027 0.002 0.1 0.105 0.099 0.07 0.038 0.032 0.039 0.093 0.075 0.049 0.077 0.069 0.042 0.221 0.129 0.143 0.075 0.184 0.123 0.049 0.097 0.049 0.06 0.065 0.318 0.068 0.148 0.049 0.06 0.036 0.029 0.021 4.459 0.029 0.031 0.027 0.79 0.046 Ba 50.72 38.786 12.895 6.202 67.29 29.514 109.835 7.205 39.568 49.107 1.731 1.947 8.677 65.222 5.426 27.208 9.559 2.057 19.702 62.097 41.659 5.597 5.815 1.296 6.502 4.91 5.933 5 5.041 4.321 5.713 28.117 12.671 2.434 4.967 9.846 9.796 3.783 7.962 5.083 10.363 6.312 76.331 57.769 76.796 15.601 9.362 10.891 38.573 14.039 629.097 2.373 1.454 93.905 40.067 59.837 La 1.188 1.683 0.973 0.825 1.292 1.489 3.612 0.323 0.85 1.041 0.297 0.677 0.724 3.216 0.775 0.731 0.395 0.208 1.28 1.278 0.992 0.558 0.557 0.22 0.318 0.536 0.413 0.234 0.314 0.26 0.427 1.261 0.676 0.401 0.324 0.474 0.501 0.178 0.613 1.913 0.354 0.585 1.461 1.025 1.291 0.915 0.857 0.15 1.04 0.556 20.933 0.13 0.22 1.672 2.6 1.527 Ce 2.449 2.618 3.159 2.554 2.789 4.26 9.069 0.196 1.993 2.69 0.166 2.282 1.284 8.622 2.328 1.539 0.752 0.077 2.611 3.103 1.981 0.72 1.502 0.431 1.013 1.677 0.649 0.556 0.713 0.62 0.91 3.761 1.926 0.864 0.807 0.893 1.149 0.416 1.436 2.468 0.927 1.944 2.919 2.084 3.064 3.03 2.82 0.287 3.192 1.917 40.052 0.278 0.731 2.687 7.247 1.511 Pr 0.335 0.272 0.605 0.437 0.432 0.714 1.299 0.02 0.326 0.432 0.01 0.47 0.172 1.336 0.414 0.208 0.106 0.006 0.271 0.454 0.279 0.121 0.305 0.067 0.205 0.311 0.088 0.093 0.114 0.103 0.17 0.666 0.334 0.122 0.131 0.118 0.194 0.067 0.205 0.422 0.158 0.376 0.367 0.281 0.476 0.586 0.539 0.039 0.577 0.377 4.387 0.042 0.149 0.319 1.178 0.236 Nd 1.662 1.445 3.756 2.555 2.399 4.138 6.533 0.115 1.902 2.452 0.044 3.115 0.874 7.428 2.586 1.139 0.574 0.024 1.577 2.642 1.498 0.614 2.03 0.323 1.311 1.915 0.497 0.529 0.666 0.594 1.09 3.921 1.979 0.604 0.752 0.56 1.176 0.398 1.256 2.699 0.914 2.336 1.632 1.359 2.592 3.572 3.405 0.181 3.469 2.375 18.254 0.231 1 1.478 6.418 1.331 Sm 0.468 0.423 1.347 0.843 0.785 1.382 1.799 0.035 0.629 0.812 0.011 1.202 0.254 2.266 1 0.387 0.198 0.006 0.561 0.886 0.495 0.185 0.813 0.111 0.5 0.717 0.191 0.19 0.25 0.204 0.406 1.354 0.676 0.17 0.261 0.154 0.438 0.155 0.493 1.049 0.335 0.874 0.383 0.366 0.825 1.266 1.309 0.05 1.192 0.879 3.457 0.085 0.443 0.391 2.12 0.443 Eu 0.294 0.214 0.471 0.287 0.413 0.513 0.705 0.026 0.325 0.385 0.011 0.432 0.09 0.825 0.375 0.239 0.106 0.008 0.254 0.452 0.329 0.096 0.311 0.063 0.19 0.262 0.069 0.075 0.091 0.082 0.14 0.469 0.241 0.058 0.093 0.05 0.179 0.067 0.187 0.388 0.152 0.324 0.295 0.327 0.48 0.474 0.484 0.029 0.463 0.332 1.358 0.036 0.165 0.332 0.734 0.288 Gd 0.556 0.479 1.608 1.063 0.918 1.644 1.951 0.051 0.756 0.961 0.012 1.522 0.314 2.568 1.352 0.492 0.272 0.01 0.715 1.022 0.616 0.211 1.151 0.14 0.672 0.985 0.289 0.289 0.371 0.28 0.559 1.69 0.882 0.209 0.336 0.182 0.619 0.253 0.706 1.456 0.47 1.219 0.399 0.415 1.027 1.555 1.674 0.06 1.434 1.074 2.986 0.134 0.656 0.445 2.547 0.518 Tb 0.088 0.071 0.257 0.178 0.144 0.265 0.303 0.009 0.117 0.154 0.002 0.242 0.052 0.397 0.229 0.079 0.045 0.002 0.118 0.158 0.098 0.032 0.198 0.023 0.111 0.171 0.056 0.053 0.067 0.049 0.096 0.275 0.147 0.03 0.057 0.028 0.109 0.05 0.123 0.248 0.083 0.207 0.059 0.064 0.166 0.251 0.276 0.01 0.229 0.177 0.383 0.025 0.123 0.068 0.422 0.081 Dy 0.575 0.432 1.658 1.19 0.95 1.726 1.906 0.062 0.749 1.007 0.019 1.588 0.35 2.546 1.549 0.54 0.303 0.017 0.828 1.007 0.652 0.215 1.322 0.151 0.734 1.184 0.438 0.391 0.511 0.355 0.653 1.829 1.007 0.204 0.413 0.197 0.787 0.405 0.885 1.7 0.617 1.422 0.373 0.41 1.099 1.581 1.811 0.072 1.465 1.157 2.141 0.196 0.868 0.426 2.728 0.513 Ho 0.118 0.088 0.337 0.251 0.193 0.355 0.376 0.014 0.15 0.203 0.004 0.319 0.074 0.505 0.323 0.111 0.067 0.004 0.172 0.198 0.129 0.048 0.272 0.034 0.151 0.246 0.103 0.092 0.119 0.076 0.138 0.379 0.216 0.041 0.088 0.043 0.174 0.097 0.191 0.353 0.137 0.301 0.074 0.083 0.224 0.319 0.372 0.017 0.298 0.242 0.411 0.047 0.192 0.086 0.565 0.103 Er 0.33 0.236 0.904 0.729 0.537 0.964 1.018 0.047 0.387 0.538 0.018 0.847 0.221 1.369 0.881 0.305 0.187 0.016 0.481 0.529 0.359 0.14 0.728 0.1 0.405 0.71 0.335 0.284 0.37 0.229 0.393 1.052 0.613 0.119 0.264 0.124 0.509 0.318 0.57 0.982 0.402 0.842 0.202 0.225 0.61 0.843 0.966 0.057 0.789 0.658 1.062 0.157 0.561 0.231 1.514 0.274 Tm 0.05 0.036 0.127 0.114 0.077 0.144 0.148 0.007 0.058 0.079 0.003 0.122 0.035 0.199 0.127 0.046 0.029 0.003 0.075 0.076 0.053 0.021 0.104 0.016 0.058 0.107 0.058 0.048 0.062 0.036 0.059 0.153 0.096 0.018 0.043 0.02 0.08 0.056 0.088 0.147 0.064 0.126 0.03 0.032 0.091 0.123 0.14 0.009 0.114 0.097 0.153 0.028 0.088 0.032 0.222 0.039 Yb 0.322 0.237 0.777 0.727 0.501 0.906 0.925 0.061 0.365 0.486 0.031 0.761 0.24 1.276 0.811 0.296 0.193 0.032 0.5 0.47 0.343 0.145 0.648 0.112 0.368 0.69 0.414 0.34 0.452 0.247 0.384 0.967 0.632 0.123 0.288 0.144 0.556 0.397 0.591 0.926 0.444 0.806 0.192 0.209 0.593 0.762 0.865 0.071 0.703 0.633 0.978 0.215 0.596 0.206 1.406 0.245 Lu 0.046 0.036 0.108 0.111 0.07 0.131 0.132 0.011 0.049 0.067 0.006 0.108 0.039 0.182 0.114 0.043 0.03 0.006 0.072 0.066 0.049 0.022 0.094 0.018 0.052 0.106 0.069 0.055 0.071 0.039 0.058 0.142 0.093 0.02 0.045 0.023 0.087 0.064 0.093 0.135 0.068 0.117 0.027 0.031 0.085 0.106 0.123 0.013 0.099 0.094 0.142 0.036 0.092 0.029 0.199 0.034 Hf 0.244 0.164 0.606 0.449 0.326 0.721 1.059 0.024 0.237 0.348 0.008 0.469 0.169 1.086 0.554 0.195 0.114 0.009 0.283 0.309 0.219 0.078 0.454 0.06 0.215 0.405 0.206 0.158 0.195 0.137 0.211 0.644 0.37 0.109 0.157 0.126 0.293 0.169 0.297 0.609 0.221 0.47 0.265 0.13 0.368 0.569 0.606 0.041 0.554 0.381 0.8 0.079 0.295 0.125 1.338 0.245 Ta 0.006 0.009 0.015 0.01 0.015 0.018 0.045 0.001 0.006 0.008 0.001 0.006 0.011 0.005 0.008 0.003 0.001 0.008 0.01 0.007 0.003 0.004 0.001 0.002 0.006 0.01 0.005 0.007 0.009 0.004 0.022 0.01 0.01 0.005 0.011 0.008 0.003 0.028 0.005 0.01 0.008 0.047 0.005 0.018 0.011 0.006 0.004 0.007 0.002 0.222 0.002 0.003 0.002 0.05 0.004 Pb 0.849 0.921 0.385 1.15 0.916 0.739 1.746 0.544 0.353 0.438 0.446 0.717 0.797 0.863 0.59 0.479 0.347 0.59 0.465 0.829 0.677 0.757 0.646 0.73 0.249 0.578 0.839 0.516 0.676 0.539 0.335 0.736 0.653 0.5 0.537 0.495 0.603 0.915 0.694 0.592 0.48 0.634 1.048 0.635 1.175 0.678 0.466 0.753 0.343 0.213 12.066 0.788 0.559 0.405 0.953 0.354 U 0.01 0.009 0.007 0.01 0.008 0.015 0.067 0.001 0.004 0.008 0.004 0.004 0.018 0.046 0.007 0.011 0.005 0.008 0.005 0.01 0.104 0.008 0.011 0.006 0.011 0.015 0.022 0.015 0.008 0.01 0.025 0.019 0.016 0.009 0.03 0.009 0.005 0.021 0.014 0.007 0.009 0.063 0.009 0.012 0.005 0.007 0.019 0.003 0.002 0.752 0.004 0.003 0.004 0.059 0.008 Th 0.025 0.02 0.018 0.031 0.021 0.041 0.173 0.003 0.006 0.02 0.002 0.008 0.053 0.147 0.016 0.021 0.012 0.019 0.008 0.018 0.018 0.012 0.009 0.007 0.029 0.025 0.015 0.025 0.015 0.019 0.067 0.043 0.043 0.023 0.063 0.022 0.009 0.024 0.016 0.015 0.021 0.145 0.023 0.027 0.015 0.018 0.01 0.005 0.004 1.07 0.006 0.006 0.005 0.173 0.008 * TR8 with number is drill core TR8 with sample position MAMBULA ICP-MS TRACE ELEMENTS Context MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core MBH core Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field Field m drill core 51.3 91 94.75 121.67 122.1 154.74 159.03 162.67 184.63 193.12 197.2 214.18 224.15 225.34 225.61 228.35 229.67 247.18 251.64 254.53 255.53 258.65 262.65 265.04 270.7 281.75 287.15 303.57 305.02 309.85 318.38 349 352.16 357.06 358.2 361.9 373.05 Field sample MB 005 MB 009 MB 011 MB 013 MB 014 MB 015 MB 016 MB 019 MB 020 MB 023 WMB 82-1 WMB 82-26 WMB 82-29 WMB 82-3 WMB 82-6 WMB 82-7 WMB 82-9 MB91-1 MB91-2 WMB535 WMB537 WMB544 WMB545 WMB546 P 47.947 56.036 43.945 35.532 39.894 20.049 143.148 55.681 40.488 46.849 62.569 44.351 34.928 35.069 40.869 42.457 30.829 30.776 34.865 60.728 63.845 59.061 58.414 85.819 69.709 44.822 38.176 30.201 34.461 50.047 53.47 75.269 41.886 62.981 80.926 66.81 72.535 74.637 66.981 64.838 80.238 29.849 47.277 60.749 19.915 70.411 100.839 45.401 36.292 10.659 71.883 68.591 75.052 31.781 61.839 46.73 58.718 51.883 90.964 21.527 50.684 Sc 4.629 6.635 7.3 41.964 34.65 27.183 18.836 32.449 57.093 78.633 71.928 6.152 27.007 18.395 8.202 14.33 37.934 30.596 30.001 74.888 70.748 76.478 80.186 82.214 2.52 10.27 8.792 23.469 32.56 18.152 24.15 12.36 21.269 20.356 40.876 6.23 20.128 74.202 74.863 77.58 78.258 19.143 36.586 82.76 27.07 79.232 1.233 38.226 0.097 28.885 82.605 86.214 0.559 32.157 21.892 24.677 68.435 0.871 64.24 14.238 17.844 V 708.65 839.315 852.082 509.424 606.295 1775.748 811.027 306.466 202.376 278.581 237.955 775.652 480.398 433.69 42.573 684.237 690.467 784.602 203.42 283.321 271.059 286.874 304.833 312.585 12.673 964.247 804.714 336.952 1094.254 3026.255 537.788 805.486 987.489 252.987 161.225 49.661 113.064 307.871 256.102 254.911 257.222 2897.888 275.898 247.352 3087.687 295.035 13.784 223.58 1.956 2691.202 224.653 221.279 33.318 1348.272 72.242 101.013 418.95 6.563 280.435 2759.935 64.998 Cr 26.744 177.234 34.608 13.75 4.796 91.705 44.604 98.238 13.799 14.108 4.13 18.666 9.581 31.24 9.756 50.958 19.713 25.791 8.375 7.346 3.792 5.524 6.046 7.833 34.44 27.964 21.415 4.616 12.589 52.065 7.12 11.962 8.906 58.907 695.742 37.258 5.503 3.787 2.341 3.638 5.094 63.749 88.079 4.873 61.102 3.694 1.967 130.829 0.661 60.824 3.739 9.193 2.943 46.152 83.937 207.223 360.515 7.016 3.603 75.287 25.283 Co 78.459 89.118 84.014 64.561 72.109 225.157 75.009 57.651 50.879 60.249 54.083 79.537 66.822 62.131 21.349 80.286 87.581 104.553 56.977 59.632 55.894 59.569 63.269 65.213 9.22 90.617 88.302 59.098 116.288 220.044 65.168 76.662 95.904 34.201 42.242 19.306 43.924 63.703 58.695 63.753 64.242 176.904 56.705 52.941 153.1 57.505 4.925 40.377 28.691 169.831 55.631 57.883 24.829 90.325 55.188 59.475 67.476 2.229 59.779 193.966 16.272 Ni 45.375 49.063 44.253 71.362 37.808 205.735 43.48 28.854 20.869 21.261 19.169 57.751 37.972 34.022 9.682 50.972 48.341 39.1 51.554 27.124 22.506 26.983 28.201 32.592 25.925 62.691 82.187 25.448 52.578 171.059 81.953 68.612 53.484 46.435 217.363 17.704 68.257 24.085 13.252 19.158 14.957 108.148 103.804 11.725 76.444 20.584 21.324 49.317 3.037 36.443 9.584 15.051 6.589 13.085 131.724 166.46 110.958 6.928 17.405 70.105 6.072 Cu 60.865 69.938 56.261 76.844 80.647 207.628 48.56 23.914 19.615 10.826 10.787 69.628 53.204 49.04 4.25 56.259 57.15 83.881 59.44 12.699 10.966 12.465 12.646 21.307 6.43 65.007 83.128 237.935 104.52 160.032 60.655 98.594 130.074 8.388 8.252 17.365 65.756 12.005 6.372 6.291 8.93 98.535 32.73 8.587 35.642 8.025 16.631 3.384 4.033 49.641 9.324 8.653 5.564 43.701 54.807 54.587 154.691 9.975 7.285 13.477 1.237 Zn 122.024 123.199 122.691 83.283 92.467 243.272 115.526 72.746 64.588 63.062 53.647 114.208 83.58 73.132 24.924 101.282 110.902 128.544 40.056 60.329 56.581 59.535 65.949 64.647 13.052 119.805 121.494 66.136 142.036 358.251 73.901 99.611 117.083 46.969 56.73 23.278 26.933 66.034 65.557 73.197 87.953 355.206 85.776 59.807 228.151 57.374 5.09 43.165 2.243 236.057 64.162 72.429 9.521 227.675 24.598 33.617 55.661 7.551 74.512 335.132 23.536 Rb 16.703 6.878 6.653 2.339 2.547 1.389 11.998 3.963 6.08 1.053 0.673 8.762 8.49 2.66 2.07 3.892 2.128 9.632 20.232 0.871 0.673 1.05 0.964 1.481 12.523 9.1 7.604 3.646 3.474 12.77 7.533 6.479 1.319 2.02 0.714 19.38 6.76 1.225 0.412 0.6 0.789 0.005 2.48 0.476 0.684 1.379 0.681 1.537 32.614 0.178 0.436 0.231 8.53 0.95 2.185 0.809 1.022 1.593 1.529 0.658 2.924 Sr 1116.215 907.659 851.521 626.281 492.438 321.96 605.419 537.19 447.454 193.21 155.841 909.248 779.103 709.757 938.371 790.999 519.308 811.974 805.439 187.701 195.256 182.85 134.789 115.05 1165.853 777.022 895.922 708.843 491.391 126.155 650.467 840.23 573.53 1016.672 682.283 1276.19 578.169 174.613 132.856 117.495 121.931 0.579 345.36 192.688 127.253 211.855 566.787 347.868 910.705 120.328 130.271 73.496 1253.47 259.605 470.907 342.728 32.249 788.261 224.882 112.889 874.582 Y 0.498 1.17 1.339 11.277 9.699 5.658 7.07 7.434 15.455 21.547 19.835 1.137 6.278 4.061 1.274 3.333 9.656 8.643 8.153 20.885 19.782 21.361 22.105 23.042 0.473 2.302 1.829 5.47 7.91 2.954 6.17 3.343 5.496 4.909 14.651 0.976 6.07 22.156 20.839 20.959 20.977 0.13 11.368 22.785 4.039 21.516 1.291 10.292 0.132 2.144 22.371 22.39 0.495 6.902 3.159 4.42 19.597 0.624 18.06 2.453 4.315 Zr 4.517 9.264 5.309 16.153 15.952 11.398 13.624 12.528 13.165 26.523 24.371 5.927 9.076 6.42 1.855 7.865 11.912 11.786 10.262 26.71 25.496 29.169 28.223 30.618 1.73 9.347 4.686 8.155 11.367 18.049 10.439 8.124 9.9 6.309 20.816 1.82 16.641 30.07 26.73 25.561 26.946 17.617 18.682 27.997 16.983 27.857 1.651 13.494 4.21 2.159 25.74 24.638 0.701 11.684 4.297 7.327 26.128 0.62 26.243 16.383 5.045 Nb 0.463 0.928 0.543 0.256 0.324 0.933 1.143 0.476 0.119 0.199 0.144 0.567 0.243 0.233 0.034 0.626 0.352 1.557 0.097 0.235 0.162 0.317 0.424 0.352 0.142 0.721 0.515 0.346 0.523 2.903 0.692 1.076 0.495 0.075 0.142 0.543 0.551 0.32 0.186 0.125 0.258 2.017 0.156 0.11 1.243 0.214 0.438 0.112 0.261 0.165 0.111 0.101 0.141 0.953 0.117 0.052 0.296 0.112 0.31 1.347 0.084 Ba 295.153 199.534 221.239 144.34 128.747 73.305 208.942 177.249 99.069 38.744 28.368 201.481 221.454 158.497 168.725 146.163 120.07 182.033 247.088 40.223 36.025 43.76 29.496 30.365 205.891 167.504 218.857 174.066 126.131 71.874 140.681 188.114 115.621 164.696 84.514 247.973 122.147 48.118 17.448 32.02 25.67 1.322 167.225 39.813 41.556 48.377 93.992 86.286 400.687 32.71 35.204 30.352 274.778 252.665 108.927 53.323 71.219 119.481 62.941 47.731 189.673 La 1.595 2.088 1.58 2.069 1.727 0.98 4.423 1.975 1.727 1.85 1.716 1.644 1.549 1.452 1.417 1.568 1.526 1.701 1.537 1.994 1.809 2.079 1.985 2.536 1.833 1.616 1.63 1.662 1.348 0.786 1.784 2.771 1.272 1.982 2.102 1.966 3.354 2.026 1.66 1.571 1.761 0.114 1.448 1.894 0.536 2.035 1.582 1.452 0.931 0.091 1.738 1.508 2.004 0.858 0.878 0.939 1.713 1.645 2.443 0.49 1.863 Ce 2.739 3.63 2.897 5.268 4.774 2.549 9.858 4.738 5.248 6.498 6.312 3.024 3.445 3.158 2.46 3.514 4.14 4.235 3.904 6.904 6.418 7.151 7.073 8.507 2.918 3.179 3.112 3.518 3.528 1.739 4.295 5.428 3.227 3.805 6.779 3.048 7.576 7.293 6.275 6.027 6.503 0.217 3.927 7.381 1.573 7.237 3.476 4.507 1.623 0.363 6.667 6.066 3.45 2.505 1.972 2.464 5.363 2.862 7.582 1.069 3.63 Pr 0.298 0.421 0.343 0.929 0.8 0.45 1.266 0.726 1.02 1.331 1.263 0.338 0.554 0.44 0.268 0.44 0.723 0.691 0.657 1.353 1.268 1.404 1.402 1.62 0.295 0.393 0.381 0.526 0.603 0.253 0.63 0.655 0.477 0.561 1.318 0.317 0.934 1.388 1.234 1.224 1.282 0.03 0.665 1.458 0.282 1.395 0.363 0.716 0.161 0.079 1.388 1.3 0.387 0.464 0.277 0.371 1.067 0.326 1.378 0.188 0.5 Nd 1.063 1.557 1.371 5.281 4.685 2.548 5.58 3.788 6.111 8.202 7.93 1.288 2.937 2.211 1.005 2.028 4.196 3.781 3.69 8.332 7.969 8.637 8.619 9.694 0.948 1.705 1.599 2.719 3.381 1.242 3.148 2.687 2.541 2.911 8.324 1.092 4.098 8.416 7.709 7.598 7.873 0.118 3.843 9.187 1.648 8.523 1.383 4.115 0.509 0.58 9.062 8.62 1.396 2.85 1.443 1.994 6.725 1.351 8.199 1.063 2.597 Sm 0.337 0.377 0.413 1.726 1.595 0.833 1.41 1.218 2.06 2.798 2.648 0.382 0.987 0.707 0.276 0.586 1.378 1.261 1.255 2.791 2.669 2.885 2.938 3.215 0.263 0.497 0.453 0.883 1.155 0.419 0.971 0.694 0.824 0.89 2.642 0.317 1.087 2.874 2.693 2.641 2.702 0.025 1.36 3.131 0.562 2.867 0.327 1.371 0.27 0.264 3.057 2.947 0.348 1.057 0.456 0.624 2.495 0.24 2.824 0.347 0.757 Eu 0.485 0.47 0.483 0.808 0.705 0.399 0.732 0.605 0.855 1.002 0.951 0.461 0.593 0.499 0.4 0.47 0.677 0.626 0.701 1.01 0.958 1.03 1.018 1.104 0.434 0.471 0.474 0.562 0.581 0.172 0.564 0.518 0.495 0.574 1.026 0.44 0.57 1.021 0.963 0.963 0.989 0.008 0.654 1.149 0.238 1.055 0.414 0.607 0.41 0.165 1.078 1.049 0.648 0.513 0.333 0.361 0.878 0.458 1.087 0.169 0.612 Gd 0.209 0.314 0.313 1.889 1.56 0.931 1.44 1.262 2.299 3.231 2.779 0.305 1.003 0.666 0.233 0.601 1.528 1.37 1.301 3.223 2.754 3.287 3.353 3.71 0.182 0.442 0.395 0.896 1.28 0.46 1.048 0.675 0.908 0.902 2.495 0.231 1.132 3.382 3.231 3.225 3.269 0.023 1.648 3.702 0.649 3.404 0.314 1.418 0.092 0.286 3.217 3.133 0.251 1.019 0.496 0.731 3.328 0.205 3.49 0.444 0.889 Tb 0.02 0.039 0.045 0.319 0.295 0.161 0.223 0.212 0.412 0.58 0.552 0.041 0.172 0.12 0.032 0.096 0.276 0.241 0.231 0.585 0.55 0.598 0.612 0.661 0.018 0.068 0.058 0.157 0.224 0.081 0.177 0.102 0.156 0.147 0.46 0.028 0.184 0.596 0.558 0.553 0.573 0.004 0.301 0.645 0.113 0.592 0.042 0.274 0.008 0.059 0.619 0.61 0.022 0.191 0.087 0.128 0.583 0.025 0.552 0.072 0.135 Dy 0.094 0.211 0.25 1.988 1.808 1.022 1.284 1.297 2.618 3.708 3.513 0.209 1.085 0.722 0.207 0.584 1.71 1.495 1.448 3.676 3.419 3.758 3.817 4.159 0.081 0.418 0.349 0.971 1.414 0.511 1.083 0.585 0.985 0.893 2.732 0.155 1.105 3.754 3.556 3.533 3.57 0.023 1.945 3.973 0.707 3.688 0.23 1.808 0.025 0.376 3.93 3.875 0.099 1.204 0.541 0.795 3.631 0.133 3.524 0.473 0.854 Ho 0.017 0.041 0.05 0.397 0.366 0.207 0.25 0.264 0.533 0.758 0.712 0.039 0.221 0.149 0.043 0.116 0.351 0.306 0.29 0.75 0.716 0.764 0.787 0.841 0.016 0.08 0.066 0.197 0.285 0.102 0.218 0.114 0.198 0.177 0.539 0.034 0.217 0.771 0.725 0.714 0.722 0.006 0.401 0.804 0.148 0.746 0.045 0.374 0.004 0.079 0.803 0.794 0.017 0.252 0.112 0.158 0.736 0.024 0.701 0.096 0.171 Er 0.047 0.11 0.127 1.028 0.939 0.553 0.66 0.699 1.396 1.975 1.867 0.11 0.59 0.392 0.125 0.318 0.917 0.816 0.769 1.963 1.872 1.998 2.056 2.233 0.045 0.214 0.176 0.518 0.757 0.269 0.573 0.299 0.524 0.447 1.374 0.098 0.578 2.018 1.908 1.889 1.906 0.015 1.096 2.093 0.387 1.965 0.115 1.004 0.012 0.198 2.085 2.056 0.043 0.635 0.294 0.428 1.95 0.06 1.854 0.255 0.449 Tm 0.007 0.014 0.02 0.151 0.141 0.08 0.091 0.103 0.21 0.294 0.276 0.016 0.086 0.06 0.019 0.046 0.138 0.12 0.112 0.292 0.28 0.297 0.309 0.326 0.007 0.033 0.025 0.076 0.11 0.042 0.083 0.045 0.076 0.067 0.202 0.015 0.083 0.306 0.286 0.283 0.294 0.002 0.167 0.311 0.055 0.293 0.016 0.154 0.001 0.027 0.31 0.303 0.005 0.098 0.045 0.063 0.279 0.008 0.267 0.037 0.064 Yb 0.034 0.097 0.113 0.917 0.814 0.486 0.562 0.657 1.289 1.811 1.688 0.095 0.55 0.366 0.136 0.287 0.84 0.756 0.692 1.78 1.677 1.811 1.901 2.012 0.046 0.189 0.156 0.492 0.671 0.248 0.52 0.263 0.459 0.41 1.223 0.103 0.499 1.851 1.767 1.734 1.752 0.022 1.04 1.864 0.346 1.767 0.101 0.946 0.008 0.154 1.869 1.852 0.028 0.575 0.271 0.375 1.743 0.046 1.66 0.233 0.4 Lu 0.006 0.013 0.016 0.134 0.118 0.072 0.082 0.096 0.187 0.263 0.249 0.014 0.079 0.053 0.021 0.043 0.123 0.11 0.103 0.265 0.246 0.267 0.28 0.292 0.007 0.029 0.022 0.071 0.098 0.036 0.076 0.039 0.069 0.059 0.176 0.018 0.072 0.273 0.262 0.252 0.269 0.004 0.155 0.27 0.05 0.26 0.014 0.14 0.002 0.021 0.274 0.274 0.004 0.087 0.04 0.056 0.247 0.006 0.239 0.036 0.056 Hf 0.15 0.28 0.198 0.714 0.731 0.548 0.607 0.523 0.696 1.168 1.098 0.192 0.394 0.291 0.07 0.305 0.599 0.565 0.468 1.193 1.126 1.28 1.286 1.36 0.051 0.327 0.193 0.362 0.575 0.71 0.456 0.279 0.462 0.325 0.942 0.062 0.58 1.271 1.117 1.123 1.141 0.575 0.791 1.188 0.62 1.166 0.05 0.575 0.092 0.117 1.176 1.167 0.562 0.165 0.284 1.378 0.015 1.203 0.573 0.251 Ta 0.027 0.061 0.034 0.023 0.022 0.073 0.137 0.034 0.015 0.028 0.014 0.036 0.018 0.036 0.006 0.057 0.03 0.312 0.01 0.025 0.015 0.03 0.043 0.034 0.004 0.047 0.04 0.04 0.042 0.32 0.075 0.068 0.043 0.007 0.007 0.037 0.037 0.034 0.023 0.021 0.039 0.142 0.018 0.018 0.086 0.022 0.038 0.012 0.028 0.011 0.02 0.019 0.014 0.075 0.011 0.007 0.034 0.017 0.033 0.095 0.009 Pb 1.349 2.569 15.079 1.735 0.62 0.416 2.918 1.066 1.234 0.662 0.306 1.438 0.518 1.217 0.73 1.482 0.592 1.902 0.758 0.207 0.702 0.452 0.736 0.447 3.248 2.473 2.617 4.004 0.767 6.621 1.828 2.869 0.611 0.59 1.301 5.135 2.224 0.444 2.765 3.321 0.794 3.069 0.464 0.344 1.014 2.321 1.279 -0.384 0.058 0.748 1.543 0.763 0.367 1.205 Th 0.021 0.15 0.049 0.025 0.026 0.024 0.739 0.1 0.042 0.09 0.054 0.075 0.019 0.017 0.007 0.226 0.036 0.113 0.022 0.085 0.06 0.115 0.09 0.179 0.053 0.109 0.047 0.068 0.038 0.387 0.219 0.415 0.041 0.021 0.037 0.07 0.42 0.085 0.059 0.039 0.079 0.026 0.019 0.037 0.019 0.079 0.07 0.024 0.177 0.001 0.042 0.033 0.047 0.023 0.03 0.012 0.098 0.039 0.119 0.018 0.039 U 0.008 0.102 0.076 0.01 0.012 0.02 0.318 0.06 0.025 0.053 0.017 0.055 0.009 0.008 0.003 0.211 0.018 0.275 0.023 0.031 0.02 0.041 0.05 0.06 0.063 0.132 0.031 0.073 0.02 0.51 0.155 0.095 0.034 0.013 0.014 0.098 0.116 0.032 0.021 0.013 0.037 0.016 0.006 0.011 0.034 0.032 0.095 0.011 0.118 0.005 0.013 0.011 0.021 0.027 0.014 0.004 0.048 0.017 0.045 0.016 0.018 Standards REFERENCE STANDARDS RUN OVER THE DURATION OF THE EXPERIMENT Run with samples from Nondweni greenstone belt BCR-1 BCR-1 BCR-1 BCR-1 BCR-1 BHVO-1 BHVO-1 BHVO-1 BHVO-1 BIR1 BIR1 BIR1 BIR1 Meas (n=24) Recom Std Dev % Dev %error Meas (n=18) Recom Std. dev % Dev %error Meas (n=26) Recom Std Dev % Dev %error Sc 30.682 32.6 1.43 4.7 -5.9 33.921 31.8 1.56 4.6 6.7 44.659 44 1.8 4 1.5 V 398.764 407 4.34 1.1 -2 323.688 317 5.43 1.7 2.1 328.825 313 8.3 2.5 5.1 Cr 9.175 16 1.54 16.8 -42.7 294 289 8.34 2.8 1.7 375.356 382 7.5 2 -1.7 Co 35.235 37 1.36 3.9 -4.8 47.392 45 2.84 6 5.3 57.152 51.4 2.8 4.9 11.2 Ni 9.81 13 1.76 17.9 -24.5 119 121 3.86 3.2 -1.7 165.442 166 4.42 2.7 -0.3 Cu 17.502 19 2.75 15.7 -7.9 148.991 136 10.47 7 9.6 137.51 126 12.67 9.2 9.1 Zn 119.853 130 5.4 4.5 -7.8 114.761 105 6.78 5.9 9.3 77.051 71 5.43 7 8.5 Rb 46.4 47.2 1.38 3 -1.7 10.569 11 1.38 13.1 -3.9 0.315 0.25 0.07 22.2 26 Sr 332.775 330 6.54 2 0.8 399.759 403 6.58 1.6 -0.8 106.448 108 2.58 2.4 -1.4 Y 36.983 38 1.97 5.3 -2.7 28.393 28 1.85 6.5 1.4 16.348 16 0.98 6 2.2 Zr 195.472 190 10.54 5.4 2.9 174.138 179 9.67 5.6 -2.7 14.755 15.5 0.87 5.9 -4.8 Nb 13.135 14 1.39 10.6 -6.2 20.341 19 1.09 5.4 7.1 0.605 0.6 0.03 5 0.8 Ba 689.554 681 15.769 2.3 1.3 137.297 139 4.45 3.2 -1.2 6.805 7 0.32 4.7 -2.8 La 24.698 24.9 1.74 7 -0.8 15.934 15.8 0.94 5.9 0.8 0.638 0.62 0.04 6.3 2.9 Ce 53.414 53.7 0.89 1.7 -0.5 39.223 39 1.04 2.7 0.6 1.982 1.95 0.12 6.1 1.6 Pr 6.859 6.8 0.34 5 0.9 5.653 5.7 0.37 6.5 -0.8 0.392 0.38 0.03 7.7 3.2 Nd 28.721 28.8 1.27 4.4 -0.3 25.276 25.2 0.87 3.4 0.3 2.368 2.5 0.1 4.2 -5.3 Sm 6.702 6.59 0.34 5.1 1.7 6.099 6.2 0.28 4.6 -1.6 1.044 1.1 0.06 5.7 -5.1 Eu 2.023 1.95 0.11 5.4 3.7 1.989 2.06 0.12 6 -3.4 0.486 0.54 0.04 7.4 -10 Gd 6.867 6.68 0.28 4.1 2.8 6.231 6.4 0.37 5.9 -2.6 1.546 1.85 0.13 7 -16.4 Tb 1.064 1.05 0.065 6.1 1.3 0.947 0.96 0.06 6.3 -1.4 0.327 0.36 0.02 5.6 -9.2 Dy 6.275 6.34 0.35 5.6 -1 5.254 5.2 0.21 4 1 2.363 2.5 0.08 3.4 -5.5 Ho 1.283 1.26 0.07 5.5 1.8 0.973 0.99 0.04 4.1 -1.7 0.53 0.57 0.03 5.7 -7 Er 3.544 3.63 0.13 3.7 -2.4 2.459 2.4 0.08 3.3 2.5 1.514 1.7 0.1 6.6 -10.9 Tm 0.545 0.56 0.03 5.5 -2.7 0.339 0.33 0.02 5.9 2.7 0.245 0.26 0.02 8.2 -5.8 Yb 3.289 3.38 0.11 3.3 -2.7 2.02 2.02 0.054 2.7 0 1.577 1.65 0.09 5.7 -4.4 Lu 0.517 0.51 0.04 7.7 1.4 0.286 0.29 0.02 7 -1.4 0.239 0.26 0.02 8.4 -8.1 Hf 5.043 4.95 0.28 5.6 1.9 4.301 4.38 0.15 3.5 -1.8 0.565 0.6 0.04 7.1 -5.8 Ta 0.806 0.81 0.02 2.5 -0.5 1.237 1.23 0.08 6.5 0.6 0.04 0.04 0.005 12.5 0 Pb 11.699 13.6 1.34 11.5 -14 3.104 2.6 0.48 15.5 19.4 3.411 3 0.67 19.6 13.7 Th 5.422 5.98 0.45 8.3 -9.3 1.204 1.08 0.11 9.1 11.5 0.032 0.03 0.004 12.5 6.7 U 1.738 1.75 0.05 2.9 -0.7 0.423 0.42 0.02 4.7 0.7 0.011 0.01 0.001 9.1 10 Average 6.1 -3.8 5.4 1.8 7.6 -0.1